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Synthesis and structural characterization of the Co(III) complex with 2 '-[1-(2-pyridinyl)-ethylidene]oxamohydrazide (Hapsox): The crystal structure of bis-{2 '-[1-(2-pyridinyl)-ethylidene]-oxamohydrazido} cobalt(III) perchlorate, [Co(apsox)(2)]ClO4
(Taylor & Francis Ltd, Abingdon, 2003)
The synthesis of a novel ligand 2'-[1-(2-pyridinyl)-ethylidene]-oxamohydrazide (Hapsox), from a series of 2-acetylpyridine acylhydrazones, and its complex with Co(III), which is the first in this series of complexes are ...
An Fe(III) complex with the dianionic form of 2,6-diacetylpyridine bis(acylhydrazone). The crystal structure of [diaqua-2 ',2 ''-(2,6-pyridinediyldiethylidyne)dioxamo-hydrazide]iron(III) perchlorate trihydrate, [Fe(dapsox)(H2O)(2)]ClO4 center dot 3H(2)O
(Taylor & Francis Ltd, Abingdon, 2002)
The title compound was prepared by a template synthesis from 2,6-diacetylpyridine, dioxamohydrazide and Fe(ClO4)(3) . 6H(2)O (mol ratio 1: 2: 1) in MeOH/H2O (3:1) solution and its structure determined by single-crystal ...
Synthesis, characterization and cytotoxic activity of organoruthenium(II)-halido complexes with 5-chloro-1H-benzimidazole-2-carboxylic acid
(Journal of Coordination Chemistry, 2019)
Three new ruthenium(II)-arene halido complexes, [(η 6 -p-cymene) RuX(L)] (1–3), were synthesized in a reaction of [(η 6 -p-cymene)RuX 2 ] 2 with 5-chloro-1H-benzimidazole-2-carboxylic acid (HL) in ethanol (X – = Cl – (1), ...
Carbon-hydrogen bond activation by a titanium neopentylidene complex
(Taylor & Francis Ltd, Abingdon, 2016)
The titanium neopentylidene complex (PNP)Ti=(CHBu)-Bu-t((CH2Bu)-Bu-t), PNP=N[2-(PPr2)-Pr-i-4-methylphenyl](2)(-), can activate both sp(2) and sp(3) C-H bonds under mild conditions. In this work, we studied the reaction ...
(Electro)chemical and antimicrobial characterization of novel Ru(II) bipyridine complexes with acetylpyridine analogs
(Taylor and Francis, 2022)
Three ruthenium-bipyridine complexes (1–3) carrying acetylpyridine ligand unit were synthesized in methanol via the reaction of [RuCl2(bpy)2] with corresponding acetylpyridine (2-, 3-, and 4-acpy). Obtained complexes were ...
Half-sandwich ruthenium(II)-arene complexes: synthesis, spectroscopic studies, biological properties, and molecular modeling
(Taylor & Francis, 2019)
In search for antitumor metal-based drugs that would mitigate the severe side-effects of cisplatin, Ru(II) complexes are gaining increasing recent interest. In this work, we report on the synthesis, characterization (1H- ...