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Synthesis, characterization and antimicrobial activity of the isothiocyanato Fe(III) Girard’s T hydrazone complex

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2018
0352-51391800079C.pdf (2.579Mb)
Authors
Čobeljić, Božidar
Pevec, Andrej
Jagličić, Zvonko
Milenković, Milica R.
Turel, Iztok
Radanović, Dušanka D.
Milenković, Marina
Anđelković, Katarina K.
Article (Published version)
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Abstract
The isothiocyanato Fe(III) complex with (E)-N,N,N-trimethyl-2-oxo--2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium was synthesized and characterized by elemental analysis, IR spectroscopy and X-ray analysis. The octahedral geometry of the Fe(III) complex consists of the deprotonated form of the hydrazone ligand coordinated through the pyridine nitrogen, azomethine nitrogen and carbonyl oxygen atoms with three isothiocyanato ligands in the remaining coordination places. The measured effective magnetic moment for Fe(III) complex corresponds to high spin Fe(III) ion. The hydrazone ligand and its Fe(III) complex showed lower activity against the tested microbial strains than standard antimicrobial drugs.
Keywords:
Hydrazone / Pseudohalides / X-ray structure, magnetic properties
Source:
Journal of the Serbian Chemical Society, 2018, 83, 12, 1327-1337
Projects:
  • Interactions of natural products, their derivatives and coordination compounds with proteins and nucleic acids (RS-172055)
Note:
  • Supplamantary material: http://cherry.chem.bg.ac.rs/handle/123456789/3307

DOI: 10.2298/JSC180828079C

ISSN: 0352-5139

WoS: 000454508900004

Scopus: 2-s2.0-85059303962
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URI
http://cherry.chem.bg.ac.rs/handle/123456789/2810
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