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Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction

dc.creatorCinderella, Andrew P.
dc.creatorVulović, Bojan
dc.creatorWatson, Donald A.
dc.date.accessioned2018-11-22T00:40:23Z
dc.date.available2018-11-22T00:40:23Z
dc.date.issued2017
dc.identifier.issn0002-7863
dc.identifier.urihttps://cherry.chem.bg.ac.rs/handle/123456789/2475
dc.description.abstractWe report the first example of a silyl-Negishi reaction between secondary zinc organometallics and silicon electrophiles. This palladium-catalyzed process provides direct access to alkyl silanes. The delicate balance of steric and electronic parameters of the employed DrewPhos ligand is paramount to suppressing isomerization and promoting efficient and selective cross-coupling.en
dc.publisherAmer Chemical Soc, Washington
dc.relationNIH [NSF CHE0421224, CHE0840401, CHE1229234, CHE1048367, NIH S10 OD016267-01, S10 RR026962-01, P20GM104316, P30GM110758]
dc.relationNational Science Foundation [CAREER CHE-1254360]
dc.relationDelaware Economic Development Office [16A00384]
dc.relationGelest, Inc. (Topper Grant Program)
dc.relationResearch Corp. Cottrell Scholars Program
dc.relationUniversity of Delaware
dc.rightsrestrictedAccess
dc.sourceJournal of the American Chemical Society
dc.titlePalladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reactionen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractЦиндерелла, Aндреw П.; Wатсон, Доналд A.; Вуловић, Бојан;
dc.citation.volume139
dc.citation.issue23
dc.citation.spage7741
dc.citation.epage7744
dc.identifier.wos000403631200018
dc.identifier.doi10.1021/jacs.7b04364
dc.citation.other139(23): 7741-7744
dc.citation.rankaM21
dc.identifier.pmid28570065
dc.description.otherSupplementary material: [http://cherry.chem.bg.ac.rs/handle/123456789/3099]
dc.type.versionpublishedVersionen
dc.identifier.scopus2-s2.0-85020540342


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