The preparation and characterization of facial and meridional isomers of uns-cis-(ethylenediamine-N,N '-di-3-propionato)cobalt(III) complexes with aliphatic alpha-S-amino acids
Abstract
A series of several complex compounds, both facial and meridional, of uns-cis-(ethylenediamine-N,N'-di-3-propionato)cobalt(III) complexes with some alpha-S-amino acids, S-alanine, S-valine, S-leucine and S-isoleucine, were prepared by the reaction of sodium uns-cis-(ethylenediamine-N,N'-di-3-propionato)(carbonato)cobaltate(III)dihydrate and the corresponding amino acid at 70 degrees C. The complexes were isolated chromatographically and characterized by elemental analysis, as well as electron absorption and infrared spectroscopy.
Keywords:
cobalt(III) complexes / ethylenediamine-N,N '-di-3-propionic acid / S-amino acidSource:
Journal of the Serbian Chemical Society, 1998, 63, 8, 669-675Publisher:
- Serbian Chemical Soc, Belgrade
Collections
Institution/Community
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Grgurić-Šipka, Sanja AU - Trifunović, Srećko R. AU - Sabo, Tibor PY - 1998 UR - https://cherry.chem.bg.ac.rs/handle/123456789/392 AB - A series of several complex compounds, both facial and meridional, of uns-cis-(ethylenediamine-N,N'-di-3-propionato)cobalt(III) complexes with some alpha-S-amino acids, S-alanine, S-valine, S-leucine and S-isoleucine, were prepared by the reaction of sodium uns-cis-(ethylenediamine-N,N'-di-3-propionato)(carbonato)cobaltate(III)dihydrate and the corresponding amino acid at 70 degrees C. The complexes were isolated chromatographically and characterized by elemental analysis, as well as electron absorption and infrared spectroscopy. PB - Serbian Chemical Soc, Belgrade T2 - Journal of the Serbian Chemical Society T1 - The preparation and characterization of facial and meridional isomers of uns-cis-(ethylenediamine-N,N '-di-3-propionato)cobalt(III) complexes with aliphatic alpha-S-amino acids VL - 63 IS - 8 SP - 669 EP - 675 UR - https://hdl.handle.net/21.15107/rcub_cherry_392 ER -
@article{ author = "Grgurić-Šipka, Sanja and Trifunović, Srećko R. and Sabo, Tibor", year = "1998", abstract = "A series of several complex compounds, both facial and meridional, of uns-cis-(ethylenediamine-N,N'-di-3-propionato)cobalt(III) complexes with some alpha-S-amino acids, S-alanine, S-valine, S-leucine and S-isoleucine, were prepared by the reaction of sodium uns-cis-(ethylenediamine-N,N'-di-3-propionato)(carbonato)cobaltate(III)dihydrate and the corresponding amino acid at 70 degrees C. The complexes were isolated chromatographically and characterized by elemental analysis, as well as electron absorption and infrared spectroscopy.", publisher = "Serbian Chemical Soc, Belgrade", journal = "Journal of the Serbian Chemical Society", title = "The preparation and characterization of facial and meridional isomers of uns-cis-(ethylenediamine-N,N '-di-3-propionato)cobalt(III) complexes with aliphatic alpha-S-amino acids", volume = "63", number = "8", pages = "669-675", url = "https://hdl.handle.net/21.15107/rcub_cherry_392" }
Grgurić-Šipka, S., Trifunović, S. R.,& Sabo, T.. (1998). The preparation and characterization of facial and meridional isomers of uns-cis-(ethylenediamine-N,N '-di-3-propionato)cobalt(III) complexes with aliphatic alpha-S-amino acids. in Journal of the Serbian Chemical Society Serbian Chemical Soc, Belgrade., 63(8), 669-675. https://hdl.handle.net/21.15107/rcub_cherry_392
Grgurić-Šipka S, Trifunović SR, Sabo T. The preparation and characterization of facial and meridional isomers of uns-cis-(ethylenediamine-N,N '-di-3-propionato)cobalt(III) complexes with aliphatic alpha-S-amino acids. in Journal of the Serbian Chemical Society. 1998;63(8):669-675. https://hdl.handle.net/21.15107/rcub_cherry_392 .
Grgurić-Šipka, Sanja, Trifunović, Srećko R., Sabo, Tibor, "The preparation and characterization of facial and meridional isomers of uns-cis-(ethylenediamine-N,N '-di-3-propionato)cobalt(III) complexes with aliphatic alpha-S-amino acids" in Journal of the Serbian Chemical Society, 63, no. 8 (1998):669-675, https://hdl.handle.net/21.15107/rcub_cherry_392 .