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Electrochemical oxidation of a complex mixture of phenolic compounds in the base media using PbO2-GNRs anodes
dc.creator | Savić, Branislava G. | |
dc.creator | Stanković, Dalibor | |
dc.creator | Živković, Sanja | |
dc.creator | Ognjanović, Miloš | |
dc.creator | Tasić, Gvozden S. | |
dc.creator | Mihajlović, Ivana J. | |
dc.creator | Brdarić, Tanja P. | |
dc.date.accessioned | 2020-10-14T07:51:07Z | |
dc.date.available | 2020-10-14T07:51:07Z | |
dc.date.issued | 2020 | |
dc.identifier.issn | 0169-4332 | |
dc.identifier.uri | https://cherry.chem.bg.ac.rs/handle/123456789/4177 | |
dc.description.abstract | A novel anode based on PbO2-GNRs nanocomposites was synthesized in order to investigate the simultaneous electrochemical oxidation of phenolic compounds in a mixture of methyl and chloro substituted phenols in alkaline solution (pH = 8.3). The crystal structure, morphology and composition of the synthesized materials were characterized using X-ray powder diffraction (XRPD), field emission scanning electron microscopy with energy dispersive X-ray spectrometer (FESEM-EDX) and transmission electron microscopy (TEM). FESEM images confirmed the presence of PbO2 nanoparticles on the PbO2-GNRs composite. The cyclic voltammetry measurements of the PbO2-GNRs electrode in 0.1 M Na2SO4 electrolyte indicated the electrochemical oxidation of phenol via indirect mechanism by hydroxyl radicals. Electrolytic oxidation of phenolic compounds was performed under potentiostatic conditions at potentials 2.3 V and 3 V. Removal efficiency of phenolic compounds increased with increasing the time of electrolysis and applied potential, up to 78% for 300 min and potential of 3 V. GC–MS chromatograms confirmed that mechanism of phenolic compounds degradation is based on their dechlorination and demethylation followed by the process of aromatic ring degradation. Newly synthesized PbO2-GNRs as electrode material could be successfully implemented in wastewater treatment of phenolic compounds by the electrochemical oxidation process. | |
dc.publisher | Elsevier | |
dc.relation | Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja - Eureka project E!13303 MED-BIO-TEST | |
dc.rights | restrictedAccess | |
dc.source | Applied Surface Science | |
dc.subject | Base medium | |
dc.subject | Electrochemical oxidation | |
dc.subject | PbO-GNRs | |
dc.subject | Phenolic compounds | |
dc.subject | Wastewater treatment | |
dc.title | Electrochemical oxidation of a complex mixture of phenolic compounds in the base media using PbO2-GNRs anodes | |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Михајловић, Ивана Ј.; Савић, Бранислава Г.; Живковић, Сања; Огњановић, Милош; Тасић, Гвозден С.; Станковић, Далибор; Брдарић, Тања П.; | |
dc.citation.volume | 529 | |
dc.citation.spage | 147120 | |
dc.identifier.wos | 000564391700008 | |
dc.identifier.doi | 10.1016/j.apsusc.2020.147120 | |
dc.citation.rank | aM21~ | |
dc.description.other | Supplementary material: [https://cherry.chem.bg.ac.rs/handle/123456789/4207] | |
dc.type.version | publishedVersion | |
dc.identifier.scopus | 2-s2.0-85087334810 |