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dc.creatorMilenković, Milica R.
dc.creatorShcherbakov, Igor N.
dc.creatorPopov, Leonid D.
dc.creatorLevchenkov, Sergey I.
dc.creatorBorodkin, Sergey A.
dc.creatorAlexandrov, Grigory G.
dc.date.accessioned2018-11-22T00:38:55Z
dc.date.available2018-11-22T00:38:55Z
dc.date.issued2017
dc.identifier.issn0277-5387
dc.identifier.urihttp://cherry.chem.bg.ac.rs/handle/123456789/2368
dc.description.abstractA square-pyramidal Ni(II) complex (1) with the composition [NiL(HL')]CIO4 center dot H2O was synthesized in the reaction of nickel(II) perchlorate and 2[2-(diphenylphosphino)benzylidene]-1-phthalazinylhydrazone (HL). The coordination surrounding the Ni(II) ion consist of a PNN coordinated deprotonated HL ligand and its corresponding oxidation product phosphine oxide HL' coordinated via two nitrogen atoms of the hydrazinophthalazine moiety. The structure of Ni(II) complex 1 was determined by X-ray analysis, IR spectroscopy, elemental analysis and magnetic measurements. In the reaction of copper(II) perchlorate with HL, a binuclear phthalazine bridged Cu(I) complex (2) was obtained with the composition [Cu-2(HL)(2)](ClO4)(2)center dot C2H5OH. The structure of Cu(I) complex 2 was determined by X-ray analysis, IR and NMR spectroscopy, elethental analysis and magnetic measurements.en
dc.publisherPergamon-Elsevier Science Ltd, Oxford
dc.relationSFedU [213.01-07-2014/03PChVG]
dc.rightsrestrictedAccess
dc.sourcePolyhedron
dc.subjectNi(II) complexen
dc.subjectCu(I) complexen
dc.subject2-(Diphenylphosphino)benzaldehydeen
dc.subjectHydralazineen
dc.subjectCrystal structureen
dc.titleSynthesis, characterization and crystal structures of Ni(II) and Cu(I) complexes with the condensation product of 2-(diphenylphosphino) benzaldehyde and 1-hydrazinophthalazineen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractПопов, Леонид Д.; Бородкин, Сергеy A.; Левцхенков, Сергеy И.; Миленковић, Милица; Схцхербаков, Игор Н.; Aлеxандров, Григорy Г.;
dc.citation.volume121
dc.citation.spage278
dc.citation.epage284
dc.identifier.wos000390626200035
dc.identifier.doi10.1016/j.poly.2016.10.020
dc.citation.other121: 278-284
dc.citation.rankM22
dc.description.otherPeer-reviewed manuscript: [http://cherry.chem.bg.ac.rs/handle/123456789/3256]
dc.description.otherSupplementary material: [http://cherry.chem.bg.ac.rs/handle/123456789/3257]
dc.type.versionpublishedVersionen
dc.identifier.scopus2-s2.0-85004019027
dc.identifier.rcubKon_3184


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