Synthesis and characterization of palladium(II) complexes with glycine coumarin derivatives

2016
Authors
Stojković, DanijelaBacchi, Alessia
Capucci, Davide
Milenković, Milica R.

Čobeljić, Božidar

Trifunović, Srećko R.

Anđelković, Katarina K.

Jevtic, Verica V.

Vuković, Nenad L.

Vukic, Milena

Sladić, Dušan

Article (Published version)
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Show full item recordAbstract
A Pd(II) complex with methyl 2-([1-{2,4-dioxochroman-3-ylidene}ethyl]amino)acetate was synthesized. The structures of both the ligand and its Pd(II) complex were determined by elemental analysis, and IR and NMR spectroscopy. Recrystallization of the Pd(II) complex from DMF/water solution resulted in its hydrolysis and the formation of the dimethylamine (2-[{1-(2,4-dioxochroman-3-ylidene) ethyl} amino] acetato) palladium(II) complex, the structure of which was determined by elemental analysis, IR, H-1- and C-13-NMR spectroscopy and X-ray analysis.
Keywords:
coumarin-derived ligands / crystal structure / mechanism of hydrolysisSource:
Journal of the Serbian Chemical Society, 2016, 81, 12, 1383-1392Publisher:
- Serbian Chemical Soc, Belgrade
Projects:
- Interactions of natural products, their derivatives and coordination compounds with proteins and nucleic acids (RS-172055)
- Synthesis, modeling, physicochemical and biological properties of organic compounds and related metal complexes (RS-172016)
Note:
- Supplementary material: http://cherry.chem.bg.ac.rs/handle/123456789/3626
DOI: 10.2298/JSC160915087S
ISSN: 0352-5139
WoS: 000392946100005
Scopus: 2-s2.0-85009841653
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Hemijski fakultetTY - JOUR AU - Stojković, Danijela AU - Bacchi, Alessia AU - Capucci, Davide AU - Milenković, Milica R. AU - Čobeljić, Božidar AU - Trifunović, Srećko R. AU - Anđelković, Katarina K. AU - Jevtic, Verica V. AU - Vuković, Nenad L. AU - Vukic, Milena AU - Sladić, Dušan PY - 2016 UR - http://cherry.chem.bg.ac.rs/handle/123456789/2392 AB - A Pd(II) complex with methyl 2-([1-{2,4-dioxochroman-3-ylidene}ethyl]amino)acetate was synthesized. The structures of both the ligand and its Pd(II) complex were determined by elemental analysis, and IR and NMR spectroscopy. Recrystallization of the Pd(II) complex from DMF/water solution resulted in its hydrolysis and the formation of the dimethylamine (2-[{1-(2,4-dioxochroman-3-ylidene) ethyl} amino] acetato) palladium(II) complex, the structure of which was determined by elemental analysis, IR, H-1- and C-13-NMR spectroscopy and X-ray analysis. PB - Serbian Chemical Soc, Belgrade T2 - Journal of the Serbian Chemical Society T1 - Synthesis and characterization of palladium(II) complexes with glycine coumarin derivatives VL - 81 IS - 12 SP - 1383 EP - 1392 DO - 10.2298/JSC160915087S ER -
@article{ author = "Stojković, Danijela and Bacchi, Alessia and Capucci, Davide and Milenković, Milica R. and Čobeljić, Božidar and Trifunović, Srećko R. and Anđelković, Katarina K. and Jevtic, Verica V. and Vuković, Nenad L. and Vukic, Milena and Sladić, Dušan", year = "2016", url = "http://cherry.chem.bg.ac.rs/handle/123456789/2392", abstract = "A Pd(II) complex with methyl 2-([1-{2,4-dioxochroman-3-ylidene}ethyl]amino)acetate was synthesized. The structures of both the ligand and its Pd(II) complex were determined by elemental analysis, and IR and NMR spectroscopy. Recrystallization of the Pd(II) complex from DMF/water solution resulted in its hydrolysis and the formation of the dimethylamine (2-[{1-(2,4-dioxochroman-3-ylidene) ethyl} amino] acetato) palladium(II) complex, the structure of which was determined by elemental analysis, IR, H-1- and C-13-NMR spectroscopy and X-ray analysis.", publisher = "Serbian Chemical Soc, Belgrade", journal = "Journal of the Serbian Chemical Society", title = "Synthesis and characterization of palladium(II) complexes with glycine coumarin derivatives", volume = "81", number = "12", pages = "1383-1392", doi = "10.2298/JSC160915087S" }
Stojković D, Bacchi A, Capucci D, Milenković MR, Čobeljić B, Trifunović SR, Anđelković KK, Jevtic VV, Vuković NL, Vukic M, Sladić D. Synthesis and characterization of palladium(II) complexes with glycine coumarin derivatives. Journal of the Serbian Chemical Society. 2016;81(12):1383-1392
Stojković, D., Bacchi, A., Capucci, D., Milenković, M. R., Čobeljić, B., Trifunović, S. R., Anđelković, K. K., Jevtic, V. V., Vuković, N. L., Vukic, M.,& Sladić, D. (2016). Synthesis and characterization of palladium(II) complexes with glycine coumarin derivatives. Journal of the Serbian Chemical SocietySerbian Chemical Soc, Belgrade., 81(12), 1383-1392. https://doi.org/10.2298/JSC160915087S
Stojković Danijela, Bacchi Alessia, Capucci Davide, Milenković Milica R., Čobeljić Božidar, Trifunović Srećko R., Anđelković Katarina K., Jevtic Verica V., Vuković Nenad L., Vukic Milena, Sladić Dušan, "Synthesis and characterization of palladium(II) complexes with glycine coumarin derivatives" 81, no. 12 (2016):1383-1392, https://doi.org/10.2298/JSC160915087S .