Synthesis and characterization of sym-cis- and unsym-cis- (ethylenediamine-N,N '-di-3-propionato)cobalt(III) complexes with symmetrical N,N '-substituted diamines
Апстракт
A series of octahedral sym-cis and unsym-cis cobalt(III) complexes involving tetradentate ethylenediamine-N,N'-di-3-propionate ion (eddp) and symmetrical diamines, [ethylenediamine (en), N,N'-dimethylethylenediamine (dmen) and N,N'-diethylethylenediamine (deen)] were prepared by reaction of sodium unsym-cis-(ethylenediamine-N,N'-di-3-propionato)(carbonato)cobaltate(III) dihydrate with the corresponding diamine. The stereochemistry of the complexes prepared was investigated through ion-exchange chromatography, electronic absorption, infrared and H-1 NMR spectroscopy.
Извор:
Synthesis and Reactivity in Inorganic and Metal-organic Chemistry, 1999, 29, 9, 1567-1578Издавач:
- Marcel Dekker Inc, New York
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Grgurić-Šipka, Sanja AU - Sabo, Tibor PY - 1999 UR - https://cherry.chem.bg.ac.rs/handle/123456789/421 AB - A series of octahedral sym-cis and unsym-cis cobalt(III) complexes involving tetradentate ethylenediamine-N,N'-di-3-propionate ion (eddp) and symmetrical diamines, [ethylenediamine (en), N,N'-dimethylethylenediamine (dmen) and N,N'-diethylethylenediamine (deen)] were prepared by reaction of sodium unsym-cis-(ethylenediamine-N,N'-di-3-propionato)(carbonato)cobaltate(III) dihydrate with the corresponding diamine. The stereochemistry of the complexes prepared was investigated through ion-exchange chromatography, electronic absorption, infrared and H-1 NMR spectroscopy. PB - Marcel Dekker Inc, New York T2 - Synthesis and Reactivity in Inorganic and Metal-organic Chemistry T1 - Synthesis and characterization of sym-cis- and unsym-cis- (ethylenediamine-N,N '-di-3-propionato)cobalt(III) complexes with symmetrical N,N '-substituted diamines VL - 29 IS - 9 SP - 1567 EP - 1578 UR - https://hdl.handle.net/21.15107/rcub_cherry_421 ER -
@article{ author = "Grgurić-Šipka, Sanja and Sabo, Tibor", year = "1999", abstract = "A series of octahedral sym-cis and unsym-cis cobalt(III) complexes involving tetradentate ethylenediamine-N,N'-di-3-propionate ion (eddp) and symmetrical diamines, [ethylenediamine (en), N,N'-dimethylethylenediamine (dmen) and N,N'-diethylethylenediamine (deen)] were prepared by reaction of sodium unsym-cis-(ethylenediamine-N,N'-di-3-propionato)(carbonato)cobaltate(III) dihydrate with the corresponding diamine. The stereochemistry of the complexes prepared was investigated through ion-exchange chromatography, electronic absorption, infrared and H-1 NMR spectroscopy.", publisher = "Marcel Dekker Inc, New York", journal = "Synthesis and Reactivity in Inorganic and Metal-organic Chemistry", title = "Synthesis and characterization of sym-cis- and unsym-cis- (ethylenediamine-N,N '-di-3-propionato)cobalt(III) complexes with symmetrical N,N '-substituted diamines", volume = "29", number = "9", pages = "1567-1578", url = "https://hdl.handle.net/21.15107/rcub_cherry_421" }
Grgurić-Šipka, S.,& Sabo, T.. (1999). Synthesis and characterization of sym-cis- and unsym-cis- (ethylenediamine-N,N '-di-3-propionato)cobalt(III) complexes with symmetrical N,N '-substituted diamines. in Synthesis and Reactivity in Inorganic and Metal-organic Chemistry Marcel Dekker Inc, New York., 29(9), 1567-1578. https://hdl.handle.net/21.15107/rcub_cherry_421
Grgurić-Šipka S, Sabo T. Synthesis and characterization of sym-cis- and unsym-cis- (ethylenediamine-N,N '-di-3-propionato)cobalt(III) complexes with symmetrical N,N '-substituted diamines. in Synthesis and Reactivity in Inorganic and Metal-organic Chemistry. 1999;29(9):1567-1578. https://hdl.handle.net/21.15107/rcub_cherry_421 .
Grgurić-Šipka, Sanja, Sabo, Tibor, "Synthesis and characterization of sym-cis- and unsym-cis- (ethylenediamine-N,N '-di-3-propionato)cobalt(III) complexes with symmetrical N,N '-substituted diamines" in Synthesis and Reactivity in Inorganic and Metal-organic Chemistry, 29, no. 9 (1999):1567-1578, https://hdl.handle.net/21.15107/rcub_cherry_421 .