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Sensitive voltammetric determination of thymol in essential oil of Carum copticum seeds using boron-doped diamond electrode
dc.creator | Stanković, Dalibor | |
dc.date.accessioned | 2019-09-12T09:51:33Z | |
dc.date.available | 2016-06-18 | |
dc.date.issued | 2015 | |
dc.identifier.issn | 0003-2697 | |
dc.identifier.uri | https://cherry.chem.bg.ac.rs/handle/123456789/3418 | |
dc.description.abstract | Essential oil of Carum copticum seeds, obtained from a local shop, was extracted and content of thymol was analyzed using square-wave voltammetry at boron-doped diamond electrode. The effect of various parameters, such as pH of supporting electrolyte and square-wave voltammetric parameters (modulation amplitude and frequency), was examined. In Britton-Robinson buffer solution (pH 4), thymol provided a single and oval-shaped irreversible oxidation peak at +1.13 V versus silver/silver chloride potassium electrode (3 M). Under optimal experimental conditions, a plot of peak height against concentration of thymol was found to be linear over the range of 4 to 100 mu M consisting of two linear ranges: from 4 to 20 mu M (R-2 = 0.9964) and from 20 to 100 mu M (R-2 = 0.9993). The effect of potential interferences such as p-cymene and gamma-terpinene (major components in essential oil of C copticum seeds) was evaluated. Thus, the proposed method displays a sufficient selectivity toward thymol with a detection limit of 3.9 mu M, and it was successfully applied for the determination of thymol in essential oil of C copticum seeds. The Prussian blue method was used for validation of the proposed electroanalytical method. | en |
dc.publisher | Academic Press Inc Elsevier Science, San Diego | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172030/RS// | |
dc.rights | embargoedAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.source | Analytical Biochemistry | |
dc.subject | Carum copticum seeds | en |
dc.subject | Thymol | en |
dc.subject | Boron-doped diamond electrode | en |
dc.title | Sensitive voltammetric determination of thymol in essential oil of Carum copticum seeds using boron-doped diamond electrode | en |
dc.type | article | |
dc.rights.license | BY-NC-ND | |
dcterms.abstract | Станковић, Далибор; | |
dc.citation.volume | 486 | |
dc.citation.spage | 1 | |
dc.citation.epage | 4 | |
dc.identifier.wos | 000359881000001 | |
dc.identifier.doi | 10.1016/j.ab.2015.06.026 | |
dc.citation.other | 486: 1-4 | |
dc.citation.rank | M22 | |
dc.identifier.pmid | 26119334 | |
dc.description.other | This is the peer-reviewed version of the following article: Stanković, D. M. Sensitive Voltammetric Determination of Thymol in Essential Oil of Carum Copticum Seeds Using Boron-Doped Diamond Electrode. Analytical Biochemistry 2015, 486, 1–4. [https://doi.org/10.1016/j.ab.2015.06.026] | |
dc.type.version | acceptedVersion | en |
dc.identifier.scopus | 2-s2.0-84937543217 | |
dc.identifier.fulltext | https://cherry.chem.bg.ac.rs/bitstream/id/14933/Sensitive_voltammetric_determination_acc_2015.pdf |