Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction
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2017
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
We report the first example of a silyl-Negishi reaction between secondary zinc organometallics and silicon electrophiles. This palladium-catalyzed process provides direct access to alkyl silanes. The delicate balance of steric and electronic parameters of the employed DrewPhos ligand is paramount to suppressing isomerization and promoting efficient and selective cross-coupling.
Izvor:
Journal of the American Chemical Society, 2017, 139, 23, 7741-7744Izdavač:
- Amer Chemical Soc, Washington
Finansiranje / projekti:
- NIH [NSF CHE0421224, CHE0840401, CHE1229234, CHE1048367, NIH S10 OD016267-01, S10 RR026962-01, P20GM104316, P30GM110758]
- National Science Foundation [CAREER CHE-1254360]
- Delaware Economic Development Office [16A00384]
- Gelest, Inc. (Topper Grant Program)
- Research Corp. Cottrell Scholars Program
- University of Delaware
Napomena:
- Supplementary material: http://cherry.chem.bg.ac.rs/handle/123456789/3099
DOI: 10.1021/jacs.7b04364
ISSN: 0002-7863
PubMed: 28570065
WoS: 000403631200018
Scopus: 2-s2.0-85020540342
Kolekcije
Institucija/grupa
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Cinderella, Andrew P. AU - Vulović, Bojan AU - Watson, Donald A. PY - 2017 UR - https://cherry.chem.bg.ac.rs/handle/123456789/2475 AB - We report the first example of a silyl-Negishi reaction between secondary zinc organometallics and silicon electrophiles. This palladium-catalyzed process provides direct access to alkyl silanes. The delicate balance of steric and electronic parameters of the employed DrewPhos ligand is paramount to suppressing isomerization and promoting efficient and selective cross-coupling. PB - Amer Chemical Soc, Washington T2 - Journal of the American Chemical Society T1 - Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction VL - 139 IS - 23 SP - 7741 EP - 7744 DO - 10.1021/jacs.7b04364 ER -
@article{ author = "Cinderella, Andrew P. and Vulović, Bojan and Watson, Donald A.", year = "2017", abstract = "We report the first example of a silyl-Negishi reaction between secondary zinc organometallics and silicon electrophiles. This palladium-catalyzed process provides direct access to alkyl silanes. The delicate balance of steric and electronic parameters of the employed DrewPhos ligand is paramount to suppressing isomerization and promoting efficient and selective cross-coupling.", publisher = "Amer Chemical Soc, Washington", journal = "Journal of the American Chemical Society", title = "Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction", volume = "139", number = "23", pages = "7741-7744", doi = "10.1021/jacs.7b04364" }
Cinderella, A. P., Vulović, B.,& Watson, D. A.. (2017). Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction. in Journal of the American Chemical Society Amer Chemical Soc, Washington., 139(23), 7741-7744. https://doi.org/10.1021/jacs.7b04364
Cinderella AP, Vulović B, Watson DA. Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction. in Journal of the American Chemical Society. 2017;139(23):7741-7744. doi:10.1021/jacs.7b04364 .
Cinderella, Andrew P., Vulović, Bojan, Watson, Donald A., "Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction" in Journal of the American Chemical Society, 139, no. 23 (2017):7741-7744, https://doi.org/10.1021/jacs.7b04364 . .