Artificial cellulose standards as calibration standards for wavelength-dispersive X-ray fluorescence analysis of elements in plant samples
Samo za registrovane korisnike
2021
Autori
Orlić, JovanaGržetić, Ivan
Goessler, Walter
Braeuer, Simone
Čáslavský, Josef
Pořízka, Jaromír
Ilijević, Konstantin
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
This research explores the possibilities and limitations of WD-XRF, applied as a method for quantification of 20 elements in plant material, using spiked cellulose standards for calibration. Three different analytical methods were investigated: 1) standards created from pure spiked cellulose; 2) spiked cellulose mixed with 20% of binder and 3) spiked cellulose applied as a thin layer on an inert carrier. Sensitivity, linearity, limit of detection, limit of quantification, repeatability, intralaboratory reproducibility, and accuracy were determined and compared. The accuracy of the investigated methods was tested by analysis of standard reference materials and comparison with other routinely used analytical techniques (ICP-OES and ICP-MS). The comparison included real plant samples which were collected from the environment characterized by different pollution levels. The accuracy of the semiquantitative standardless method was also considered and compared with other investigated methods.... Tested methods can be very precise, with good intralaboratory reproducibility over wide linear range.
Ključne reči:
Accuracy / Green chemistry / Method comparison / Precision / Sample preparation / WD-XRFIzvor:
Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 2021, 502, 106-117Izdavač:
- Elsevier
Finansiranje / projekti:
- Ministarstvo nauke, tehnološkog razvoja i inovacija Republike Srbije, institucionalno finansiranje - 200168 (Univerzitet u Beogradu, Hemijski fakultet) (RS-MESTD-inst-2020-200168)
- Geohemijska ispitivanja sedimentnih stena - fosilna goriva i zagađivači životne sredine (RS-MESTD-Basic Research (BR or ON)-176006)
Napomena:
- Supplementary material: https://cherry.chem.bg.ac.rs/handle/123456789/4615
Povezane informacije:
DOI: 10.1016/j.nimb.2021.06.012
ISSN: 0168-583X
WoS: 000678559800001
Scopus: 2-s2.0-85108994809
URI
https://www.sciencedirect.com/science/article/pii/S0168583X21002238https://cherry.chem.bg.ac.rs/handle/123456789/4614
Kolekcije
Institucija/grupa
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Orlić, Jovana AU - Gržetić, Ivan AU - Goessler, Walter AU - Braeuer, Simone AU - Čáslavský, Josef AU - Pořízka, Jaromír AU - Ilijević, Konstantin PY - 2021 UR - https://www.sciencedirect.com/science/article/pii/S0168583X21002238 UR - https://cherry.chem.bg.ac.rs/handle/123456789/4614 AB - This research explores the possibilities and limitations of WD-XRF, applied as a method for quantification of 20 elements in plant material, using spiked cellulose standards for calibration. Three different analytical methods were investigated: 1) standards created from pure spiked cellulose; 2) spiked cellulose mixed with 20% of binder and 3) spiked cellulose applied as a thin layer on an inert carrier. Sensitivity, linearity, limit of detection, limit of quantification, repeatability, intralaboratory reproducibility, and accuracy were determined and compared. The accuracy of the investigated methods was tested by analysis of standard reference materials and comparison with other routinely used analytical techniques (ICP-OES and ICP-MS). The comparison included real plant samples which were collected from the environment characterized by different pollution levels. The accuracy of the semiquantitative standardless method was also considered and compared with other investigated methods. Tested methods can be very precise, with good intralaboratory reproducibility over wide linear range. PB - Elsevier T2 - Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms T1 - Artificial cellulose standards as calibration standards for wavelength-dispersive X-ray fluorescence analysis of elements in plant samples VL - 502 SP - 106 EP - 117 DO - 10.1016/j.nimb.2021.06.012 ER -
@article{ author = "Orlić, Jovana and Gržetić, Ivan and Goessler, Walter and Braeuer, Simone and Čáslavský, Josef and Pořízka, Jaromír and Ilijević, Konstantin", year = "2021", abstract = "This research explores the possibilities and limitations of WD-XRF, applied as a method for quantification of 20 elements in plant material, using spiked cellulose standards for calibration. Three different analytical methods were investigated: 1) standards created from pure spiked cellulose; 2) spiked cellulose mixed with 20% of binder and 3) spiked cellulose applied as a thin layer on an inert carrier. Sensitivity, linearity, limit of detection, limit of quantification, repeatability, intralaboratory reproducibility, and accuracy were determined and compared. The accuracy of the investigated methods was tested by analysis of standard reference materials and comparison with other routinely used analytical techniques (ICP-OES and ICP-MS). The comparison included real plant samples which were collected from the environment characterized by different pollution levels. The accuracy of the semiquantitative standardless method was also considered and compared with other investigated methods. Tested methods can be very precise, with good intralaboratory reproducibility over wide linear range.", publisher = "Elsevier", journal = "Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms", title = "Artificial cellulose standards as calibration standards for wavelength-dispersive X-ray fluorescence analysis of elements in plant samples", volume = "502", pages = "106-117", doi = "10.1016/j.nimb.2021.06.012" }
Orlić, J., Gržetić, I., Goessler, W., Braeuer, S., Čáslavský, J., Pořízka, J.,& Ilijević, K.. (2021). Artificial cellulose standards as calibration standards for wavelength-dispersive X-ray fluorescence analysis of elements in plant samples. in Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms Elsevier., 502, 106-117. https://doi.org/10.1016/j.nimb.2021.06.012
Orlić J, Gržetić I, Goessler W, Braeuer S, Čáslavský J, Pořízka J, Ilijević K. Artificial cellulose standards as calibration standards for wavelength-dispersive X-ray fluorescence analysis of elements in plant samples. in Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms. 2021;502:106-117. doi:10.1016/j.nimb.2021.06.012 .
Orlić, Jovana, Gržetić, Ivan, Goessler, Walter, Braeuer, Simone, Čáslavský, Josef, Pořízka, Jaromír, Ilijević, Konstantin, "Artificial cellulose standards as calibration standards for wavelength-dispersive X-ray fluorescence analysis of elements in plant samples" in Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 502 (2021):106-117, https://doi.org/10.1016/j.nimb.2021.06.012 . .