Crystal and molecular structure of five coordinate copper(II) complex with 2,6-bis[1-(methoxycarbonylmethyl-hydrazono)ethyl] pyridine
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1999
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The title compound was obtained by a template synthesis from 2,6-diacetylpyridine, ethylhydrazinoacetate and CuCl2 . 2H(2)O (molar ratio 1 : 2 : 1, in methanol), and its structure has been determined by single-crystal X-ray diffraction: monoclinic space group P2(1)/c, a = 13.906(5), b = 18.199(6), c = 16.641(6) Angstrom, beta = 107.18(3)degrees and z = 4. The ligand was found to be tridentate in a trigonal-bipyramidal coordination geometry with two chloride ligands. There are two independent complex molecules, one of which is hydrogen bonded to the water of crystallization.
Ključne reči:
copper(II) complexes / 2,6-diacetylpyridine derivative / open-chain ligand / crystal structure / trigonal-bipyramidal geometryIzvor:
Journal of Chemical Crystallography, 1999, 29, 5, 575-580Izdavač:
- Kluwer Academic/Plenum Publ, New York
DOI: 10.1023/A:1009500919942
ISSN: 1074-1542
WoS: 000083888800010
Scopus: 2-s2.0-0033130426
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Institucija/grupa
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Anđelković, Katarina K. AU - Tellgren, R AU - Niketic, SR AU - Sladić, Dušan AU - Poleti, D PY - 1999 UR - https://cherry.chem.bg.ac.rs/handle/123456789/425 AB - The title compound was obtained by a template synthesis from 2,6-diacetylpyridine, ethylhydrazinoacetate and CuCl2 . 2H(2)O (molar ratio 1 : 2 : 1, in methanol), and its structure has been determined by single-crystal X-ray diffraction: monoclinic space group P2(1)/c, a = 13.906(5), b = 18.199(6), c = 16.641(6) Angstrom, beta = 107.18(3)degrees and z = 4. The ligand was found to be tridentate in a trigonal-bipyramidal coordination geometry with two chloride ligands. There are two independent complex molecules, one of which is hydrogen bonded to the water of crystallization. PB - Kluwer Academic/Plenum Publ, New York T2 - Journal of Chemical Crystallography T1 - Crystal and molecular structure of five coordinate copper(II) complex with 2,6-bis[1-(methoxycarbonylmethyl-hydrazono)ethyl] pyridine VL - 29 IS - 5 SP - 575 EP - 580 DO - 10.1023/A:1009500919942 ER -
@article{ author = "Anđelković, Katarina K. and Tellgren, R and Niketic, SR and Sladić, Dušan and Poleti, D", year = "1999", abstract = "The title compound was obtained by a template synthesis from 2,6-diacetylpyridine, ethylhydrazinoacetate and CuCl2 . 2H(2)O (molar ratio 1 : 2 : 1, in methanol), and its structure has been determined by single-crystal X-ray diffraction: monoclinic space group P2(1)/c, a = 13.906(5), b = 18.199(6), c = 16.641(6) Angstrom, beta = 107.18(3)degrees and z = 4. The ligand was found to be tridentate in a trigonal-bipyramidal coordination geometry with two chloride ligands. There are two independent complex molecules, one of which is hydrogen bonded to the water of crystallization.", publisher = "Kluwer Academic/Plenum Publ, New York", journal = "Journal of Chemical Crystallography", title = "Crystal and molecular structure of five coordinate copper(II) complex with 2,6-bis[1-(methoxycarbonylmethyl-hydrazono)ethyl] pyridine", volume = "29", number = "5", pages = "575-580", doi = "10.1023/A:1009500919942" }
Anđelković, K. K., Tellgren, R., Niketic, S., Sladić, D.,& Poleti, D.. (1999). Crystal and molecular structure of five coordinate copper(II) complex with 2,6-bis[1-(methoxycarbonylmethyl-hydrazono)ethyl] pyridine. in Journal of Chemical Crystallography Kluwer Academic/Plenum Publ, New York., 29(5), 575-580. https://doi.org/10.1023/A:1009500919942
Anđelković KK, Tellgren R, Niketic S, Sladić D, Poleti D. Crystal and molecular structure of five coordinate copper(II) complex with 2,6-bis[1-(methoxycarbonylmethyl-hydrazono)ethyl] pyridine. in Journal of Chemical Crystallography. 1999;29(5):575-580. doi:10.1023/A:1009500919942 .
Anđelković, Katarina K., Tellgren, R, Niketic, SR, Sladić, Dušan, Poleti, D, "Crystal and molecular structure of five coordinate copper(II) complex with 2,6-bis[1-(methoxycarbonylmethyl-hydrazono)ethyl] pyridine" in Journal of Chemical Crystallography, 29, no. 5 (1999):575-580, https://doi.org/10.1023/A:1009500919942 . .