Four out of six theoretically possible isomers of the (1,3-diaminopropane)bis(S-tyrosinato)cobalt(III) complex, having the cis(O) configuration, were isolated, and the trans(O) isomer was only defined in the eluate. The isomers were separated on an optically active Sephadex QAE column. Geometrical and absolute configurations of the isomers were determined by electronic absorption, circular dichroic and H-1 NMR spectra. The effect of the aromatic side group of the coordinated S-tyrosinato ligand on the stereoselective formation of the obtained isomers was examined.
TY - JOUR
AU - Malinar, M.J.
AU - Miodragović Đenana U.
AU - Milosavljevic, S
AU - Celap, MB
AU - Vucelic, D
PY - 1998
UR - https://cherry.chem.bg.ac.rs/handle/123456789/402
AB - Four out of six theoretically possible isomers of the (1,3-diaminopropane)bis(S-tyrosinato)cobalt(III) complex, having the cis(O) configuration, were isolated, and the trans(O) isomer was only defined in the eluate. The isomers were separated on an optically active Sephadex QAE column. Geometrical and absolute configurations of the isomers were determined by electronic absorption, circular dichroic and H-1 NMR spectra. The effect of the aromatic side group of the coordinated S-tyrosinato ligand on the stereoselective formation of the obtained isomers was examined.
PB - Gordon Breach Sci Publ Ltd, Reading
T2 - Enantiomer
T1 - Mixed cobalt(III) complexes with S-tyrosine and 1,3-diaminopropane
VL - 3
IS - 4-5
SP - 349
EP - 356
UR - https://hdl.handle.net/21.15107/rcub_cherry_402
UR - Kon_1375
ER -
@article{
author = "Malinar, M.J. and Miodragović Đenana U. and Milosavljevic, S and Celap, MB and Vucelic, D",
year = "1998",
abstract = "Four out of six theoretically possible isomers of the (1,3-diaminopropane)bis(S-tyrosinato)cobalt(III) complex, having the cis(O) configuration, were isolated, and the trans(O) isomer was only defined in the eluate. The isomers were separated on an optically active Sephadex QAE column. Geometrical and absolute configurations of the isomers were determined by electronic absorption, circular dichroic and H-1 NMR spectra. The effect of the aromatic side group of the coordinated S-tyrosinato ligand on the stereoselective formation of the obtained isomers was examined.",
publisher = "Gordon Breach Sci Publ Ltd, Reading",
journal = "Enantiomer",
title = "Mixed cobalt(III) complexes with S-tyrosine and 1,3-diaminopropane",
volume = "3",
number = "4-5",
pages = "349-356",
url = "https://hdl.handle.net/21.15107/rcub_cherry_402, Kon_1375"
}
Malinar, M.J., Miodragović Đenana U., Milosavljevic, S., Celap, M.,& Vucelic, D.. (1998). Mixed cobalt(III) complexes with S-tyrosine and 1,3-diaminopropane. in Enantiomer
Gordon Breach Sci Publ Ltd, Reading., 3(4-5), 349-356.
https://hdl.handle.net/21.15107/rcub_cherry_402
Malinar M, Miodragović Đenana U., Milosavljevic S, Celap M, Vucelic D. Mixed cobalt(III) complexes with S-tyrosine and 1,3-diaminopropane. in Enantiomer. 1998;3(4-5):349-356.
https://hdl.handle.net/21.15107/rcub_cherry_402 .
Malinar, M.J., Miodragović Đenana U., Milosavljevic, S, Celap, MB, Vucelic, D, "Mixed cobalt(III) complexes with S-tyrosine and 1,3-diaminopropane" in Enantiomer, 3, no. 4-5 (1998):349-356,
https://hdl.handle.net/21.15107/rcub_cherry_402 .
