Transition-metal complexes with hydrazides and hydrazones .7. Dioxomolybdenum(VI) complexes of salicylaldehyde p-hydroxybenzoylhydrazone and their thermal stability
Нема приказа
Аутори
Ivanović, I.Anđelković, Katarina K.
Leovac, Vukadin M.
Klisarov, L
Lazarevic, M
Minić, Dragica M.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Several new complexes of dioxomolybdenum(VI) of the general formula [MoO2(L)S], where L is the dianion of salicylaldehyde p-hydroxybenzoylhydrazone and S denotes H2O, MeOH, py, PPh(3), DMSO or DMF, were synthesized and characterized by elemental analysis, electronic UV-VIS and IR spectra, thermal analysis, molar conductivity and magnetic susceptibility measurements. Salicylaldehyde p-hydroxybenzoylhydrazone participates in the coordination as a tridentate ligand with the ONO set of donor atoms. The complexes contain a cis-MoO2 group and are of octahedral geometry. Complexes of the MoO(2)L type were also prepared by synthesis in CHCl3 solution and by isothermal heating of[MoO2(L)S] complexes. The MoO(2)L complex synthesized in CHCl3 solution has most probably a pentacoordinated structure while the complex obtained by isothermal heating of [MoO2(L)S] has a polymeric hexacoordinated structure.
Кључне речи:
complexesИзвор:
Journal of Thermal Analysis, 1996, 46, 6, 1741-1750Издавач:
- John Wiley & Sons Ltd, W Sussex
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Ivanović, I. AU - Anđelković, Katarina K. AU - Leovac, Vukadin M. AU - Klisarov, L AU - Lazarevic, M AU - Minić, Dragica M. PY - 1996 UR - https://cherry.chem.bg.ac.rs/handle/123456789/2249 AB - Several new complexes of dioxomolybdenum(VI) of the general formula [MoO2(L)S], where L is the dianion of salicylaldehyde p-hydroxybenzoylhydrazone and S denotes H2O, MeOH, py, PPh(3), DMSO or DMF, were synthesized and characterized by elemental analysis, electronic UV-VIS and IR spectra, thermal analysis, molar conductivity and magnetic susceptibility measurements. Salicylaldehyde p-hydroxybenzoylhydrazone participates in the coordination as a tridentate ligand with the ONO set of donor atoms. The complexes contain a cis-MoO2 group and are of octahedral geometry. Complexes of the MoO(2)L type were also prepared by synthesis in CHCl3 solution and by isothermal heating of[MoO2(L)S] complexes. The MoO(2)L complex synthesized in CHCl3 solution has most probably a pentacoordinated structure while the complex obtained by isothermal heating of [MoO2(L)S] has a polymeric hexacoordinated structure. PB - John Wiley & Sons Ltd, W Sussex T2 - Journal of Thermal Analysis T1 - Transition-metal complexes with hydrazides and hydrazones .7. Dioxomolybdenum(VI) complexes of salicylaldehyde p-hydroxybenzoylhydrazone and their thermal stability VL - 46 IS - 6 SP - 1741 EP - 1750 UR - https://hdl.handle.net/21.15107/rcub_cherry_2249 ER -
@article{ author = "Ivanović, I. and Anđelković, Katarina K. and Leovac, Vukadin M. and Klisarov, L and Lazarevic, M and Minić, Dragica M.", year = "1996", abstract = "Several new complexes of dioxomolybdenum(VI) of the general formula [MoO2(L)S], where L is the dianion of salicylaldehyde p-hydroxybenzoylhydrazone and S denotes H2O, MeOH, py, PPh(3), DMSO or DMF, were synthesized and characterized by elemental analysis, electronic UV-VIS and IR spectra, thermal analysis, molar conductivity and magnetic susceptibility measurements. Salicylaldehyde p-hydroxybenzoylhydrazone participates in the coordination as a tridentate ligand with the ONO set of donor atoms. The complexes contain a cis-MoO2 group and are of octahedral geometry. Complexes of the MoO(2)L type were also prepared by synthesis in CHCl3 solution and by isothermal heating of[MoO2(L)S] complexes. The MoO(2)L complex synthesized in CHCl3 solution has most probably a pentacoordinated structure while the complex obtained by isothermal heating of [MoO2(L)S] has a polymeric hexacoordinated structure.", publisher = "John Wiley & Sons Ltd, W Sussex", journal = "Journal of Thermal Analysis", title = "Transition-metal complexes with hydrazides and hydrazones .7. Dioxomolybdenum(VI) complexes of salicylaldehyde p-hydroxybenzoylhydrazone and their thermal stability", volume = "46", number = "6", pages = "1741-1750", url = "https://hdl.handle.net/21.15107/rcub_cherry_2249" }
Ivanović, I., Anđelković, K. K., Leovac, V. M., Klisarov, L., Lazarevic, M.,& Minić, D. M.. (1996). Transition-metal complexes with hydrazides and hydrazones .7. Dioxomolybdenum(VI) complexes of salicylaldehyde p-hydroxybenzoylhydrazone and their thermal stability. in Journal of Thermal Analysis John Wiley & Sons Ltd, W Sussex., 46(6), 1741-1750. https://hdl.handle.net/21.15107/rcub_cherry_2249
Ivanović I, Anđelković KK, Leovac VM, Klisarov L, Lazarevic M, Minić DM. Transition-metal complexes with hydrazides and hydrazones .7. Dioxomolybdenum(VI) complexes of salicylaldehyde p-hydroxybenzoylhydrazone and their thermal stability. in Journal of Thermal Analysis. 1996;46(6):1741-1750. https://hdl.handle.net/21.15107/rcub_cherry_2249 .
Ivanović, I., Anđelković, Katarina K., Leovac, Vukadin M., Klisarov, L, Lazarevic, M, Minić, Dragica M., "Transition-metal complexes with hydrazides and hydrazones .7. Dioxomolybdenum(VI) complexes of salicylaldehyde p-hydroxybenzoylhydrazone and their thermal stability" in Journal of Thermal Analysis, 46, no. 6 (1996):1741-1750, https://hdl.handle.net/21.15107/rcub_cherry_2249 .