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dc.creatorRomanović, Mima
dc.creatorČobeljić, Božidar
dc.creatorPevec, Andrej
dc.creatorTurel, Iztok
dc.creatorSpasojević, Vojislav
dc.creatorTsaturyan, Arshak A.
dc.creatorShcherbakov, Igor N.
dc.creatorAnđelković, Katarina K.
dc.creatorMilenković, Marina
dc.creatorRadanović, Dušanka D.
dc.creatorMilenković, Milica R.
dc.date.accessioned2019-06-06T11:48:59Z
dc.date.available2018-02-27
dc.date.issued2017
dc.identifier.issn0277-5387
dc.identifier.urihttps://cherry.chem.bg.ac.rs/handle/123456789/3100
dc.description.abstractA dinuclear double end-on azido bridged KM complex [Ni2L2(mu-(1),(1)-N-3)(2)(N-3)(2)] (1) with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) has been synthesized and characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction, magnetic measurements and DFT studies. In complex 1 intra-dimer ferromagnetic coupling between Ni2+ ions (J= +12.0(2) cm(-1)) and inter-dimer antiferromagnetic interaction (delta = -0.8(3) cm(-1)) were observed. DFT-BS calculations provided explanation of ferromagnetic exchange coupling in complex 1.
dc.publisherPergamon-Elsevier Science Ltd, Oxford
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172055/RS//
dc.relationCOST Action
dc.relationSlovenian Research Agency [P-0175]
dc.relationSFedU [213.01-07-2014/03PChVG]
dc.rightsembargoedAccess
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.sourcePolyhedron
dc.subjectCrystal structure
dc.subjectDFT
dc.subjectHydrazones
dc.subjectMagnetic properties
dc.subjectNi(II) complex
dc.titleSynthesis, crystal structure, magnetic properties and DFT study of dinuclear Ni(II) complex with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent
dc.typearticle
dc.rights.licenseBY-NC-ND
dcterms.abstractПевец, Aндреј; Миленковић, Милица Р. ; Миленковић, Марина; Aнђелковић, Катарина К. ; Турел, Изток; Романовић, Мима Ч.; Чобељић, Божидар ; Спасојевић, Војислав; Тсатурyан, Aрсхак A. ; Схцхербаков, Игор Н.; Радановић, Душанка Д. ;
dc.citation.volume128
dc.citation.spage30
dc.citation.epage37
dc.identifier.wos000401047100005
dc.identifier.doi10.1016/j.poly.2017.02.039
dc.citation.rankM22
dc.description.otherThis is the peer-reviewed version of the following article: Romanović, M. Č.; Čobeljić, B. R.; Pevec, A.; Turel, I.; Spasojević, V.; Tsaturyan, A. A.; Shcherbakov, I. N.; Anđelković, K. K.; Milenković, M.; Radanović, D.; et al. Synthesis, Crystal Structure, Magnetic Properties and DFT Study of Dinuclear Ni(II) Complex with the Condensation Product of 2-Quinolinecarboxaldehyde and Girard’s T Reagent. Polyhedron 2017, 128, 30–37. [https://doi.org/10.1016/j.poly.2017.02.039]
dc.description.otherSupplementary material:[http://cherry.chem.bg.ac.rs/handle/123456789/3101]
dc.type.versionacceptedVersion
dc.identifier.scopus2-s2.0-85015629397
dc.identifier.fulltexthttps://cherry.chem.bg.ac.rs/bitstream/id/7477/10.1016@j.poly.2017.02.039.pdf


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