Synthesis and structure of aquamethanol-2',2'''-(2,6-pyridin-diyldiethylidene)-dioxamohydrazidocobalt(II) perchlorate
Apstrakt
The complex [Co(H(2)L)(H2O) (MeOH)](ClO4)(2)[H(2)L] = 2',2triple prime-(2,6-pyridindiyl-diethylidene) -dioxamohydrazide] has been prepared by direct and template syntheses and characterized by elemental analysis, IR spectroscopy, and magnetic susceptibility measurements. The crystal structure of the complex has also been determined. The cobalt atom is seven coordinated with approximately pentagonal-bipyramidal geometry. The H2O and methanol are axial with the planar pentadentate H(2)L ligand forming the equatorial plane. The possible reaction mechanism has been proposed.
Ključne reči:
cobalt(II) complex / 2,6-diacetylpyridine derivative / open chain ligand / crystal structure / pentagonal-bipyramidal geometry / IR spectraIzvor:
Polyhedron, 1996, 15, 24, 4361-4366Izdavač:
- Pergamon-Elsevier Science Ltd, Oxford
DOI: 10.1016/0277-5387(96)00234-3
ISSN: 0277-5387
WoS: A1996VM01700006
Scopus: 2-s2.0-0000316928
Kolekcije
Institucija/grupa
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Anđelković, Katarina K. AU - Ivanović, I. AU - Prelesnik, BV AU - Leovac, Vukadin M. AU - Poleti, D PY - 1996 UR - https://cherry.chem.bg.ac.rs/handle/123456789/2251 AB - The complex [Co(H(2)L)(H2O) (MeOH)](ClO4)(2)[H(2)L] = 2',2triple prime-(2,6-pyridindiyl-diethylidene) -dioxamohydrazide] has been prepared by direct and template syntheses and characterized by elemental analysis, IR spectroscopy, and magnetic susceptibility measurements. The crystal structure of the complex has also been determined. The cobalt atom is seven coordinated with approximately pentagonal-bipyramidal geometry. The H2O and methanol are axial with the planar pentadentate H(2)L ligand forming the equatorial plane. The possible reaction mechanism has been proposed. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - Polyhedron T1 - Synthesis and structure of aquamethanol-2',2'''-(2,6-pyridin-diyldiethylidene)-dioxamohydrazidocobalt(II) perchlorate VL - 15 IS - 24 SP - 4361 EP - 4366 DO - 10.1016/0277-5387(96)00234-3 ER -
@article{ author = "Anđelković, Katarina K. and Ivanović, I. and Prelesnik, BV and Leovac, Vukadin M. and Poleti, D", year = "1996", abstract = "The complex [Co(H(2)L)(H2O) (MeOH)](ClO4)(2)[H(2)L] = 2',2triple prime-(2,6-pyridindiyl-diethylidene) -dioxamohydrazide] has been prepared by direct and template syntheses and characterized by elemental analysis, IR spectroscopy, and magnetic susceptibility measurements. The crystal structure of the complex has also been determined. The cobalt atom is seven coordinated with approximately pentagonal-bipyramidal geometry. The H2O and methanol are axial with the planar pentadentate H(2)L ligand forming the equatorial plane. The possible reaction mechanism has been proposed.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "Polyhedron", title = "Synthesis and structure of aquamethanol-2',2'''-(2,6-pyridin-diyldiethylidene)-dioxamohydrazidocobalt(II) perchlorate", volume = "15", number = "24", pages = "4361-4366", doi = "10.1016/0277-5387(96)00234-3" }
Anđelković, K. K., Ivanović, I., Prelesnik, B., Leovac, V. M.,& Poleti, D.. (1996). Synthesis and structure of aquamethanol-2',2'''-(2,6-pyridin-diyldiethylidene)-dioxamohydrazidocobalt(II) perchlorate. in Polyhedron Pergamon-Elsevier Science Ltd, Oxford., 15(24), 4361-4366. https://doi.org/10.1016/0277-5387(96)00234-3
Anđelković KK, Ivanović I, Prelesnik B, Leovac VM, Poleti D. Synthesis and structure of aquamethanol-2',2'''-(2,6-pyridin-diyldiethylidene)-dioxamohydrazidocobalt(II) perchlorate. in Polyhedron. 1996;15(24):4361-4366. doi:10.1016/0277-5387(96)00234-3 .
Anđelković, Katarina K., Ivanović, I., Prelesnik, BV, Leovac, Vukadin M., Poleti, D, "Synthesis and structure of aquamethanol-2',2'''-(2,6-pyridin-diyldiethylidene)-dioxamohydrazidocobalt(II) perchlorate" in Polyhedron, 15, no. 24 (1996):4361-4366, https://doi.org/10.1016/0277-5387(96)00234-3 . .