Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus

Wild, Stefan; Fickert, Michael; Mitrović, Aleksandra D.; Lloret, Vicent; Neiss, Christian; Vidal‐Moya, Jose Alejandro; Rivero‐Crespo, Miguel Angel; Leyva‐Pérez, Antonio; Werbach, Katharina; Peterlik, Herwig; Grabau, Mathias; Wittkämper, Haiko; Papp, Christian; Steinrück, Hans-Peter; Pichler, Thomas; Görling, Andreas; Hauke, Frank; Abellán, Gonzalo; Hirsch, Andreas

doi:10.1002/anie.201811181

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2019

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Abstract

The chemical bulk reductive covalent functionalization of thin‐layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes

Keywords:

31P NMR spectroscopy / black phosphorus / covalent functionalization / Raman spectroscopy / reductive route

Source:
Angewandte Chemie International Edition, 2019, 58, 17, 5763-5768

Publisher:

Wiley

Funding / projects:

European Research Council (ERC Advanced Grant 742145 B-PhosphoChem to A.H., and ERC Starting Grant 2D-PnictoChem 804110 to G.A.).
European Union Seventh Framework Programme under grant agreement No. 604391 Graphene Flagship.
Тhe Postdoctoral Junior Leader Fellowship Programme from “la Caixa” Banking Foundation (LCF/BQ/PI18/11630018).
Тhe Deutsche Forschungsgemeinschaft (DFG; FLAGERA AB694/2-1).
Generalitat Valenciana (SEJI/2018/034 grant).
FAU (Emerging Talents Initiative grant #WS16-17_Nat_04).
SFB 953 “Synthetic Carbon Allotropes” funded by the DFG.
Cluster of Excellence “Engineering of Advanced Materials”.
Free State of Bavaria (Research Network “Solar Technologies go Hybrid”).
Alexander von Humboldt (AvH) Foundation for a postdoctoral fellowship.
This work was supported by the MINECO (Spain) through the Excellence Unit Mar&a de Maeztu (MDM-2015-0538) and the Project CTQ2017-86735-P.

DOI: 10.1002/anie.201811181

ISSN: 1433-7851

WoS: 000466593400049

Scopus: 2-s2.0-85063260069

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TY  - JOUR
AU  - Wild, Stefan
AU  - Fickert, Michael
AU  - Mitrović, Aleksandra D.
AU  - Lloret, Vicent
AU  - Neiss, Christian
AU  - Vidal‐Moya, Jose Alejandro
AU  - Rivero‐Crespo, Miguel Angel
AU  - Leyva‐Pérez, Antonio
AU  - Werbach, Katharina
AU  - Peterlik, Herwig
AU  - Grabau, Mathias
AU  - Wittkämper, Haiko
AU  - Papp, Christian
AU  - Steinrück, Hans-Peter
AU  - Pichler, Thomas
AU  - Görling, Andreas
AU  - Hauke, Frank
AU  - Abellán, Gonzalo
AU  - Hirsch, Andreas
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3936
AB  - The chemical bulk reductive covalent functionalization of thin‐layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes
PB  - Wiley
T2  - Angewandte Chemie International Edition
T1  - Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus
VL  - 58
IS  - 17
SP  - 5763
EP  - 5768
DO  - 10.1002/anie.201811181
ER  -

@article{
author = "Wild, Stefan and Fickert, Michael and Mitrović, Aleksandra D. and Lloret, Vicent and Neiss, Christian and Vidal‐Moya, Jose Alejandro and Rivero‐Crespo, Miguel Angel and Leyva‐Pérez, Antonio and Werbach, Katharina and Peterlik, Herwig and Grabau, Mathias and Wittkämper, Haiko and Papp, Christian and Steinrück, Hans-Peter and Pichler, Thomas and Görling, Andreas and Hauke, Frank and Abellán, Gonzalo and Hirsch, Andreas",
year = "2019",
abstract = "The chemical bulk reductive covalent functionalization of thin‐layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes",
publisher = "Wiley",
journal = "Angewandte Chemie International Edition",
title = "Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus",
volume = "58",
number = "17",
pages = "5763-5768",
doi = "10.1002/anie.201811181"
}

Wild, S., Fickert, M., Mitrović, A. D., Lloret, V., Neiss, C., Vidal‐Moya, J. A., Rivero‐Crespo, M. A., Leyva‐Pérez, A., Werbach, K., Peterlik, H., Grabau, M., Wittkämper, H., Papp, C., Steinrück, H., Pichler, T., Görling, A., Hauke, F., Abellán, G.,& Hirsch, A.. (2019). Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus. in Angewandte Chemie International Edition
Wiley., 58(17), 5763-5768.
https://doi.org/10.1002/anie.201811181

Wild S, Fickert M, Mitrović AD, Lloret V, Neiss C, Vidal‐Moya JA, Rivero‐Crespo MA, Leyva‐Pérez A, Werbach K, Peterlik H, Grabau M, Wittkämper H, Papp C, Steinrück H, Pichler T, Görling A, Hauke F, Abellán G, Hirsch A. Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus. in Angewandte Chemie International Edition. 2019;58(17):5763-5768.
doi:10.1002/anie.201811181 .

Wild, Stefan, Fickert, Michael, Mitrović, Aleksandra D., Lloret, Vicent, Neiss, Christian, Vidal‐Moya, Jose Alejandro, Rivero‐Crespo, Miguel Angel, Leyva‐Pérez, Antonio, Werbach, Katharina, Peterlik, Herwig, Grabau, Mathias, Wittkämper, Haiko, Papp, Christian, Steinrück, Hans-Peter, Pichler, Thomas, Görling, Andreas, Hauke, Frank, Abellán, Gonzalo, Hirsch, Andreas, "Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus" in Angewandte Chemie International Edition, 58, no. 17 (2019):5763-5768,
https://doi.org/10.1002/anie.201811181 . .