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Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA
dc.creator | Zianna, Ariadni | |
dc.creator | Šumar-Ristović, Maja | |
dc.creator | Psomas, George | |
dc.creator | Hatzidimitriou, Antonis | |
dc.creator | Coutouli-Argyropoulou, Evdoxia | |
dc.creator | Lalia-Kantouri, Maria | |
dc.date.accessioned | 2019-08-29T15:00:33Z | |
dc.date.available | 2016-10-01 | |
dc.date.issued | 2015 | |
dc.identifier.issn | 0095-8972 | |
dc.identifier.uri | https://cherry.chem.bg.ac.rs/handle/123456789/3350 | |
dc.description.abstract | Five Cd( II) complexes with the anion of 5- NO2- salicylaldehydeH ( 5- NO2- saloH) in the absence or presence of the alpha-diimine 1,10- phenanthroline ( phen), 2,2'- dipyridylamine ( dpamH), 2,2'- dipyridine ( bipy), or 2,9- dimethyl- 1,10- phenanthroline ( neoc) were synthesized and characterized as [Cd(5- NO2- salo)(2)(CH3OH)(2)] (1), [Cd(5-NO2- salo)(2)( phen)] center dot 2CH3OH center dot H2O (2), [Cd(5- NO2- salo) 2( dpam.)] (3), [Cd-3(5-NO2- salo)(6)(bipy)(2)] (4), and [ Cd(5-NO2-salo)(neoc)(NO3)](2) (5). Based on spectroscopic results ( IR, UV, NMR), elemental analysis and conductivity measurements an octahedral geometry around cadmium metal ion is suggested, with the 5- NO2- salicylaldehyde ligand having different coordination modes. The structures determined by X-ray crystallography verified neutral mononuclear 1-3 and trinuclear 4. Simultaneous TG/DTG-DTA technique was used to analyze the thermal behavior of 1, 2, and 3. The complexes bind tightly to calf-thymus DNA mainly by intercalation, as concluded by DNA viscosity measurements and exhibit significant displacement of EB from the EB- DNA complex. | en |
dc.publisher | Taylor & Francis Ltd, Abingdon | |
dc.relation | Aristotle University of Thessaloniki | |
dc.rights | embargoedAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.source | Journal of Coordination Chemistry | |
dc.subject | Cadmium(II) complexes | en |
dc.subject | Crystal structure | en |
dc.subject | Interaction with DNA | en |
dc.title | Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA | en |
dc.type | article | |
dc.rights.license | BY-NC-ND | |
dcterms.abstract | Зианна, Aриадни; Шумар-Ристовић, Маја; Псомас, Георге; Хатзидимитриоу, Aнтонис; Цоутоули-Aргyропоулоу, Евдоxиа; Лалиа-Кантоури, Мариа; | |
dc.citation.volume | 68 | |
dc.citation.issue | 24 | |
dc.citation.spage | 4444 | |
dc.citation.epage | 4463 | |
dc.identifier.wos | 000365654700012 | |
dc.identifier.doi | 10.1080/00958972.2015.1101075 | |
dc.citation.rank | M23 | |
dc.description.other | This is the peer-reviewed version of the following article: Zianna, A.; Sumar Ristovic, M.; Psomas, G.; Hatzidimitriou, A.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Cadmium(II) Complexes of 5-Nitro-Salicylaldehyde and α -Diimines: Synthesis, Structure and Interaction with Calf-Thymus DNA. Journal of Coordination Chemistry 2015, 68 (24), 4444–4463. [https://doi.org/10.1080/00958972.2015.1101075] | |
dc.description.other | Supplementary material: [http://cherry.chem.bg.ac.rs/handle/123456789/3351] | |
dc.type.version | acceptedVersion | en |
dc.identifier.scopus | 2-s2.0-84948415680 | |
dc.identifier.fulltext | https://cherry.chem.bg.ac.rs/bitstream/id/14647/Cadmium(II)_complexes_of_acc-2015.pdf |