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dc.creatorSovilj, Sofija P.
dc.creatorVuković, G
dc.creatorBabic, K
dc.creatorSabo, Tibor
dc.creatorMacura, S
dc.creatorJuranic, N
dc.date.accessioned2018-11-22T00:01:45Z
dc.date.available2018-11-22T00:01:45Z
dc.date.issued1997
dc.identifier.issn0095-8972
dc.identifier.urihttp://cherry.chem.bg.ac.rs/handle/123456789/2590
dc.description.abstract4-Morpholine-, piperidine-, 4-piperazine- and N-methyl- piperazine-dithiocarbamate complexes of Cobalt (III) with 1, 4, 8, 11-tetraazacyclotetradecane, of general formula [Co(Rdtc)cyclam] (ClO4)(2), have been prepared and have been characterized. The complexes adopt cis-octahedral geometry with folded macrocyclic ligand and with the dithiocarbamate bound as a bidentate. trans-influence of the dithiocarbamate ligands was studied by NMR spectroscopy and established the order piperidine-dtc gt 4-morpholine-dtc gt N-methyl-piperazine-dtc.en
dc.publisherGordon Breach Sci Publ Ltd, Reading
dc.rightsrestrictedAccess
dc.sourceJournal of Coordination Chemistry
dc.subjectcobalt(III)en
dc.subjectmacrocyclesen
dc.subjectdithiocarbamatesen
dc.subjectsynthesisen
dc.subjectcomplexesen
dc.titleMixed-ligand complexes of cobalt(III) with dithiocarbamates and a cyclic tetradentate secondary amineen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractЈураниц, Н; Вуковиц, Г; Бабиц, К; Совиљ, СП; Мацура, С; Сабо, Тибор;
dc.citation.volume41
dc.citation.issue1-2
dc.citation.spage19
dc.citation.epage25
dc.identifier.wosA1997XA90900003
dc.identifier.doi10.1080/00958979708027954
dc.citation.other41(1-2): 19-25
dc.type.versionpublishedVersionen
dc.identifier.scopus2-s2.0-0002436319
dc.identifier.rcubKon_3593


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