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dc.creatorNikolić, Stefan
dc.creatorĆirić, Ivanka
dc.creatorRoller, Alexander
dc.creatorLukeš, Vladimir
dc.creatorArion, Vladimir B.
dc.creatorGrgurić-Šipka, Sanja
dc.date.accessioned2019-06-14T11:29:08Z
dc.date.available2018-05-30
dc.date.issued2017
dc.identifier.issn1144-0546
dc.identifier.urihttps://cherry.chem.bg.ac.rs/handle/123456789/3124
dc.description.abstractMono and dinuclear p-cymene-ruthenium(II) complexes [RuCl(L-1)(eta(6)-p-cymene)]Cl, where L-1 is propionic acid hydrazide (1) and [Ru2Cl2(L-2)(eta(6)-p-cymene)2], where H2L2 is N-1,N-2-dipropionylhydrazine (2), were prepared by a reaction of [RuCl2(eta(6)-p-cymene)](2) with the corresponding ligand precursor. Upon the reaction of [RuCl2(eta(6)-p-cymene)](2) with butyric acid hydrazide and pentanoic acid hydrazide in a 1:1 molar ratio in situ formation of tetradentate bridging ligands, N-1,N-2-dibutanoylhydrazine and N1,N2-dipentanoylhydrazine, respectively, occurred and the dinuclear complexes [Ru2Cl2(L-3)(eta(6)-p-cymene)2] (3) and [Ru2Cl2(L-4)(eta(6)-p-cymene)(2)] (4) were isolated. The compounds were characterised by elemental analysis, ESI-mass spectrometry, IR and 1D and 2D NMR spectroscopies. The structures of all complexes were established using single crystal X-ray crystallography. According to these data in both the mono- and dinuclear complexes the ruthenium atoms adopt the usual three-leg piano-stool geometry which is common for this type of complexes. Combining DFT calculations with the characterisation of the final products using X-ray diffraction, a possible reaction mechanism was discussed.
dc.publisherRoyal Soc Chemistry, Cambridge
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172035/RS//
dc.relationinfo:eu-repo/grantAgreement/EC/FP7/256716/EU//
dc.relationAustrian-Serbian mobility grant New potential anticancer drugs based on organoruthenium compounds with organic co-ligands [451-03-01039/2015-09/03, SRB-08/2016-2017]
dc.rightsembargoedAccess
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.sourceNew Journal of Chemistry
dc.titleConversion of hydrazides into: N, N ′-diacylhydrazines in the presence of a ruthenium(II)-arene complex
dc.typearticle
dc.rights.licenseBY-NC-ND
dcterms.abstractНиколић, Стефан; Гргурић-Шипка, Сања; Роллер, Aлеxандер; Лукеш, Владимир; Aрион, Владимир Б.; Ћирић, Иванка;
dc.citation.volume41
dc.citation.issue14
dc.citation.spage6857
dc.citation.epage6865
dc.identifier.wos000405276100093
dc.identifier.doi10.1039/c7nj00965h
dc.citation.rankM22
dc.description.otherThis is the peer-reviewed version of the following article: Nikolić, S.; Ćirić, I.; Roller, A.; Lukeš, V.; Arion, V. B.; Grgurić-Šipka, S. Conversion of Hydrazides into: N, N ′-Diacylhydrazines in the Presence of a Ruthenium(II)-Arene Complex. New Journal of Chemistry 2017, 41 (14), 6857–6865. [https://doi.org/10.1039/c7nj00965h]
dc.description.otherSupplementary material: [http://cherry.chem.bg.ac.rs/handle/123456789/3125]
dc.type.versionacceptedVersion
dc.identifier.scopus2-s2.0-85023167150
dc.identifier.fulltexthttps://cherry.chem.bg.ac.rs/bitstream/id/7594/10.1039@C7NJ00965H.pdf


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