Organic geochemical approach in the identification of oil-type pollutants in water and sediment of the River Ibar
2017
Аутори
Milicević, ZoranMarinović, Dragan
Gajica, Gordana
Kašanin-Grubin, Milica
Jovanović, Verka
Jovančićević, Branimir
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
In this paper an applied organic geochemical approach in studying the nature of organic matter (OM) in water and sediments of the River Ibar (upsteream and downstream of towns Kosovska Mitrovica and Kraljevo) was used. A forensic approach that relies on the fact that the composition of OM of recent sediments and oil varies due to geological age and maturity was applied. The content of bitumen, its group composition of saturated, aromatic and NSO compounds (nitrogen, sulphur, and oxygen compounds) and the distribution of n-alkanes in saturated fractions identified by gas chromatography-mass spectrometry (in almost all samples incorporated into the colloidal micelles formed by water and NSO compounds) could not answer the question whether OM in isolated extracts has native or anthropogenic origin. However, the presence of sterane and terpane, with the distribution of structural and stereochemical isomers characteristic of oil, as a form of most matture OM in sediments, unambiguously conf...irmed presence of oil type pollutants in anlayzed samples. Based on significant differences in the distributions of these polycyclic alkane (water-water, sediment-sediment and water-sediment), it was concluded that they have more than one source of pollution, and that the River Ibar is permanently exposed to this form of pollution.
Кључне речи:
petroleum pollutants / biomarkers / urban pollution / environmentИзвор:
Journal of the Serbian Chemical Society, 2017, 82, 5, 593-605Издавач:
- Serbian Chemical Soc, Belgrade
Финансирање / пројекти:
- Геохемијска испитивања седиментних стена - фосилна горива и загађивачи животне средине (RS-MESTD-Basic Research (BR or ON)-176006)
Напомена:
- Supplementary material: http://cherry.chem.bg.ac.rs/handle/123456789/3062
DOI: 10.2298/JSC161129022M
ISSN: 0352-5139
WoS: 000408085400010
Scopus: 2-s2.0-85021700762
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Milicević, Zoran AU - Marinović, Dragan AU - Gajica, Gordana AU - Kašanin-Grubin, Milica AU - Jovanović, Verka AU - Jovančićević, Branimir PY - 2017 UR - https://cherry.chem.bg.ac.rs/handle/123456789/2507 AB - In this paper an applied organic geochemical approach in studying the nature of organic matter (OM) in water and sediments of the River Ibar (upsteream and downstream of towns Kosovska Mitrovica and Kraljevo) was used. A forensic approach that relies on the fact that the composition of OM of recent sediments and oil varies due to geological age and maturity was applied. The content of bitumen, its group composition of saturated, aromatic and NSO compounds (nitrogen, sulphur, and oxygen compounds) and the distribution of n-alkanes in saturated fractions identified by gas chromatography-mass spectrometry (in almost all samples incorporated into the colloidal micelles formed by water and NSO compounds) could not answer the question whether OM in isolated extracts has native or anthropogenic origin. However, the presence of sterane and terpane, with the distribution of structural and stereochemical isomers characteristic of oil, as a form of most matture OM in sediments, unambiguously confirmed presence of oil type pollutants in anlayzed samples. Based on significant differences in the distributions of these polycyclic alkane (water-water, sediment-sediment and water-sediment), it was concluded that they have more than one source of pollution, and that the River Ibar is permanently exposed to this form of pollution. PB - Serbian Chemical Soc, Belgrade T2 - Journal of the Serbian Chemical Society T1 - Organic geochemical approach in the identification of oil-type pollutants in water and sediment of the River Ibar VL - 82 IS - 5 SP - 593 EP - 605 DO - 10.2298/JSC161129022M ER -
@article{ author = "Milicević, Zoran and Marinović, Dragan and Gajica, Gordana and Kašanin-Grubin, Milica and Jovanović, Verka and Jovančićević, Branimir", year = "2017", abstract = "In this paper an applied organic geochemical approach in studying the nature of organic matter (OM) in water and sediments of the River Ibar (upsteream and downstream of towns Kosovska Mitrovica and Kraljevo) was used. A forensic approach that relies on the fact that the composition of OM of recent sediments and oil varies due to geological age and maturity was applied. The content of bitumen, its group composition of saturated, aromatic and NSO compounds (nitrogen, sulphur, and oxygen compounds) and the distribution of n-alkanes in saturated fractions identified by gas chromatography-mass spectrometry (in almost all samples incorporated into the colloidal micelles formed by water and NSO compounds) could not answer the question whether OM in isolated extracts has native or anthropogenic origin. However, the presence of sterane and terpane, with the distribution of structural and stereochemical isomers characteristic of oil, as a form of most matture OM in sediments, unambiguously confirmed presence of oil type pollutants in anlayzed samples. Based on significant differences in the distributions of these polycyclic alkane (water-water, sediment-sediment and water-sediment), it was concluded that they have more than one source of pollution, and that the River Ibar is permanently exposed to this form of pollution.", publisher = "Serbian Chemical Soc, Belgrade", journal = "Journal of the Serbian Chemical Society", title = "Organic geochemical approach in the identification of oil-type pollutants in water and sediment of the River Ibar", volume = "82", number = "5", pages = "593-605", doi = "10.2298/JSC161129022M" }
Milicević, Z., Marinović, D., Gajica, G., Kašanin-Grubin, M., Jovanović, V.,& Jovančićević, B.. (2017). Organic geochemical approach in the identification of oil-type pollutants in water and sediment of the River Ibar. in Journal of the Serbian Chemical Society Serbian Chemical Soc, Belgrade., 82(5), 593-605. https://doi.org/10.2298/JSC161129022M
Milicević Z, Marinović D, Gajica G, Kašanin-Grubin M, Jovanović V, Jovančićević B. Organic geochemical approach in the identification of oil-type pollutants in water and sediment of the River Ibar. in Journal of the Serbian Chemical Society. 2017;82(5):593-605. doi:10.2298/JSC161129022M .
Milicević, Zoran, Marinović, Dragan, Gajica, Gordana, Kašanin-Grubin, Milica, Jovanović, Verka, Jovančićević, Branimir, "Organic geochemical approach in the identification of oil-type pollutants in water and sediment of the River Ibar" in Journal of the Serbian Chemical Society, 82, no. 5 (2017):593-605, https://doi.org/10.2298/JSC161129022M . .