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Laccase Polyphenolic Biosensor Supported on MnO2@GNP Decorated SPCE: Preparation, Characterization, and Analytical Application
dc.creator | Đurđić, Slađana Z. | |
dc.creator | Stanković, V. | |
dc.creator | Vlahović, Filip | |
dc.creator | Ognjanović, Miloš | |
dc.creator | Kalcher, K. | |
dc.creator | Ćirković Veličković, Tanja | |
dc.creator | Mutić, Jelena | |
dc.creator | Stanković, Dalibor | |
dc.date.accessioned | 2021-07-21T08:21:40Z | |
dc.date.available | 2021-07-21T08:21:40Z | |
dc.date.issued | 2021 | |
dc.identifier.issn | 0013-4651 | |
dc.identifier.uri | https://cherry.chem.bg.ac.rs/handle/123456789/4474 | |
dc.description.abstract | Based on graphene nanoplatelets capability to build block composites, as well as well-known electrochemical characteristic of the manganese oxide materials, in the present research, a nanocomposite, formed from graphene nanoplatelets (GNP) and manganese(IV)-oxide (MnO2) nanoparticles, has been proposed as a novel and convenient support for enzyme immobilization. Performance of screen printed carbon electrodes (SPCEs) was significantly improved after their modification with GNP@MnO2 (SPCE/GNP@MnO2). The polyphenolic index biosensor was prepared by applying the drop coating technique using laccase and Nafion®. Developed biosensor shows a fast and reliable amperometric response toward caffeic acid, as a model compound, at operating potential of +0.40 V (vs Ag/AgCl), with a wide linear range and detection limit of 1.9 μmol l−1. Developed procedure was successfully applied for the determination of polyphenolic indexes in wine samples. Recovery tests indicate excellent accuracy and precision of the method, concluding that the biosensor can offer a fast, accurate, reliable and precise determination of the polyphenolic index. More importantly, our results suggest a great potential for the application in real samples. | |
dc.language | en | |
dc.publisher | The Electrochemical Society (ECS) | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200168/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200026/RS// | |
dc.relation | CEEPUS network CIII-CZ-0212-13-1920-M- 131892 (Education of Modern Analytical and Bioanalytical Methods). | |
dc.relation | Eureka project call, E! 13303 MED-BIO-TEST. | |
dc.rights | restrictedAccess | |
dc.source | Journal of The Electrochemical Society | |
dc.title | Laccase Polyphenolic Biosensor Supported on MnO2@GNP Decorated SPCE: Preparation, Characterization, and Analytical Application | |
dc.type | article | en |
dc.rights.license | ARR | |
dcterms.abstract | Станковић, Далибор; Ђурђић, Слађана З.; Влаховић, Филип; Огњановић, Милош; Калцхер, К.; Ћирковић-Величковић, Тања; Мутић, Јелена; Станковић, В.; | |
dc.citation.volume | 168 | |
dc.citation.issue | 3 | |
dc.citation.spage | 037510 | |
dc.identifier.wos | 000629756800001 | |
dc.identifier.doi | 10.1149/1945-7111/abeaf2 | |
dc.citation.rank | M21~ | |
dc.description.other | The peer-review version: [https://cherry.chem.bg.ac.rs/handle/123456789/4475] | |
dc.type.version | publishedVersion | |
dc.identifier.scopus | 2-s2.0-85103235625 |