The Influence of Alkyl Polyglucosides (And Highly Ethoxylated Alcohol Boosters) on the Phase Behavior of a Water/Toluene/Technical Alkyl Polyethoxylate Microemulsion System
2016
Authors
Ilić, MarijaHaegel, Franz-Hubert
Pavelkić, Vesna
Zlatanović, Dragan
Nikolić-Mandić, Snežana D.
Lolić, Aleksandar
Nedić, Zoran
Article (Published version)
Metadata
Show full item recordAbstract
The influence of additives (alkyl polyglucoside, Glucopon 600 CS UP and alcohol ethoxylate C18E100) on the behavior of the water/toluene/Lutensol ON 50 (technical oxoalcohol, i-C10E5) microemulsion system as a function of temperature and composition has been investigated. The phase behavior of the microemulsions was determined by vertical sections through the Gibbs phase prism (fish-like phase diagrams). Alkyl polyglucoside shifts the one phase region to lower temperatures compared with water/toluene/Lutensol ON 50 mixtures. This is contrary to the expectation, considering the extreme hydrophilic nature of the sugar headgroup. The addition of hydrophilic alcohol ethoxylate (C18E100) to the water/toluene/Lutensol ON 50 system increases the solubilization capacity of the surfactant, even if the co-surfactant is used in small quantities, and shifts the one-phase region to higher temperature by a few degrees C.
Keywords:
microemulsion / toluene / alkyl polyglucoside / oxoalcohol ethoxylate / efficiency booster / fish diagramsSource:
Chemical Industry and Chemical Engineering Quarterly / CICEQ, 2016, 22, 1, 27-32Publisher:
- Assoc Chemical Eng, Belgrade
Funding / projects:
- Development of new and improvement of existing electrochemical, spectroscopic and flow injection (FIA) methods on environmental quality monitoring (RS-MESTD-Basic Research (BR or ON)-172051)
- DAAD (Germany)
DOI: 10.2298/CICEQ141105015I
ISSN: 1451-9372
WoS: 000374140200004
Scopus: 2-s2.0-84962339406
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Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Ilić, Marija AU - Haegel, Franz-Hubert AU - Pavelkić, Vesna AU - Zlatanović, Dragan AU - Nikolić-Mandić, Snežana D. AU - Lolić, Aleksandar AU - Nedić, Zoran PY - 2016 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1916 AB - The influence of additives (alkyl polyglucoside, Glucopon 600 CS UP and alcohol ethoxylate C18E100) on the behavior of the water/toluene/Lutensol ON 50 (technical oxoalcohol, i-C10E5) microemulsion system as a function of temperature and composition has been investigated. The phase behavior of the microemulsions was determined by vertical sections through the Gibbs phase prism (fish-like phase diagrams). Alkyl polyglucoside shifts the one phase region to lower temperatures compared with water/toluene/Lutensol ON 50 mixtures. This is contrary to the expectation, considering the extreme hydrophilic nature of the sugar headgroup. The addition of hydrophilic alcohol ethoxylate (C18E100) to the water/toluene/Lutensol ON 50 system increases the solubilization capacity of the surfactant, even if the co-surfactant is used in small quantities, and shifts the one-phase region to higher temperature by a few degrees C. PB - Assoc Chemical Eng, Belgrade T2 - Chemical Industry and Chemical Engineering Quarterly / CICEQ T1 - The Influence of Alkyl Polyglucosides (And Highly Ethoxylated Alcohol Boosters) on the Phase Behavior of a Water/Toluene/Technical Alkyl Polyethoxylate Microemulsion System VL - 22 IS - 1 SP - 27 EP - 32 DO - 10.2298/CICEQ141105015I ER -
@article{ author = "Ilić, Marija and Haegel, Franz-Hubert and Pavelkić, Vesna and Zlatanović, Dragan and Nikolić-Mandić, Snežana D. and Lolić, Aleksandar and Nedić, Zoran", year = "2016", abstract = "The influence of additives (alkyl polyglucoside, Glucopon 600 CS UP and alcohol ethoxylate C18E100) on the behavior of the water/toluene/Lutensol ON 50 (technical oxoalcohol, i-C10E5) microemulsion system as a function of temperature and composition has been investigated. The phase behavior of the microemulsions was determined by vertical sections through the Gibbs phase prism (fish-like phase diagrams). Alkyl polyglucoside shifts the one phase region to lower temperatures compared with water/toluene/Lutensol ON 50 mixtures. This is contrary to the expectation, considering the extreme hydrophilic nature of the sugar headgroup. The addition of hydrophilic alcohol ethoxylate (C18E100) to the water/toluene/Lutensol ON 50 system increases the solubilization capacity of the surfactant, even if the co-surfactant is used in small quantities, and shifts the one-phase region to higher temperature by a few degrees C.", publisher = "Assoc Chemical Eng, Belgrade", journal = "Chemical Industry and Chemical Engineering Quarterly / CICEQ", title = "The Influence of Alkyl Polyglucosides (And Highly Ethoxylated Alcohol Boosters) on the Phase Behavior of a Water/Toluene/Technical Alkyl Polyethoxylate Microemulsion System", volume = "22", number = "1", pages = "27-32", doi = "10.2298/CICEQ141105015I" }
Ilić, M., Haegel, F., Pavelkić, V., Zlatanović, D., Nikolić-Mandić, S. D., Lolić, A.,& Nedić, Z.. (2016). The Influence of Alkyl Polyglucosides (And Highly Ethoxylated Alcohol Boosters) on the Phase Behavior of a Water/Toluene/Technical Alkyl Polyethoxylate Microemulsion System. in Chemical Industry and Chemical Engineering Quarterly / CICEQ Assoc Chemical Eng, Belgrade., 22(1), 27-32. https://doi.org/10.2298/CICEQ141105015I
Ilić M, Haegel F, Pavelkić V, Zlatanović D, Nikolić-Mandić SD, Lolić A, Nedić Z. The Influence of Alkyl Polyglucosides (And Highly Ethoxylated Alcohol Boosters) on the Phase Behavior of a Water/Toluene/Technical Alkyl Polyethoxylate Microemulsion System. in Chemical Industry and Chemical Engineering Quarterly / CICEQ. 2016;22(1):27-32. doi:10.2298/CICEQ141105015I .
Ilić, Marija, Haegel, Franz-Hubert, Pavelkić, Vesna, Zlatanović, Dragan, Nikolić-Mandić, Snežana D., Lolić, Aleksandar, Nedić, Zoran, "The Influence of Alkyl Polyglucosides (And Highly Ethoxylated Alcohol Boosters) on the Phase Behavior of a Water/Toluene/Technical Alkyl Polyethoxylate Microemulsion System" in Chemical Industry and Chemical Engineering Quarterly / CICEQ, 22, no. 1 (2016):27-32, https://doi.org/10.2298/CICEQ141105015I . .