Ring closure reaction of 4-tert-butyl-4-penten-1-ol with electrophilic reagents
Apstrakt
The reaction of 4-tert-butyl-4-penten-1-ol 3 with some electrophilic reagents (such as mineral acids, mercuric acetate, peracids) has been investigated. It is found that in the acid (H2SO4) catalysed reaction of 3, the products of 1,2-methyl rearrangement are produced. The oxymercuration/demercuration reaction of 3 and its reaction with meta-chloroperbenzoic acid afford in high yields exclusively Markovnikov-type products.
Izvor:
Indian Journal of Chemistry. Section B: Organic and Medicinal Chemistry, 1999, 38, 1, 101-105Izdavač:
- Natl Inst Science Communication, New Delhi
Kolekcije
Institucija/grupa
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Mihailović, ML AU - Gojkovic, S AU - Milosavljevic, S AU - Konstantinovic, S PY - 1999 UR - https://cherry.chem.bg.ac.rs/handle/123456789/412 AB - The reaction of 4-tert-butyl-4-penten-1-ol 3 with some electrophilic reagents (such as mineral acids, mercuric acetate, peracids) has been investigated. It is found that in the acid (H2SO4) catalysed reaction of 3, the products of 1,2-methyl rearrangement are produced. The oxymercuration/demercuration reaction of 3 and its reaction with meta-chloroperbenzoic acid afford in high yields exclusively Markovnikov-type products. PB - Natl Inst Science Communication, New Delhi T2 - Indian Journal of Chemistry. Section B: Organic and Medicinal Chemistry T1 - Ring closure reaction of 4-tert-butyl-4-penten-1-ol with electrophilic reagents VL - 38 IS - 1 SP - 101 EP - 105 UR - https://hdl.handle.net/21.15107/rcub_cherry_412 ER -
@article{ author = "Mihailović, ML and Gojkovic, S and Milosavljevic, S and Konstantinovic, S", year = "1999", abstract = "The reaction of 4-tert-butyl-4-penten-1-ol 3 with some electrophilic reagents (such as mineral acids, mercuric acetate, peracids) has been investigated. It is found that in the acid (H2SO4) catalysed reaction of 3, the products of 1,2-methyl rearrangement are produced. The oxymercuration/demercuration reaction of 3 and its reaction with meta-chloroperbenzoic acid afford in high yields exclusively Markovnikov-type products.", publisher = "Natl Inst Science Communication, New Delhi", journal = "Indian Journal of Chemistry. Section B: Organic and Medicinal Chemistry", title = "Ring closure reaction of 4-tert-butyl-4-penten-1-ol with electrophilic reagents", volume = "38", number = "1", pages = "101-105", url = "https://hdl.handle.net/21.15107/rcub_cherry_412" }
Mihailović, M., Gojkovic, S., Milosavljevic, S.,& Konstantinovic, S.. (1999). Ring closure reaction of 4-tert-butyl-4-penten-1-ol with electrophilic reagents. in Indian Journal of Chemistry. Section B: Organic and Medicinal Chemistry Natl Inst Science Communication, New Delhi., 38(1), 101-105. https://hdl.handle.net/21.15107/rcub_cherry_412
Mihailović M, Gojkovic S, Milosavljevic S, Konstantinovic S. Ring closure reaction of 4-tert-butyl-4-penten-1-ol with electrophilic reagents. in Indian Journal of Chemistry. Section B: Organic and Medicinal Chemistry. 1999;38(1):101-105. https://hdl.handle.net/21.15107/rcub_cherry_412 .
Mihailović, ML, Gojkovic, S, Milosavljevic, S, Konstantinovic, S, "Ring closure reaction of 4-tert-butyl-4-penten-1-ol with electrophilic reagents" in Indian Journal of Chemistry. Section B: Organic and Medicinal Chemistry, 38, no. 1 (1999):101-105, https://hdl.handle.net/21.15107/rcub_cherry_412 .