Приказ основних података о документу
A Non-Heme Iron Photocatalyst for Light-Driven Aerobic Oxidation of Methanol
dc.creator | Chen, Juan | |
dc.creator | Stepanović, Stepan | |
dc.creator | Draksharapu, Apparao | |
dc.creator | Gruden-Pavlović, Maja | |
dc.creator | Browne, Wesley R. | |
dc.date.accessioned | 2018-11-22T00:43:31Z | |
dc.date.available | 2018-11-22T00:43:31Z | |
dc.date.issued | 2018 | |
dc.identifier.issn | 1433-7851 | |
dc.identifier.uri | https://cherry.chem.bg.ac.rs/handle/123456789/2104 | |
dc.description.abstract | Non-heme (L)Fe-III and (L)Fe-III-O-Fe-III(L) complexes (L=1,1-di(pyridin-2-yl)-N,N-bis(pyridin-2-ylmethyl)-ethan-1-amine) underwent reduction under irradiation to the Fe-II state with concomitant oxidation of methanol to methanal, without the need for a secondary photosensitizer. Spectroscopic and DFT studies support a mechanism in which irradiation results in charge-transfer excitation of a Fe-III-mu-O-Fe-III complex to generate [(L)Fe-IV=O](2+) (observed transiently during irradiation in acetonitrile), and an equivalent of (L)Fe-II. Under aerobic conditions, irradiation accelerates reoxidation from the Fe-II to the Fe-III state with O-2, thus closing the cycle of methanol oxidation to methanal. | en |
dc.publisher | Wiley-V C H Verlag Gmbh, Weinheim | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172035/RS// | |
dc.relation | info:eu-repo/grantAgreement/EC/FP7/279549/EU// | |
dc.relation | Center for Information Technology of the University of Groningen | |
dc.relation | Labex ARCANE [ANR-11-LABX-003] | |
dc.relation | Chinese Scholarship Council (CSC) | |
dc.relation | COST association action ECOSTBio (STSM) [CM1305, 38503] | |
dc.rights | openAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc/4.0/ | |
dc.source | Angewandte Chemie (International Edition) | |
dc.subject | diiron complexes | en |
dc.subject | iron | en |
dc.subject | oxidation | en |
dc.subject | photochemistry | en |
dc.subject | reaction mechanisms | en |
dc.title | A Non-Heme Iron Photocatalyst for Light-Driven Aerobic Oxidation of Methanol | en |
dc.type | article | |
dc.rights.license | BY-NC | |
dcterms.abstract | Степановиц, Степан; Цхен, Јуан; Груден-Павловић, Маја; Броwне, Wеслеy Р.; Драксхарапу, Aппарао; | |
dc.citation.volume | 57 | |
dc.citation.issue | 12 | |
dc.citation.spage | 3207 | |
dc.citation.epage | 3211 | |
dc.identifier.wos | 000426759900036 | |
dc.identifier.doi | 10.1002/anie.201712678 | |
dc.citation.other | 57(12): 3207-3211 | |
dc.citation.rank | aM21 | |
dc.identifier.pmid | 29334586 | |
dc.type.version | publishedVersion | |
dc.identifier.scopus | 2-s2.0-85042067927 | |
dc.identifier.fulltext | https://cherry.chem.bg.ac.rs/bitstream/id/9123/2102.pdf |