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Conversion of hydrazides into: N, N ′-diacylhydrazines in the presence of a ruthenium(II)-arene complex
dc.creator | Nikolić, Stefan | |
dc.creator | Ćirić, Ivanka | |
dc.creator | Roller, Alexander | |
dc.creator | Lukeš, Vladimir | |
dc.creator | Arion, Vladimir B. | |
dc.creator | Grgurić-Šipka, Sanja | |
dc.date.accessioned | 2019-06-14T11:29:08Z | |
dc.date.available | 2018-05-30 | |
dc.date.issued | 2017 | |
dc.identifier.issn | 1144-0546 | |
dc.identifier.uri | https://cherry.chem.bg.ac.rs/handle/123456789/3124 | |
dc.description.abstract | Mono and dinuclear p-cymene-ruthenium(II) complexes [RuCl(L-1)(eta(6)-p-cymene)]Cl, where L-1 is propionic acid hydrazide (1) and [Ru2Cl2(L-2)(eta(6)-p-cymene)2], where H2L2 is N-1,N-2-dipropionylhydrazine (2), were prepared by a reaction of [RuCl2(eta(6)-p-cymene)](2) with the corresponding ligand precursor. Upon the reaction of [RuCl2(eta(6)-p-cymene)](2) with butyric acid hydrazide and pentanoic acid hydrazide in a 1:1 molar ratio in situ formation of tetradentate bridging ligands, N-1,N-2-dibutanoylhydrazine and N1,N2-dipentanoylhydrazine, respectively, occurred and the dinuclear complexes [Ru2Cl2(L-3)(eta(6)-p-cymene)2] (3) and [Ru2Cl2(L-4)(eta(6)-p-cymene)(2)] (4) were isolated. The compounds were characterised by elemental analysis, ESI-mass spectrometry, IR and 1D and 2D NMR spectroscopies. The structures of all complexes were established using single crystal X-ray crystallography. According to these data in both the mono- and dinuclear complexes the ruthenium atoms adopt the usual three-leg piano-stool geometry which is common for this type of complexes. Combining DFT calculations with the characterisation of the final products using X-ray diffraction, a possible reaction mechanism was discussed. | |
dc.publisher | Royal Soc Chemistry, Cambridge | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172035/RS// | |
dc.relation | info:eu-repo/grantAgreement/EC/FP7/256716/EU// | |
dc.relation | Austrian-Serbian mobility grant New potential anticancer drugs based on organoruthenium compounds with organic co-ligands [451-03-01039/2015-09/03, SRB-08/2016-2017] | |
dc.rights | embargoedAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.source | New Journal of Chemistry | |
dc.title | Conversion of hydrazides into: N, N ′-diacylhydrazines in the presence of a ruthenium(II)-arene complex | |
dc.type | article | |
dc.rights.license | BY-NC-ND | |
dcterms.abstract | Николић, Стефан; Гргурић-Шипка, Сања; Роллер, Aлеxандер; Лукеш, Владимир; Aрион, Владимир Б.; Ћирић, Иванка; | |
dc.citation.volume | 41 | |
dc.citation.issue | 14 | |
dc.citation.spage | 6857 | |
dc.citation.epage | 6865 | |
dc.identifier.wos | 000405276100093 | |
dc.identifier.doi | 10.1039/c7nj00965h | |
dc.citation.rank | M22 | |
dc.description.other | This is the peer-reviewed version of the following article: Nikolić, S.; Ćirić, I.; Roller, A.; Lukeš, V.; Arion, V. B.; Grgurić-Šipka, S. Conversion of Hydrazides into: N, N ′-Diacylhydrazines in the Presence of a Ruthenium(II)-Arene Complex. New Journal of Chemistry 2017, 41 (14), 6857–6865. [https://doi.org/10.1039/c7nj00965h] | |
dc.description.other | Supplementary material: [http://cherry.chem.bg.ac.rs/handle/123456789/3125] | |
dc.type.version | acceptedVersion | |
dc.identifier.scopus | 2-s2.0-85023167150 | |
dc.identifier.fulltext | https://cherry.chem.bg.ac.rs/bitstream/id/7594/10.1039@C7NJ00965H.pdf |