Intermolecular free radical additions to strained cycloalkenes. Cyclopropene and cyclobutene as radical accepters
Abstract
Intermolecular additions of electrophilic radicals to cyclopropene and cyclobutene derivatives afford the addition products in 37-50% yield. The strain relief in the intermediary radical accelerates the addition, as shown by competitive addition experiments. (C) 2000 Elsevier Science Ltd. All rights reserved.
Keywords:
radicals and radical reactions / cyclopropenes / cyclobutenes / xanthates / strained compoundsSource:
Tetrahedron Letters, 2000, 41, 16, 2979-2982Publisher:
- Pergamon-Elsevier Science Ltd, Oxford
DOI: 10.1016/S0040-4039(00)00286-0
ISSN: 0040-4039
WoS: 000086681200050
Scopus: 2-s2.0-0342369341
Collections
Institution/Community
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Ferjančić, Zorana AU - Čeković, Živorad AU - Saičić, Radomir PY - 2000 UR - https://cherry.chem.bg.ac.rs/handle/123456789/433 AB - Intermolecular additions of electrophilic radicals to cyclopropene and cyclobutene derivatives afford the addition products in 37-50% yield. The strain relief in the intermediary radical accelerates the addition, as shown by competitive addition experiments. (C) 2000 Elsevier Science Ltd. All rights reserved. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - Tetrahedron Letters T1 - Intermolecular free radical additions to strained cycloalkenes. Cyclopropene and cyclobutene as radical accepters VL - 41 IS - 16 SP - 2979 EP - 2982 DO - 10.1016/S0040-4039(00)00286-0 ER -
@article{ author = "Ferjančić, Zorana and Čeković, Živorad and Saičić, Radomir", year = "2000", abstract = "Intermolecular additions of electrophilic radicals to cyclopropene and cyclobutene derivatives afford the addition products in 37-50% yield. The strain relief in the intermediary radical accelerates the addition, as shown by competitive addition experiments. (C) 2000 Elsevier Science Ltd. All rights reserved.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "Tetrahedron Letters", title = "Intermolecular free radical additions to strained cycloalkenes. Cyclopropene and cyclobutene as radical accepters", volume = "41", number = "16", pages = "2979-2982", doi = "10.1016/S0040-4039(00)00286-0" }
Ferjančić, Z., Čeković, Ž.,& Saičić, R.. (2000). Intermolecular free radical additions to strained cycloalkenes. Cyclopropene and cyclobutene as radical accepters. in Tetrahedron Letters Pergamon-Elsevier Science Ltd, Oxford., 41(16), 2979-2982. https://doi.org/10.1016/S0040-4039(00)00286-0
Ferjančić Z, Čeković Ž, Saičić R. Intermolecular free radical additions to strained cycloalkenes. Cyclopropene and cyclobutene as radical accepters. in Tetrahedron Letters. 2000;41(16):2979-2982. doi:10.1016/S0040-4039(00)00286-0 .
Ferjančić, Zorana, Čeković, Živorad, Saičić, Radomir, "Intermolecular free radical additions to strained cycloalkenes. Cyclopropene and cyclobutene as radical accepters" in Tetrahedron Letters, 41, no. 16 (2000):2979-2982, https://doi.org/10.1016/S0040-4039(00)00286-0 . .