Highly Selective Electrochemical Determination of Phlorizin Using Square Wave Voltammetry at a Boron-Doped Diamond Electrode
Апстракт
A boron-doped diamond electrode was used as an electrochemical sensor for the determination of phlorizin (aka phloridzin, phlorrhizin) using square wave voltammetry (SWV). Phlorizin (Phl) exhibited a well-defined oxidation peak at +0.9 V (versus Ag/AgCl electrode 3 M KCl) in solutions with a pH value of 6.0. Parameters such as pH value and scan rate were optimized for cyclic voltammetry as well as amplitude and frequency for SWV. The sensor gave excellent response with a wide linear dynamic range for concentrations of phlorizin from 3 to 100 mu M with a detection limit of 0.23 mu M and a good repeatability (+/- 0.9%, n = 7 measurements, c = 10 mu M). The effect of interferences by most common compounds was tested, and the method was successfully applied to the determination of the title compound in apple root extracts and urine samples with satisfactory recovery.
Кључне речи:
Boron-doped diamond electrode / Phlorizin / Voltammetric sensor / Apple root extractsИзвор:
Food Analytical Methods, 2017, 10, 11, 3747-3752Издавач:
- Springer, New York
Финансирање / пројекти:
- Примена унапређених оксидационих процеса и наноструктурисаних оксидних материјала за уклањање загађивача из животне средине, развој и оптимизација инструменталних техника за праћење ефикасности (RS-MESTD-Basic Research (BR or ON)-172030)
- Strengthening of the MagBioVin Research and Innovation Team for Development of Novel Approaches for Tumour Therapy based on Nanostructured Materials (EU-FP7-621375)
- Austrian Agency for International Cooperation in Education and Research (OeAD-GmbH), Centre for International Cooperation Mobility (ICM)
- ADA
- University of Graz
Напомена:
- Supplementary material: http://cherry.chem.bg.ac.rs/handle/123456789/3036
DOI: 10.1007/s12161-017-0935-x
ISSN: 1936-9751
WoS: 000412116000027
Scopus: 2-s2.0-85019763374
Колекције
Институција/група
Inovacioni centar / Innovation CentreTY - JOUR AU - Mehmeti, Eda AU - Stanković, Dalibor AU - Ortner, Astrid AU - Zavašnik, Janez AU - Kalcher, Kurt PY - 2017 UR - https://cherry.chem.bg.ac.rs/handle/123456789/2531 AB - A boron-doped diamond electrode was used as an electrochemical sensor for the determination of phlorizin (aka phloridzin, phlorrhizin) using square wave voltammetry (SWV). Phlorizin (Phl) exhibited a well-defined oxidation peak at +0.9 V (versus Ag/AgCl electrode 3 M KCl) in solutions with a pH value of 6.0. Parameters such as pH value and scan rate were optimized for cyclic voltammetry as well as amplitude and frequency for SWV. The sensor gave excellent response with a wide linear dynamic range for concentrations of phlorizin from 3 to 100 mu M with a detection limit of 0.23 mu M and a good repeatability (+/- 0.9%, n = 7 measurements, c = 10 mu M). The effect of interferences by most common compounds was tested, and the method was successfully applied to the determination of the title compound in apple root extracts and urine samples with satisfactory recovery. PB - Springer, New York T2 - Food Analytical Methods T1 - Highly Selective Electrochemical Determination of Phlorizin Using Square Wave Voltammetry at a Boron-Doped Diamond Electrode VL - 10 IS - 11 SP - 3747 EP - 3752 DO - 10.1007/s12161-017-0935-x ER -
@article{ author = "Mehmeti, Eda and Stanković, Dalibor and Ortner, Astrid and Zavašnik, Janez and Kalcher, Kurt", year = "2017", abstract = "A boron-doped diamond electrode was used as an electrochemical sensor for the determination of phlorizin (aka phloridzin, phlorrhizin) using square wave voltammetry (SWV). Phlorizin (Phl) exhibited a well-defined oxidation peak at +0.9 V (versus Ag/AgCl electrode 3 M KCl) in solutions with a pH value of 6.0. Parameters such as pH value and scan rate were optimized for cyclic voltammetry as well as amplitude and frequency for SWV. The sensor gave excellent response with a wide linear dynamic range for concentrations of phlorizin from 3 to 100 mu M with a detection limit of 0.23 mu M and a good repeatability (+/- 0.9%, n = 7 measurements, c = 10 mu M). The effect of interferences by most common compounds was tested, and the method was successfully applied to the determination of the title compound in apple root extracts and urine samples with satisfactory recovery.", publisher = "Springer, New York", journal = "Food Analytical Methods", title = "Highly Selective Electrochemical Determination of Phlorizin Using Square Wave Voltammetry at a Boron-Doped Diamond Electrode", volume = "10", number = "11", pages = "3747-3752", doi = "10.1007/s12161-017-0935-x" }
Mehmeti, E., Stanković, D., Ortner, A., Zavašnik, J.,& Kalcher, K.. (2017). Highly Selective Electrochemical Determination of Phlorizin Using Square Wave Voltammetry at a Boron-Doped Diamond Electrode. in Food Analytical Methods Springer, New York., 10(11), 3747-3752. https://doi.org/10.1007/s12161-017-0935-x
Mehmeti E, Stanković D, Ortner A, Zavašnik J, Kalcher K. Highly Selective Electrochemical Determination of Phlorizin Using Square Wave Voltammetry at a Boron-Doped Diamond Electrode. in Food Analytical Methods. 2017;10(11):3747-3752. doi:10.1007/s12161-017-0935-x .
Mehmeti, Eda, Stanković, Dalibor, Ortner, Astrid, Zavašnik, Janez, Kalcher, Kurt, "Highly Selective Electrochemical Determination of Phlorizin Using Square Wave Voltammetry at a Boron-Doped Diamond Electrode" in Food Analytical Methods, 10, no. 11 (2017):3747-3752, https://doi.org/10.1007/s12161-017-0935-x . .