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Distribution of major and trace elements in the Kovin lignite (Serbia)

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Authors
Životić, Dragana R.
Cvetković, Olga
Vulić, Predrag J.
Gržetić, Ivan
Simić, Vladimir
Ilijević, Konstantin
Dojčinović, Biljana P.
Erić, Suzana
Radić, Bogdan
Stojadinović, Sanja M.
Trifunović, Snežana S.
Article (Published version)
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Abstract
A geochemical and mineralogical study was performed on lignite samples from the Upper Miocene Kovin deposit, hosting three coal seams. The Kovin lignite is characterized by high moisture content, medium to high ash yield, medium to high sulphur content and a relatively low gross and net calorific value. The mineralogical composition, and major and trace element contents were determined by X-ray diffraction, scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS) analyses, and inductively coupled plasma optical emission spectrometry (ICP-OES). The most abundant minerals in all lignite samples from the three coal seams are clays (illite/smectite), silicates (quartz, plagioclase), sulphates (gypsum/anhydrite) and carbonate (calcite). The other iron-rich minerals are sulphides, oxides and hydroxides (pyrite, mag-netite, haematite, and limonite). In general, mineral matter in the matrix coal consists of illite/ smectite and quartz, while xylite-rich coals, apart fro...m illite/smectite, have a higher content of sulphates and Fe-oxide/hydroxide minerals. The lignite from the Kovin deposit is enriched in As, Cd, Co, Cr, Cu, Ga, Li, Mn, Mo, Ni, Pb, V, Zn, Gd, Tb, Er and Lu in comparison with the Clarke values for brown coals. The statistical analysis of bulk compositional data shows inorganic affinity for the majority of the major and trace elements and possible association with pyrite, illite/ smectite and calcite.

Keywords:
Kovin deposit / Lignites / Major and trace elements / Mineral composition
Source:
Geologia Croatica, 2019, 72, 1, 51-79
Publisher:
  • Crossref
Funding / projects:
  • Geochemical investigations of sedimentary rocks - fossil fuels and environmental pollutants (RS-176006)
  • Magmatism and geodynamics of the Balkan Peninsula from Mesozoic to present day: significance for the formation of metallic and non-metallic mineral deposits (RS-176016)
  • Rational design and synthesis of biologically active and coordination compounds and functional materials, relevant for (bio)nanotechnology (RS-172035)

DOI: 10.4154/gc.2019.06

ISSN: 1330-030X

WoS: 000465140000005

Scopus: 2-s2.0-85063438807
[ Google Scholar ]
3
6
URI
https://cherry.chem.bg.ac.rs/handle/123456789/2897
Collections
  • Publikacije
Institution/Community
Hemijski fakultet
TY  - JOUR
AU  - Životić, Dragana R.
AU  - Cvetković, Olga
AU  - Vulić, Predrag J.
AU  - Gržetić, Ivan
AU  - Simić, Vladimir
AU  - Ilijević, Konstantin
AU  - Dojčinović, Biljana P.
AU  - Erić, Suzana
AU  - Radić, Bogdan
AU  - Stojadinović, Sanja M.
AU  - Trifunović, Snežana S.
PY  - 2019
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2897
AB  - A geochemical and mineralogical study was performed on lignite samples from the Upper Miocene Kovin deposit, hosting three coal seams. The Kovin lignite is characterized by high moisture content, medium to high ash yield, medium to high sulphur content and a relatively low gross and net calorific value. The mineralogical composition, and major and trace element contents were determined by X-ray diffraction, scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS) analyses, and inductively coupled plasma optical emission spectrometry (ICP-OES). The most abundant minerals in all lignite samples from the three coal seams are clays (illite/smectite), silicates (quartz, plagioclase), sulphates (gypsum/anhydrite) and carbonate (calcite). The other iron-rich minerals are sulphides, oxides and hydroxides (pyrite, mag-netite, haematite, and limonite). In general, mineral matter in the matrix coal consists of illite/ smectite and quartz, while xylite-rich coals, apart from illite/smectite, have a higher content of sulphates and Fe-oxide/hydroxide minerals. The lignite from the Kovin deposit is enriched in As, Cd, Co, Cr, Cu, Ga, Li, Mn, Mo, Ni, Pb, V, Zn, Gd, Tb, Er and Lu in comparison with the Clarke values for brown coals. The statistical analysis of bulk compositional data shows inorganic affinity for the majority of the major and trace elements and possible association with pyrite, illite/ smectite and calcite.
PB  - Crossref
T2  - Geologia Croatica
T1  - Distribution of major and trace elements in the Kovin lignite (Serbia)
VL  - 72
IS  - 1
SP  - 51
EP  - 79
DO  - 10.4154/gc.2019.06
ER  - 
@article{
author = "Životić, Dragana R. and Cvetković, Olga and Vulić, Predrag J. and Gržetić, Ivan and Simić, Vladimir and Ilijević, Konstantin and Dojčinović, Biljana P. and Erić, Suzana and Radić, Bogdan and Stojadinović, Sanja M. and Trifunović, Snežana S.",
year = "2019, 2019",
abstract = "A geochemical and mineralogical study was performed on lignite samples from the Upper Miocene Kovin deposit, hosting three coal seams. The Kovin lignite is characterized by high moisture content, medium to high ash yield, medium to high sulphur content and a relatively low gross and net calorific value. The mineralogical composition, and major and trace element contents were determined by X-ray diffraction, scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS) analyses, and inductively coupled plasma optical emission spectrometry (ICP-OES). The most abundant minerals in all lignite samples from the three coal seams are clays (illite/smectite), silicates (quartz, plagioclase), sulphates (gypsum/anhydrite) and carbonate (calcite). The other iron-rich minerals are sulphides, oxides and hydroxides (pyrite, mag-netite, haematite, and limonite). In general, mineral matter in the matrix coal consists of illite/ smectite and quartz, while xylite-rich coals, apart from illite/smectite, have a higher content of sulphates and Fe-oxide/hydroxide minerals. The lignite from the Kovin deposit is enriched in As, Cd, Co, Cr, Cu, Ga, Li, Mn, Mo, Ni, Pb, V, Zn, Gd, Tb, Er and Lu in comparison with the Clarke values for brown coals. The statistical analysis of bulk compositional data shows inorganic affinity for the majority of the major and trace elements and possible association with pyrite, illite/ smectite and calcite.",
publisher = "Crossref",
journal = "Geologia Croatica",
title = "Distribution of major and trace elements in the Kovin lignite (Serbia)",
volume = "72",
number = "1",
pages = "51-79",
doi = "10.4154/gc.2019.06"
}
Životić, D. R., Cvetković, O., Vulić, P. J., Gržetić, I., Simić, V., Ilijević, K., Dojčinović, B. P., Erić, S., Radić, B., Stojadinović, S. M.,& Trifunović, S. S.. (2019). Distribution of major and trace elements in the Kovin lignite (Serbia). in Geologia Croatica
Crossref., 72(1), 51-79.
https://doi.org/10.4154/gc.2019.06
Životić DR, Cvetković O, Vulić PJ, Gržetić I, Simić V, Ilijević K, Dojčinović BP, Erić S, Radić B, Stojadinović SM, Trifunović SS. Distribution of major and trace elements in the Kovin lignite (Serbia). in Geologia Croatica. 2019;72(1):51-79.
doi:10.4154/gc.2019.06 .
Životić, Dragana R., Cvetković, Olga, Vulić, Predrag J., Gržetić, Ivan, Simić, Vladimir, Ilijević, Konstantin, Dojčinović, Biljana P., Erić, Suzana, Radić, Bogdan, Stojadinović, Sanja M., Trifunović, Snežana S., "Distribution of major and trace elements in the Kovin lignite (Serbia)" in Geologia Croatica, 72, no. 1 (2019):51-79,
https://doi.org/10.4154/gc.2019.06 . .

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