A Pd(II) complex with methyl 2-([1-{2,4-dioxochroman-3-ylidene}ethyl]amino)acetate was synthesized. The structures of both the ligand and its Pd(II) complex were determined by elemental analysis, and IR and NMR spectroscopy. Recrystallization of the Pd(II) complex from DMF/water solution resulted in its hydrolysis and the formation of the dimethylamine (2-[{1-(2,4-dioxochroman-3-ylidene) ethyl} amino] acetato) palladium(II) complex, the structure of which was determined by elemental analysis, IR, H-1- and C-13-NMR spectroscopy and X-ray analysis.
Keywords:
coumarin-derived ligands / crystal structure / mechanism of hydrolysis
Source:
Journal of the Serbian Chemical Society, 2016, 81, 12, 1383-1392
TY - JOUR
AU - Stojković, Danijela
AU - Bacchi, Alessia
AU - Capucci, Davide
AU - Milenković, Milica R.
AU - Čobeljić, Božidar
AU - Trifunović, Srećko R.
AU - Anđelković, Katarina K.
AU - Jevtic, Verica V.
AU - Vuković, Nenad L.
AU - Vukic, Milena
AU - Sladić, Dušan
PY - 2016
UR - http://cherry.chem.bg.ac.rs/handle/123456789/2392
AB - A Pd(II) complex with methyl 2-([1-{2,4-dioxochroman-3-ylidene}ethyl]amino)acetate was synthesized. The structures of both the ligand and its Pd(II) complex were determined by elemental analysis, and IR and NMR spectroscopy. Recrystallization of the Pd(II) complex from DMF/water solution resulted in its hydrolysis and the formation of the dimethylamine (2-[{1-(2,4-dioxochroman-3-ylidene) ethyl} amino] acetato) palladium(II) complex, the structure of which was determined by elemental analysis, IR, H-1- and C-13-NMR spectroscopy and X-ray analysis.
PB - Serbian Chemical Soc, Belgrade
T2 - Journal of the Serbian Chemical Society
T1 - Synthesis and characterization of palladium(II) complexes with glycine coumarin derivatives
VL - 81
IS - 12
SP - 1383
EP - 1392
DO - 10.2298/JSC160915087S
ER -
@article{
author = "Stojković, Danijela and Bacchi, Alessia and Capucci, Davide and Milenković, Milica R. and Čobeljić, Božidar and Trifunović, Srećko R. and Anđelković, Katarina K. and Jevtic, Verica V. and Vuković, Nenad L. and Vukic, Milena and Sladić, Dušan",
year = "2016",
url = "http://cherry.chem.bg.ac.rs/handle/123456789/2392",
abstract = "A Pd(II) complex with methyl 2-([1-{2,4-dioxochroman-3-ylidene}ethyl]amino)acetate was synthesized. The structures of both the ligand and its Pd(II) complex were determined by elemental analysis, and IR and NMR spectroscopy. Recrystallization of the Pd(II) complex from DMF/water solution resulted in its hydrolysis and the formation of the dimethylamine (2-[{1-(2,4-dioxochroman-3-ylidene) ethyl} amino] acetato) palladium(II) complex, the structure of which was determined by elemental analysis, IR, H-1- and C-13-NMR spectroscopy and X-ray analysis.",
publisher = "Serbian Chemical Soc, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Synthesis and characterization of palladium(II) complexes with glycine coumarin derivatives",
volume = "81",
number = "12",
pages = "1383-1392",
doi = "10.2298/JSC160915087S"
}
Stojković D, Bacchi A, Capucci D, Milenković MR, Čobeljić B, Trifunović SR, Anđelković KK, Jevtic VV, Vuković NL, Vukic M, Sladić D. Synthesis and characterization of palladium(II) complexes with glycine coumarin derivatives. Journal of the Serbian Chemical Society. 2016;81(12):1383-1392
Stojković, D., Bacchi, A., Capucci, D., Milenković, M. R., Čobeljić, B., Trifunović, S. R., Anđelković, K. K., Jevtic, V. V., Vuković, N. L., Vukic, M.,& Sladić, D. (2016). Synthesis and characterization of palladium(II) complexes with glycine coumarin derivatives.
Journal of the Serbian Chemical SocietySerbian Chemical Soc, Belgrade., 81(12), 1383-1392.
https://doi.org/10.2298/JSC160915087S
Stojković Danijela, Bacchi Alessia, Capucci Davide, Milenković Milica R., Čobeljić Božidar, Trifunović Srećko R., Anđelković Katarina K., Jevtic Verica V., Vuković Nenad L., Vukic Milena, Sladić Dušan, "Synthesis and characterization of palladium(II) complexes with glycine coumarin derivatives" 81, no. 12 (2016):1383-1392,
https://doi.org/10.2298/JSC160915087S .
