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Ligand field analysis of metal-oxygen interactions-II. Tris(oxalato)chromate(III)
(Polyhedron, 1991)
Ligand field analysis of [Cr(ox)3]3- has been performed using the angular overlap model (AOM) approach. The metal-oxygen interactions were treated as locally anisotropic. The Trees' correction and the explicit treatment ...
Synthesis and structure of aquamethanol-2',2'''-(2,6-pyridin-diyldiethylidene)-dioxamohydrazidocobalt(II) perchlorate
(Pergamon-Elsevier Science Ltd, Oxford, 1996)
The complex [Co(H(2)L)(H2O) (MeOH)](ClO4)(2)[H(2)L] = 2',2triple prime-(2,6-pyridindiyl-diethylidene) -dioxamohydrazide] has been prepared by direct and template syntheses and characterized by elemental analysis, IR ...
Synthesis and structure of aqua-2',2'''-(2,6-pyridindiyldiethylidene) dioxamohydrazide-copper(II) hydrate
(Pergamon-Elsevier Science Ltd, Oxford, 1997)
In a template synthesis from copper(II) acetate, 2,6-diacetylpyridine, and semioxamazide (NH2CO CONHNH2), two new copper(II) complexes, [Cu(dapsox)(H2O)]. H2O and [Cu(Hdapsox)(H2O)]ClO4, (where H(2)dapsox = 2',2'''-(2,6- ...
The anisotropic pi-effect of the nitro group in ammine-nitro cobalt(III) complexes
(Pergamon-Elsevier Science Ltd, Oxford, 1997)
The analysis of crystal structures of the series of ammine-nitro cobalt(III) complexes has shown that Co-NO2 bond lengths can be successfully rationalized on the basis of the anisotropic pi-effect of nitro groups. This ...
Ligand field analysis of metal-oxygen interactions-I. Tris(oxalato)cobaltate(III)
(Polyhedron, 1991)
Ligand field analysis of [Co(ox)3]3- has been performed using the angular overlap model (AOM) approach. The metal-oxygen interactions were treated as locally anisotropic. Experimental spectra were well reproduced by the ...
Cu(II), Ni(II) and Fe(III) complexes with 2 ',2 '''-(2,6-pyridindiyldiethylidene)-dioxamohydrazide in a monoanionic form. The crystal structure of aqua-2 ',2 '''-(2,6-pyridindiyldiethylidene)-dioxamohydrazidecopper(II) perchlorate
(Pergamon-Elsevier Science Ltd, Oxford, 1998)
Starting from Cu(II) and Ni(II) perchlorate and Fe(III) chloride in the presence of 2,6-diacetylpyridine (dap) and semioxamazide (sox), the [Cu(Hdapsox)H2O]ClO4 (I), [Ni(Hdapsox)(MeOH)(2)]ClO4 (II) and [Fe(Hdapsox)Cl-2]. ...