Faculty of Chemistry Repository - Cherry
University of Belgrade - Faculty of Chemistry
    • English
    • Српски
    • Српски (Serbia)
  • English 
    • English
    • Serbian (Cyrillic)
    • Serbian (Latin)
  • Login
View Item 
  •   Cherry
  • Hemijski fakultet
  • Publikacije
  • View Item
  •   Cherry
  • Hemijski fakultet
  • Publikacije
  • View Item
JavaScript is disabled for your browser. Some features of this site may not work without it.

Geochemical fractionation and assessment of probabilistic ecological risk of potential toxic elements in sediments using Monte Carlo simulations

Thumbnail
2019
Geochemical_Fractionation_and_pub_2019.pdf (3.163Mb)
Authors
Sakan, Sanja M.
Sakan, Nenad
Popović, Aleksandar R.
Škrivanj, Sandra B.
Đorđević, Dragana S.
Article (Published version)
Metadata
Show full item record
Abstract
The need for further research into potentially toxic elements in Serbian rivers led to an investigation of distributions, sources, and ecological risks in a sample base of sediments from 15 rivers. The analyses were carried out through both experimental and theoretical methods. Geochemical fractionation of Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, As, V, and Zn in sediments was studied using a sequential extraction procedure. Both a Håkanson risk index (RI) and a Monte Carlo simulation (MCS) were used in order to estimate ecological risk, applying the probability distribution of RI values instead of single-point calculations. In order to both further the development of the used method and include additional processes, software for the simulations was developed instead of using proprietary solutions. Metal fractionation showed high percentage recoveries of Cd, Cr, Co, Cu, Fe, Ni, and V in residual fractions. The high content of Pb, Mn, and Zn in mobile fractions might cause serious environmental ...concerns. In some localities, Cu and Cd could be problematic elements, since their mobility was high. An environmental assessment based on the described criteria provided risk levels varying from low to median (mainly contributed by Cd and Cu).

Keywords:
Monte Carlo simulation / Geochemical fractionation / Hierarchical clustering / Probabilistic ecological risk / Sediments / Toxic elements
Source:
Molecules, 2019, 24, 11
Publisher:
  • MDPI
Funding / projects:
  • The study of physicochemical and biochemical processes in living environment that have impacts on pollution and the investigation of possibilities for minimizing the consequences (RS-172001)

DOI: 10.3390/molecules24112145

ISSN: 1420-3049

WoS: 000472631000118

Scopus: 2-s2.0-85066730412
[ Google Scholar ]
3
2
URI
https://cherry.chem.bg.ac.rs/handle/123456789/3707
Collections
  • Publikacije
Institution/Community
Hemijski fakultet
TY  - JOUR
AU  - Sakan, Sanja M.
AU  - Sakan, Nenad
AU  - Popović, Aleksandar R.
AU  - Škrivanj, Sandra B.
AU  - Đorđević, Dragana S.
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3707
AB  - The need for further research into potentially toxic elements in Serbian rivers led to an investigation of distributions, sources, and ecological risks in a sample base of sediments from 15 rivers. The analyses were carried out through both experimental and theoretical methods. Geochemical fractionation of Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, As, V, and Zn in sediments was studied using a sequential extraction procedure. Both a Håkanson risk index (RI) and a Monte Carlo simulation (MCS) were used in order to estimate ecological risk, applying the probability distribution of RI values instead of single-point calculations. In order to both further the development of the used method and include additional processes, software for the simulations was developed instead of using proprietary solutions. Metal fractionation showed high percentage recoveries of Cd, Cr, Co, Cu, Fe, Ni, and V in residual fractions. The high content of Pb, Mn, and Zn in mobile fractions might cause serious environmental concerns. In some localities, Cu and Cd could be problematic elements, since their mobility was high. An environmental assessment based on the described criteria provided risk levels varying from low to median (mainly contributed by Cd and Cu).
PB  - MDPI
T2  - Molecules
T1  - Geochemical fractionation and assessment of probabilistic ecological risk of potential toxic elements in sediments using Monte Carlo simulations
VL  - 24
IS  - 11
DO  - 10.3390/molecules24112145
ER  - 
@article{
author = "Sakan, Sanja M. and Sakan, Nenad and Popović, Aleksandar R. and Škrivanj, Sandra B. and Đorđević, Dragana S.",
year = "2019",
abstract = "The need for further research into potentially toxic elements in Serbian rivers led to an investigation of distributions, sources, and ecological risks in a sample base of sediments from 15 rivers. The analyses were carried out through both experimental and theoretical methods. Geochemical fractionation of Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, As, V, and Zn in sediments was studied using a sequential extraction procedure. Both a Håkanson risk index (RI) and a Monte Carlo simulation (MCS) were used in order to estimate ecological risk, applying the probability distribution of RI values instead of single-point calculations. In order to both further the development of the used method and include additional processes, software for the simulations was developed instead of using proprietary solutions. Metal fractionation showed high percentage recoveries of Cd, Cr, Co, Cu, Fe, Ni, and V in residual fractions. The high content of Pb, Mn, and Zn in mobile fractions might cause serious environmental concerns. In some localities, Cu and Cd could be problematic elements, since their mobility was high. An environmental assessment based on the described criteria provided risk levels varying from low to median (mainly contributed by Cd and Cu).",
publisher = "MDPI",
journal = "Molecules",
title = "Geochemical fractionation and assessment of probabilistic ecological risk of potential toxic elements in sediments using Monte Carlo simulations",
volume = "24",
number = "11",
doi = "10.3390/molecules24112145"
}
Sakan, S. M., Sakan, N., Popović, A. R., Škrivanj, S. B.,& Đorđević, D. S.. (2019). Geochemical fractionation and assessment of probabilistic ecological risk of potential toxic elements in sediments using Monte Carlo simulations. in Molecules
MDPI., 24(11).
https://doi.org/10.3390/molecules24112145
Sakan SM, Sakan N, Popović AR, Škrivanj SB, Đorđević DS. Geochemical fractionation and assessment of probabilistic ecological risk of potential toxic elements in sediments using Monte Carlo simulations. in Molecules. 2019;24(11).
doi:10.3390/molecules24112145 .
Sakan, Sanja M., Sakan, Nenad, Popović, Aleksandar R., Škrivanj, Sandra B., Đorđević, Dragana S., "Geochemical fractionation and assessment of probabilistic ecological risk of potential toxic elements in sediments using Monte Carlo simulations" in Molecules, 24, no. 11 (2019),
https://doi.org/10.3390/molecules24112145 . .

DSpace software copyright © 2002-2015  DuraSpace
About CHERRY - CHEmistry RepositoRY | Send Feedback

re3dataOpenAIRERCUB
 

 

All of DSpaceInstitutions/communitiesAuthorsTitlesSubjectsThis institutionAuthorsTitlesSubjects

Statistics

View Usage Statistics

DSpace software copyright © 2002-2015  DuraSpace
About CHERRY - CHEmistry RepositoRY | Send Feedback

re3dataOpenAIRERCUB