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Kinetics of NiO and NiCl2 hydrogen reduction as precursors and properties of produced Ni/Al2O3 and Ni-Pd/Al2O3 catalysts

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2015
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Authors
Sokić, M.
Kamberović, Željko
Nikolić, Vladimir
Marković, Bojan D.
Korać, Marija
Anić, Z.
Gavrilovski, Milorad
Article (Published version)
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Abstract
The objects of this investigation were the comparative kinetic analysis of the NiO and NiCl2 reduction by hydrogen during an induction period and elimination of the calcination during the synthesis of Ni/Al2O3 catalysts. The effect of temperature and time on NiO and NiCl2 reduction degrees was studied. Avrami I equation was selected as the most favorable kinetic model and used to determine activation energy of the NiO and NiCl2 reduction for the investigated temperature range (623-923 K) and time intervals (1-5 minutes). The investigation enabled reaching conclusions about the reaction ability and rate of the reduction processes. Afterward, Ni/Al2O3 catalysts were obtained by using oxide and chloride precursor for Ni. The catalysts were supported on alumina-based foam and prepared via aerosol route. Properties of the samples before and after low-temperature hydrogen reduction (633 K) were compared. Obtained results indicated that the synthesis of Ni/Al2O3 catalysts can be more efficien...t if chloride precursor for Ni is directly reduced by hydrogen during the synthesis process, without the calcination step. In addition, Ni-Pd/Al2O3 catalysts with different metal content were prepared by using chloride precursors. Lower reduction temperature was utilized and the chlorides were almost completely reduced at 533 K. © 2015 Miroslav Sokić et al.

Source:
Scientific World Journal, 2015, 2015, 601970-
Funding / projects:
  • Developing technological processes for nonstandard copper concentrates processing with the aim to decrease pollutants emission (RS-34023)
  • Innovative synergy of by-products, waste minimization and clean technologies in metallurgy (RS-34033)

DOI: 10.1155/2015/601970

ISSN: 2356-6140

Scopus: 2-s2.0-84924246784
[ Google Scholar ]
2
URI
https://cherry.chem.bg.ac.rs/handle/123456789/287
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  • Publikacije
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Inovacioni centar
TY  - JOUR
AU  - Sokić, M.
AU  - Kamberović, Željko
AU  - Nikolić, Vladimir
AU  - Marković, Bojan D.
AU  - Korać, Marija
AU  - Anić, Z.
AU  - Gavrilovski, Milorad
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/287
AB  - The objects of this investigation were the comparative kinetic analysis of the NiO and NiCl2 reduction by hydrogen during an induction period and elimination of the calcination during the synthesis of Ni/Al2O3 catalysts. The effect of temperature and time on NiO and NiCl2 reduction degrees was studied. Avrami I equation was selected as the most favorable kinetic model and used to determine activation energy of the NiO and NiCl2 reduction for the investigated temperature range (623-923 K) and time intervals (1-5 minutes). The investigation enabled reaching conclusions about the reaction ability and rate of the reduction processes. Afterward, Ni/Al2O3 catalysts were obtained by using oxide and chloride precursor for Ni. The catalysts were supported on alumina-based foam and prepared via aerosol route. Properties of the samples before and after low-temperature hydrogen reduction (633 K) were compared. Obtained results indicated that the synthesis of Ni/Al2O3 catalysts can be more efficient if chloride precursor for Ni is directly reduced by hydrogen during the synthesis process, without the calcination step. In addition, Ni-Pd/Al2O3 catalysts with different metal content were prepared by using chloride precursors. Lower reduction temperature was utilized and the chlorides were almost completely reduced at 533 K. © 2015 Miroslav Sokić et al.
T2  - Scientific World Journal
T1  - Kinetics of NiO and NiCl2 hydrogen reduction as precursors and properties of produced Ni/Al2O3 and Ni-Pd/Al2O3 catalysts
VL  - 2015
SP  - 601970
DO  - 10.1155/2015/601970
UR  - Kon_1233
ER  - 
@article{
author = "Sokić, M. and Kamberović, Željko and Nikolić, Vladimir and Marković, Bojan D. and Korać, Marija and Anić, Z. and Gavrilovski, Milorad",
year = "2015",
abstract = "The objects of this investigation were the comparative kinetic analysis of the NiO and NiCl2 reduction by hydrogen during an induction period and elimination of the calcination during the synthesis of Ni/Al2O3 catalysts. The effect of temperature and time on NiO and NiCl2 reduction degrees was studied. Avrami I equation was selected as the most favorable kinetic model and used to determine activation energy of the NiO and NiCl2 reduction for the investigated temperature range (623-923 K) and time intervals (1-5 minutes). The investigation enabled reaching conclusions about the reaction ability and rate of the reduction processes. Afterward, Ni/Al2O3 catalysts were obtained by using oxide and chloride precursor for Ni. The catalysts were supported on alumina-based foam and prepared via aerosol route. Properties of the samples before and after low-temperature hydrogen reduction (633 K) were compared. Obtained results indicated that the synthesis of Ni/Al2O3 catalysts can be more efficient if chloride precursor for Ni is directly reduced by hydrogen during the synthesis process, without the calcination step. In addition, Ni-Pd/Al2O3 catalysts with different metal content were prepared by using chloride precursors. Lower reduction temperature was utilized and the chlorides were almost completely reduced at 533 K. © 2015 Miroslav Sokić et al.",
journal = "Scientific World Journal",
title = "Kinetics of NiO and NiCl2 hydrogen reduction as precursors and properties of produced Ni/Al2O3 and Ni-Pd/Al2O3 catalysts",
volume = "2015",
pages = "601970",
doi = "10.1155/2015/601970",
url = "Kon_1233"
}
Sokić, M., Kamberović, Ž., Nikolić, V., Marković, B. D., Korać, M., Anić, Z.,& Gavrilovski, M.. (2015). Kinetics of NiO and NiCl2 hydrogen reduction as precursors and properties of produced Ni/Al2O3 and Ni-Pd/Al2O3 catalysts. in Scientific World Journal, 2015, 601970.
https://doi.org/10.1155/2015/601970
Kon_1233
Sokić M, Kamberović Ž, Nikolić V, Marković BD, Korać M, Anić Z, Gavrilovski M. Kinetics of NiO and NiCl2 hydrogen reduction as precursors and properties of produced Ni/Al2O3 and Ni-Pd/Al2O3 catalysts. in Scientific World Journal. 2015;2015:601970.
doi:10.1155/2015/601970
Kon_1233 .
Sokić, M., Kamberović, Željko, Nikolić, Vladimir, Marković, Bojan D., Korać, Marija, Anić, Z., Gavrilovski, Milorad, "Kinetics of NiO and NiCl2 hydrogen reduction as precursors and properties of produced Ni/Al2O3 and Ni-Pd/Al2O3 catalysts" in Scientific World Journal, 2015 (2015):601970,
https://doi.org/10.1155/2015/601970 .,
Kon_1233 .

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