Carbonate, oxalato and malonato bridged Cu(II) and Co(II) complexes with an octaazamacrocyclic ligand
Abstract
Four new Cu(II) and Co(II) complexes having an octaazamacrocyclic ligand derived from cyclam, N,N'N,",N'''-tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane, with either an mu-carbonato, oxalato or malonato as the additional ligand were isolated and investigated by elemental analysis, electronic and IR spectroscopy, as well as molar conductivity, magnetic and cyclic voltammetry (CV) measurements. Their microbiological activity was also tested. Binuclear or tetranuclear structures, depending on the bridging ligand and metal ion, was proposed.
Keywords:
Cu(II) acid Co(II) complexes / octaazamacrocycle / mu-carboxylato ligandsSource:
Journal of the Serbian Chemical Society, 1998, 63, 10, 781-791Publisher:
- Serbian Chemical Soc, Belgrade
Collections
Institution/Community
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Miodragović, Zoran AU - Vuckovic, G AU - Sovilj, Sofija P. AU - Manojlović, Dragan D. AU - Malinar, M.J. PY - 1998 UR - https://cherry.chem.bg.ac.rs/handle/123456789/396 AB - Four new Cu(II) and Co(II) complexes having an octaazamacrocyclic ligand derived from cyclam, N,N'N,",N'''-tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane, with either an mu-carbonato, oxalato or malonato as the additional ligand were isolated and investigated by elemental analysis, electronic and IR spectroscopy, as well as molar conductivity, magnetic and cyclic voltammetry (CV) measurements. Their microbiological activity was also tested. Binuclear or tetranuclear structures, depending on the bridging ligand and metal ion, was proposed. PB - Serbian Chemical Soc, Belgrade T2 - Journal of the Serbian Chemical Society T1 - Carbonate, oxalato and malonato bridged Cu(II) and Co(II) complexes with an octaazamacrocyclic ligand VL - 63 IS - 10 SP - 781 EP - 791 UR - https://hdl.handle.net/21.15107/rcub_cherry_396 ER -
@article{ author = "Miodragović, Zoran and Vuckovic, G and Sovilj, Sofija P. and Manojlović, Dragan D. and Malinar, M.J.", year = "1998", abstract = "Four new Cu(II) and Co(II) complexes having an octaazamacrocyclic ligand derived from cyclam, N,N'N,",N'''-tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane, with either an mu-carbonato, oxalato or malonato as the additional ligand were isolated and investigated by elemental analysis, electronic and IR spectroscopy, as well as molar conductivity, magnetic and cyclic voltammetry (CV) measurements. Their microbiological activity was also tested. Binuclear or tetranuclear structures, depending on the bridging ligand and metal ion, was proposed.", publisher = "Serbian Chemical Soc, Belgrade", journal = "Journal of the Serbian Chemical Society", title = "Carbonate, oxalato and malonato bridged Cu(II) and Co(II) complexes with an octaazamacrocyclic ligand", volume = "63", number = "10", pages = "781-791", url = "https://hdl.handle.net/21.15107/rcub_cherry_396" }
Miodragović, Z., Vuckovic, G., Sovilj, S. P., Manojlović, D. D.,& Malinar, M.J.. (1998). Carbonate, oxalato and malonato bridged Cu(II) and Co(II) complexes with an octaazamacrocyclic ligand. in Journal of the Serbian Chemical Society Serbian Chemical Soc, Belgrade., 63(10), 781-791. https://hdl.handle.net/21.15107/rcub_cherry_396
Miodragović Z, Vuckovic G, Sovilj SP, Manojlović DD, Malinar M. Carbonate, oxalato and malonato bridged Cu(II) and Co(II) complexes with an octaazamacrocyclic ligand. in Journal of the Serbian Chemical Society. 1998;63(10):781-791. https://hdl.handle.net/21.15107/rcub_cherry_396 .
Miodragović, Zoran, Vuckovic, G, Sovilj, Sofija P., Manojlović, Dragan D., Malinar, M.J., "Carbonate, oxalato and malonato bridged Cu(II) and Co(II) complexes with an octaazamacrocyclic ligand" in Journal of the Serbian Chemical Society, 63, no. 10 (1998):781-791, https://hdl.handle.net/21.15107/rcub_cherry_396 .