Syntheses and characterization of 2-acetylpyridine-aminoguanidine and its copper(II) complexes: Crystallographic and antimicrobial study
Autori
Vojinović-Ješić, Ljiljana S.Radanović, Mirjana M.
Rodić, Marko
Živković-Radovanović, Vukosava
Jovanović, Ljiljana S.
Leovac, Vukadin M.
Članak u časopisu (Recenzirana verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
The syntheses, physico-chemical and microbiological properties of the ligand, 2-acetylpyridine-aminoguanidine dihydrogensulfate monohydrate and its five complexes with Cu(II) are described. The compounds were characterized by single crystal X-ray crystallography. Common fragments encountered in some of the structures were compared by r.m.s. overlay calculations as well as half-normal probability plots. In these complexes the chelate ligand is coordinated in its neutral form in a tridentate N-3-coordination mode, via pyridine, azomethine and imino nitrogen atoms of the aminoguanidine fragment. In these complexes the Cu(II) ion is situated in moderately or severely distorted square-pyramidal surroundings. The antimicrobial activity of the ligand and the complexes were examined against 6 selected bacterial and 3 fungal strains.
Ključne reči:
2-Acetylpyridine-aminoguanidine / Copper(II) complexes / Crystal structure / Spectra / Antimicrobial activityIzvor:
Polyhedron, 2016, 117, 526-534Izdavač:
- Pergamon-Elsevier Science Ltd, Oxford
Finansiranje / projekti:
- Dizajniranje, sinteza, karakterizacija i procena praktične primene koordinacionih i organometalnih jedinjenja (RS-MESTD-Basic Research (BR or ON)-172014)
Napomena:
- This is peer-reviewed version of the following article: Vojinović-Ješić, L. S.; Radanović, M. M.; Rodić, M. V.; Živković-Radovanović, V.; Jovanović, L. S.; Leovac, V. M. Syntheses and Characterization of 2-Acetylpyridine-Aminoguanidine and Its Copper(II) Complexes: Crystallographic and Antimicrobial Study. Polyhedron 2016, 117, 526–534. https://doi.org/10.1016/j.poly.2016.06.032
- Supplementary material: http://cherry.chem.bg.ac.rs/handle/123456789/3583
DOI: 10.1016/j.poly.2016.06.032
ISSN: 0277-5387
WoS: 000384384500062
Scopus: 2-s2.0-84978388851
Kolekcije
Institucija/grupa
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Vojinović-Ješić, Ljiljana S. AU - Radanović, Mirjana M. AU - Rodić, Marko AU - Živković-Radovanović, Vukosava AU - Jovanović, Ljiljana S. AU - Leovac, Vukadin M. PY - 2016 UR - https://cherry.chem.bg.ac.rs/handle/123456789/3580 AB - The syntheses, physico-chemical and microbiological properties of the ligand, 2-acetylpyridine-aminoguanidine dihydrogensulfate monohydrate and its five complexes with Cu(II) are described. The compounds were characterized by single crystal X-ray crystallography. Common fragments encountered in some of the structures were compared by r.m.s. overlay calculations as well as half-normal probability plots. In these complexes the chelate ligand is coordinated in its neutral form in a tridentate N-3-coordination mode, via pyridine, azomethine and imino nitrogen atoms of the aminoguanidine fragment. In these complexes the Cu(II) ion is situated in moderately or severely distorted square-pyramidal surroundings. The antimicrobial activity of the ligand and the complexes were examined against 6 selected bacterial and 3 fungal strains. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - Polyhedron T1 - Syntheses and characterization of 2-acetylpyridine-aminoguanidine and its copper(II) complexes: Crystallographic and antimicrobial study VL - 117 SP - 526 EP - 534 DO - 10.1016/j.poly.2016.06.032 ER -
@article{ author = "Vojinović-Ješić, Ljiljana S. and Radanović, Mirjana M. and Rodić, Marko and Živković-Radovanović, Vukosava and Jovanović, Ljiljana S. and Leovac, Vukadin M.", year = "2016", abstract = "The syntheses, physico-chemical and microbiological properties of the ligand, 2-acetylpyridine-aminoguanidine dihydrogensulfate monohydrate and its five complexes with Cu(II) are described. The compounds were characterized by single crystal X-ray crystallography. Common fragments encountered in some of the structures were compared by r.m.s. overlay calculations as well as half-normal probability plots. In these complexes the chelate ligand is coordinated in its neutral form in a tridentate N-3-coordination mode, via pyridine, azomethine and imino nitrogen atoms of the aminoguanidine fragment. In these complexes the Cu(II) ion is situated in moderately or severely distorted square-pyramidal surroundings. The antimicrobial activity of the ligand and the complexes were examined against 6 selected bacterial and 3 fungal strains.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "Polyhedron", title = "Syntheses and characterization of 2-acetylpyridine-aminoguanidine and its copper(II) complexes: Crystallographic and antimicrobial study", volume = "117", pages = "526-534", doi = "10.1016/j.poly.2016.06.032" }
Vojinović-Ješić, L. S., Radanović, M. M., Rodić, M., Živković-Radovanović, V., Jovanović, L. S.,& Leovac, V. M.. (2016). Syntheses and characterization of 2-acetylpyridine-aminoguanidine and its copper(II) complexes: Crystallographic and antimicrobial study. in Polyhedron Pergamon-Elsevier Science Ltd, Oxford., 117, 526-534. https://doi.org/10.1016/j.poly.2016.06.032
Vojinović-Ješić LS, Radanović MM, Rodić M, Živković-Radovanović V, Jovanović LS, Leovac VM. Syntheses and characterization of 2-acetylpyridine-aminoguanidine and its copper(II) complexes: Crystallographic and antimicrobial study. in Polyhedron. 2016;117:526-534. doi:10.1016/j.poly.2016.06.032 .
Vojinović-Ješić, Ljiljana S., Radanović, Mirjana M., Rodić, Marko, Živković-Radovanović, Vukosava, Jovanović, Ljiljana S., Leovac, Vukadin M., "Syntheses and characterization of 2-acetylpyridine-aminoguanidine and its copper(II) complexes: Crystallographic and antimicrobial study" in Polyhedron, 117 (2016):526-534, https://doi.org/10.1016/j.poly.2016.06.032 . .