New radical reactions of S-alkoxycarbonyl xanthates. Total synthesis of (+/-)-cinnamolide and (+/-)-metlhylenolactocin

dc.creator	Forbes, JE
dc.creator	Saičić, Radomir
dc.creator	Zard, SZ
dc.date.accessioned	2018-11-22T00:02:36Z
dc.date.available	2018-11-22T00:02:36Z
dc.date.issued	1999
dc.identifier.issn	0040-4020
dc.identifier.uri	https://cherry.chem.bg.ac.rs/handle/123456789/409
dc.description.abstract	Irradiation with visible light of S-alkoxycarbonyl xanthates derived from various alcohols gives rise to alkoxycarbonyl radicals with bifurcate reactivity: loss of carbon dioxide leads to deoxygenated derivatives (i.e. alkyl xanthates) whereas intramolecular addition to a suitably located double bond produces lactones; these new reactions were applied to the total synthesis of (+/-)-cinnamolide and (+/-)-methylenolactocin. (C) 1999 Elsevier Science Ltd. All rights reserved.	en
dc.publisher	Pergamon-Elsevier Science Ltd, Oxford
dc.rights	restrictedAccess
dc.source	Tetrahedron
dc.title	New radical reactions of S-alkoxycarbonyl xanthates. Total synthesis of (+/-)-cinnamolide and (+/-)-metlhylenolactocin	en
dc.type	article
dc.rights.license	ARR
dcterms.abstract	Зард, СЗ; Саичић, Радомир; Форбес, ЈЕ;
dc.citation.volume	55
dc.citation.issue	12
dc.citation.spage	3791
dc.citation.epage	3802
dc.identifier.wos	000079099800027
dc.identifier.doi	10.1016/S0040-4020(98)01184-3
dc.citation.other	55(12): 3791-3802
dc.citation.rank	M22
dc.type.version	publishedVersion	en
dc.identifier.scopus	2-s2.0-0033583016