Oxidative degradation of aromatic N-compounds using cobalt containing montmorillonite-based catalysts
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2020
Authors
Ilić, IlijaMilutinović-Nikolić, Aleksandra D.
Mojović, Zorica D.
Vuković, Zoran
Vulić, Predrag J.
Gržetić, Ivan
Banković, Predrag
Jović-Jovičić, Nataša
Article (Published version)
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Show full item recordAbstract
The goal of this work was the synthesis of a montmorillonite based catalyst for advanced oxidative degradation of organic water pollutants. Montmorillonite (Mt) –rich bentonite was acid-activated (MtA), and impregnated with cobalt (II) solution using the incipient wetness impregnation method. The impregnation was followed by heat treatment. Cobalt(II) ions were added in the quantities corresponding to 0.5 and 1.0 of the cation exchange capacity value. All samples were characterized by using chemical analysis, X-ray powder diffraction (XRPD), Electron paramagnetic resonance (EPR), X-ray photoelectron spectroscopy (XPS), Scanning electron microscopy (SEM) coupled with Energy-dispersive X-ray spectroscopy (EDS), Transmission electron microscopy (TEM) and low temperature N2 physisorption. The incorporation of the cobalt in the impregnated samples and the development of porous structure in the acid-activated ones were confirmed. The montmorillonite (Mt) was used as a catalyst support, while... the cobalt in its oxide form was responsible for the generation of sulfo-radicals from Oxone®. Two aromatic N-compounds were tested as model pollutants: diazo dye - Acid Orange 10 (AO10) and nicotine. It was found that the synthesized catalysts could be used for the degradation of both pollutants, although more efficiently in AO10 degradation. The acid activation, higher cobalt loading, and temperature were found to be beneficial for the degradation of AO10.
Keywords:
Acid activation / Catalyst / Cobalt / Incipient wetness impregnation / Montmorillonite / Oxone®Source:
Applied Clay Science, 2020, 193, 105668-Publisher:
- Elsevier
Funding / projects:
- Eksperimentalna i kliničko-farmakološka istraživanja mehanizma dejstva i interakcija lekova u nervnom i kardiovaskularnom sistemu (RS-MESTD-MPN2006-2010-145001)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) (RS-MESTD-inst-2020-200026)
Note:
- Supplementary material: http://cherry.chem.bg.ac.rs/handle/123456789/4046
DOI: 10.1016/j.clay.2020.105668
ISSN: 0169-1317
WoS: 000545902900011
Scopus: 2-s2.0-85084596942
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Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Ilić, Ilija AU - Milutinović-Nikolić, Aleksandra D. AU - Mojović, Zorica D. AU - Vuković, Zoran AU - Vulić, Predrag J. AU - Gržetić, Ivan AU - Banković, Predrag AU - Jović-Jovičić, Nataša PY - 2020 UR - https://cherry.chem.bg.ac.rs/handle/123456789/4045 AB - The goal of this work was the synthesis of a montmorillonite based catalyst for advanced oxidative degradation of organic water pollutants. Montmorillonite (Mt) –rich bentonite was acid-activated (MtA), and impregnated with cobalt (II) solution using the incipient wetness impregnation method. The impregnation was followed by heat treatment. Cobalt(II) ions were added in the quantities corresponding to 0.5 and 1.0 of the cation exchange capacity value. All samples were characterized by using chemical analysis, X-ray powder diffraction (XRPD), Electron paramagnetic resonance (EPR), X-ray photoelectron spectroscopy (XPS), Scanning electron microscopy (SEM) coupled with Energy-dispersive X-ray spectroscopy (EDS), Transmission electron microscopy (TEM) and low temperature N2 physisorption. The incorporation of the cobalt in the impregnated samples and the development of porous structure in the acid-activated ones were confirmed. The montmorillonite (Mt) was used as a catalyst support, while the cobalt in its oxide form was responsible for the generation of sulfo-radicals from Oxone®. Two aromatic N-compounds were tested as model pollutants: diazo dye - Acid Orange 10 (AO10) and nicotine. It was found that the synthesized catalysts could be used for the degradation of both pollutants, although more efficiently in AO10 degradation. The acid activation, higher cobalt loading, and temperature were found to be beneficial for the degradation of AO10. PB - Elsevier T2 - Applied Clay Science T1 - Oxidative degradation of aromatic N-compounds using cobalt containing montmorillonite-based catalysts VL - 193 SP - 105668 DO - 10.1016/j.clay.2020.105668 ER -
@article{ author = "Ilić, Ilija and Milutinović-Nikolić, Aleksandra D. and Mojović, Zorica D. and Vuković, Zoran and Vulić, Predrag J. and Gržetić, Ivan and Banković, Predrag and Jović-Jovičić, Nataša", year = "2020", abstract = "The goal of this work was the synthesis of a montmorillonite based catalyst for advanced oxidative degradation of organic water pollutants. Montmorillonite (Mt) –rich bentonite was acid-activated (MtA), and impregnated with cobalt (II) solution using the incipient wetness impregnation method. The impregnation was followed by heat treatment. Cobalt(II) ions were added in the quantities corresponding to 0.5 and 1.0 of the cation exchange capacity value. All samples were characterized by using chemical analysis, X-ray powder diffraction (XRPD), Electron paramagnetic resonance (EPR), X-ray photoelectron spectroscopy (XPS), Scanning electron microscopy (SEM) coupled with Energy-dispersive X-ray spectroscopy (EDS), Transmission electron microscopy (TEM) and low temperature N2 physisorption. The incorporation of the cobalt in the impregnated samples and the development of porous structure in the acid-activated ones were confirmed. The montmorillonite (Mt) was used as a catalyst support, while the cobalt in its oxide form was responsible for the generation of sulfo-radicals from Oxone®. Two aromatic N-compounds were tested as model pollutants: diazo dye - Acid Orange 10 (AO10) and nicotine. It was found that the synthesized catalysts could be used for the degradation of both pollutants, although more efficiently in AO10 degradation. The acid activation, higher cobalt loading, and temperature were found to be beneficial for the degradation of AO10.", publisher = "Elsevier", journal = "Applied Clay Science", title = "Oxidative degradation of aromatic N-compounds using cobalt containing montmorillonite-based catalysts", volume = "193", pages = "105668", doi = "10.1016/j.clay.2020.105668" }
Ilić, I., Milutinović-Nikolić, A. D., Mojović, Z. D., Vuković, Z., Vulić, P. J., Gržetić, I., Banković, P.,& Jović-Jovičić, N.. (2020). Oxidative degradation of aromatic N-compounds using cobalt containing montmorillonite-based catalysts. in Applied Clay Science Elsevier., 193, 105668. https://doi.org/10.1016/j.clay.2020.105668
Ilić I, Milutinović-Nikolić AD, Mojović ZD, Vuković Z, Vulić PJ, Gržetić I, Banković P, Jović-Jovičić N. Oxidative degradation of aromatic N-compounds using cobalt containing montmorillonite-based catalysts. in Applied Clay Science. 2020;193:105668. doi:10.1016/j.clay.2020.105668 .
Ilić, Ilija, Milutinović-Nikolić, Aleksandra D., Mojović, Zorica D., Vuković, Zoran, Vulić, Predrag J., Gržetić, Ivan, Banković, Predrag, Jović-Jovičić, Nataša, "Oxidative degradation of aromatic N-compounds using cobalt containing montmorillonite-based catalysts" in Applied Clay Science, 193 (2020):105668, https://doi.org/10.1016/j.clay.2020.105668 . .