A novel method of molecular imprinting applied to the template cholesterol
Autori
Pešić, Miloš P.Todorov, Miljana D.
Becskereki, Gergely
Horvai, George
Verbić, Tatjana
Tóth, Blanka
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
A novel method is successfully tested for non-covalent imprinting. Conditions are used which practically exclude the formation of prepolymerization complexes. The template is cholesterol, and no so-called functional monomer is used. The polymers contain only an acrylic diester crosslinker. The porogen isopropanol prevents even hydrogen bonding between the template and the monomer in the prepolymerization solution. Despite of these apparently very disadvantageous conditions, appreciable imprinting factors for cholesterol and imprinted selectivity against some other steroids are observed, similar to other cholesterol MIPs with proven analytical usefulness.
Ključne reči:
Adsorption / Cholesterol / Cholesterol / Estradiol / Molecular imprinting / Polymers / Steroids / StigmasterolIzvor:
Talanta, 2020, 217, 121075-Izdavač:
- Elsevier
Finansiranje / projekti:
- Racionalni dizajn i sinteza biološki aktivnih i koordinacionih jedinjenja i funkcionalnih materijala, relevantnih u (bio)nanotehnologiji (RS-MESTD-Basic Research (BR or ON)-172035)
DOI: 10.1016/j.talanta.2020.121075
ISSN: 0039-9140
WoS: 000537880200068
Scopus: 2-s2.0-85083887240
Kolekcije
Institucija/grupa
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Pešić, Miloš P. AU - Todorov, Miljana D. AU - Becskereki, Gergely AU - Horvai, George AU - Verbić, Tatjana AU - Tóth, Blanka PY - 2020 UR - https://cherry.chem.bg.ac.rs/handle/123456789/3951 AB - A novel method is successfully tested for non-covalent imprinting. Conditions are used which practically exclude the formation of prepolymerization complexes. The template is cholesterol, and no so-called functional monomer is used. The polymers contain only an acrylic diester crosslinker. The porogen isopropanol prevents even hydrogen bonding between the template and the monomer in the prepolymerization solution. Despite of these apparently very disadvantageous conditions, appreciable imprinting factors for cholesterol and imprinted selectivity against some other steroids are observed, similar to other cholesterol MIPs with proven analytical usefulness. PB - Elsevier T2 - Talanta T1 - A novel method of molecular imprinting applied to the template cholesterol VL - 217 SP - 121075 DO - 10.1016/j.talanta.2020.121075 ER -
@article{ author = "Pešić, Miloš P. and Todorov, Miljana D. and Becskereki, Gergely and Horvai, George and Verbić, Tatjana and Tóth, Blanka", year = "2020", abstract = "A novel method is successfully tested for non-covalent imprinting. Conditions are used which practically exclude the formation of prepolymerization complexes. The template is cholesterol, and no so-called functional monomer is used. The polymers contain only an acrylic diester crosslinker. The porogen isopropanol prevents even hydrogen bonding between the template and the monomer in the prepolymerization solution. Despite of these apparently very disadvantageous conditions, appreciable imprinting factors for cholesterol and imprinted selectivity against some other steroids are observed, similar to other cholesterol MIPs with proven analytical usefulness.", publisher = "Elsevier", journal = "Talanta", title = "A novel method of molecular imprinting applied to the template cholesterol", volume = "217", pages = "121075", doi = "10.1016/j.talanta.2020.121075" }
Pešić, M. P., Todorov, M. D., Becskereki, G., Horvai, G., Verbić, T.,& Tóth, B.. (2020). A novel method of molecular imprinting applied to the template cholesterol. in Talanta Elsevier., 217, 121075. https://doi.org/10.1016/j.talanta.2020.121075
Pešić MP, Todorov MD, Becskereki G, Horvai G, Verbić T, Tóth B. A novel method of molecular imprinting applied to the template cholesterol. in Talanta. 2020;217:121075. doi:10.1016/j.talanta.2020.121075 .
Pešić, Miloš P., Todorov, Miljana D., Becskereki, Gergely, Horvai, George, Verbić, Tatjana, Tóth, Blanka, "A novel method of molecular imprinting applied to the template cholesterol" in Talanta, 217 (2020):121075, https://doi.org/10.1016/j.talanta.2020.121075 . .