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Mixed-ligand complexes of cobalt(III) with dithiocarbamates and a cyclic tetradentate secondary amine
dc.creator | Sovilj, Sofija P. | |
dc.creator | Vuković, G | |
dc.creator | Babic, K | |
dc.creator | Sabo, Tibor | |
dc.creator | Macura, S. | |
dc.creator | Juranić, N. | |
dc.date.accessioned | 2018-11-22T00:01:45Z | |
dc.date.available | 2018-11-22T00:01:45Z | |
dc.date.issued | 1997 | |
dc.identifier.issn | 0095-8972 | |
dc.identifier.uri | https://cherry.chem.bg.ac.rs/handle/123456789/2590 | |
dc.description.abstract | 4-Morpholine-, piperidine-, 4-piperazine- and N-methyl- piperazine-dithiocarbamate complexes of Cobalt (III) with 1, 4, 8, 11-tetraazacyclotetradecane, of general formula [Co(Rdtc)cyclam] (ClO4)(2), have been prepared and have been characterized. The complexes adopt cis-octahedral geometry with folded macrocyclic ligand and with the dithiocarbamate bound as a bidentate. trans-influence of the dithiocarbamate ligands was studied by NMR spectroscopy and established the order piperidine-dtc gt 4-morpholine-dtc gt N-methyl-piperazine-dtc. | en |
dc.publisher | Gordon Breach Sci Publ Ltd, Reading | |
dc.rights | restrictedAccess | |
dc.source | Journal of Coordination Chemistry | |
dc.subject | cobalt(III) | en |
dc.subject | macrocycles | en |
dc.subject | dithiocarbamates | en |
dc.subject | synthesis | en |
dc.subject | complexes | en |
dc.title | Mixed-ligand complexes of cobalt(III) with dithiocarbamates and a cyclic tetradentate secondary amine | en |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Јураниц, Н; Вуковиц, Г; Бабиц, К; Совиљ, СП; Мацура, С; Сабо, Тибор; | |
dc.citation.volume | 41 | |
dc.citation.issue | 1-2 | |
dc.citation.spage | 19 | |
dc.citation.epage | 25 | |
dc.identifier.wos | A1997XA90900003 | |
dc.identifier.doi | 10.1080/00958979708027954 | |
dc.citation.other | 41(1-2): 19-25 | |
dc.type.version | publishedVersion | en |
dc.identifier.scopus | 2-s2.0-0002436319 |
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