A novel method is successfully tested for non-covalent imprinting. Conditions are used which practically exclude the formation of prepolymerization complexes. The template is cholesterol, and no so-called functional monomer is used. The polymers contain only an acrylic diester crosslinker. The porogen isopropanol prevents even hydrogen bonding between the template and the monomer in the prepolymerization solution. Despite of these apparently very disadvantageous conditions, appreciable imprinting factors for cholesterol and imprinted selectivity against some other steroids are observed, similar to other cholesterol MIPs with proven analytical usefulness.
TY - JOUR
AU - Pešić, Miloš P.
AU - Todorov, Miljana D.
AU - Becskereki, Gergely
AU - Horvai, George
AU - Verbić, Tatjana
AU - Tóth, Blanka
PY - 2020
UR - https://cherry.chem.bg.ac.rs/handle/123456789/3951
AB - A novel method is successfully tested for non-covalent imprinting. Conditions are used which practically exclude the formation of prepolymerization complexes. The template is cholesterol, and no so-called functional monomer is used. The polymers contain only an acrylic diester crosslinker. The porogen isopropanol prevents even hydrogen bonding between the template and the monomer in the prepolymerization solution. Despite of these apparently very disadvantageous conditions, appreciable imprinting factors for cholesterol and imprinted selectivity against some other steroids are observed, similar to other cholesterol MIPs with proven analytical usefulness.
PB - Elsevier
T2 - Talanta
T1 - A novel method of molecular imprinting applied to the template cholesterol
VL - 217
SP - 121075
DO - 10.1016/j.talanta.2020.121075
ER -
@article{
author = "Pešić, Miloš P. and Todorov, Miljana D. and Becskereki, Gergely and Horvai, George and Verbić, Tatjana and Tóth, Blanka",
year = "2020",
abstract = "A novel method is successfully tested for non-covalent imprinting. Conditions are used which practically exclude the formation of prepolymerization complexes. The template is cholesterol, and no so-called functional monomer is used. The polymers contain only an acrylic diester crosslinker. The porogen isopropanol prevents even hydrogen bonding between the template and the monomer in the prepolymerization solution. Despite of these apparently very disadvantageous conditions, appreciable imprinting factors for cholesterol and imprinted selectivity against some other steroids are observed, similar to other cholesterol MIPs with proven analytical usefulness.",
publisher = "Elsevier",
journal = "Talanta",
title = "A novel method of molecular imprinting applied to the template cholesterol",
volume = "217",
pages = "121075",
doi = "10.1016/j.talanta.2020.121075"
}
Pešić, M. P., Todorov, M. D., Becskereki, G., Horvai, G., Verbić, T.,& Tóth, B.. (2020). A novel method of molecular imprinting applied to the template cholesterol. in Talanta
Elsevier., 217, 121075.
https://doi.org/10.1016/j.talanta.2020.121075
Pešić MP, Todorov MD, Becskereki G, Horvai G, Verbić T, Tóth B. A novel method of molecular imprinting applied to the template cholesterol. in Talanta. 2020;217:121075.
doi:10.1016/j.talanta.2020.121075 .
Pešić, Miloš P., Todorov, Miljana D., Becskereki, Gergely, Horvai, George, Verbić, Tatjana, Tóth, Blanka, "A novel method of molecular imprinting applied to the template cholesterol" in Talanta, 217 (2020):121075,
https://doi.org/10.1016/j.talanta.2020.121075 . .
