Meridional geometrical isomers of cobalt(III) complexes with sarcosine (N-methylglycine) and tetradentate ligands edda (ethylenediamine-N, N ' -diacetate ion), eddp (ethylenediamine-N, N ' -di-3-propionate ion) and 1,3-pdda (1, 3-propylenediamine-N,N ' -diacetate ion) have been prepared. The edda and eddp cobalt(III) complexes were made by the reaction of sarcosine and sodium ethylenediamine-N, N ' -diacetato(carbonato)cobaltate(III), and sodium uns-cis-(ethylenediamine-N,, N ' -di-3-propionato)(carbonato)cobaltate(III) dihydrate, respectively. The previously synthesized pdda-cobalt(III) complex with sarcosine was obtained by a new route by direct synthesis of cobalt(II) chloride hexahydrate with sarcosine and 1,3-pdda in the presents of lead(IV) oxide. Complexes were isolated chromatographically and characterized by elemental analysis, electron absorption spectra, infrared spectra and H-1 NMR spectroscopy.
Keywords:
cobalt (II) complexes / edda type ligands / sarcosine
Source:
Journal of Coordination Chemistry, 2001, 53, 4, 355-363
Publisher:
Gordon Breach Publishing, Taylor & Francis Group, Philadelphia
TY - JOUR
AU - Dinovic, VM
AU - Grgurić-Šipka, Sanja
AU - Xu, XY
AU - Sabo, Tibor
PY - 2001
UR - https://cherry.chem.bg.ac.rs/handle/123456789/463
AB - Meridional geometrical isomers of cobalt(III) complexes with sarcosine (N-methylglycine) and tetradentate ligands edda (ethylenediamine-N, N ' -diacetate ion), eddp (ethylenediamine-N, N ' -di-3-propionate ion) and 1,3-pdda (1, 3-propylenediamine-N,N ' -diacetate ion) have been prepared. The edda and eddp cobalt(III) complexes were made by the reaction of sarcosine and sodium ethylenediamine-N, N ' -diacetato(carbonato)cobaltate(III), and sodium uns-cis-(ethylenediamine-N,, N ' -di-3-propionato)(carbonato)cobaltate(III) dihydrate, respectively. The previously synthesized pdda-cobalt(III) complex with sarcosine was obtained by a new route by direct synthesis of cobalt(II) chloride hexahydrate with sarcosine and 1,3-pdda in the presents of lead(IV) oxide. Complexes were isolated chromatographically and characterized by elemental analysis, electron absorption spectra, infrared spectra and H-1 NMR spectroscopy.
PB - Gordon Breach Publishing, Taylor & Francis Group, Philadelphia
T2 - Journal of Coordination Chemistry
T1 - Preparation and characterization of cobalt(III) complexes with sarcosine and some tetradentate ligands of the edda type
VL - 53
IS - 4
SP - 355
EP - 363
DO - 10.1080/00958970108022622
UR - Kon_1437
ER -
@article{
author = "Dinovic, VM and Grgurić-Šipka, Sanja and Xu, XY and Sabo, Tibor",
year = "2001",
abstract = "Meridional geometrical isomers of cobalt(III) complexes with sarcosine (N-methylglycine) and tetradentate ligands edda (ethylenediamine-N, N ' -diacetate ion), eddp (ethylenediamine-N, N ' -di-3-propionate ion) and 1,3-pdda (1, 3-propylenediamine-N,N ' -diacetate ion) have been prepared. The edda and eddp cobalt(III) complexes were made by the reaction of sarcosine and sodium ethylenediamine-N, N ' -diacetato(carbonato)cobaltate(III), and sodium uns-cis-(ethylenediamine-N,, N ' -di-3-propionato)(carbonato)cobaltate(III) dihydrate, respectively. The previously synthesized pdda-cobalt(III) complex with sarcosine was obtained by a new route by direct synthesis of cobalt(II) chloride hexahydrate with sarcosine and 1,3-pdda in the presents of lead(IV) oxide. Complexes were isolated chromatographically and characterized by elemental analysis, electron absorption spectra, infrared spectra and H-1 NMR spectroscopy.",
publisher = "Gordon Breach Publishing, Taylor & Francis Group, Philadelphia",
journal = "Journal of Coordination Chemistry",
title = "Preparation and characterization of cobalt(III) complexes with sarcosine and some tetradentate ligands of the edda type",
volume = "53",
number = "4",
pages = "355-363",
doi = "10.1080/00958970108022622",
url = "Kon_1437"
}
Dinovic, V., Grgurić-Šipka, S., Xu, X.,& Sabo, T.. (2001). Preparation and characterization of cobalt(III) complexes with sarcosine and some tetradentate ligands of the edda type. in Journal of Coordination Chemistry
Gordon Breach Publishing, Taylor & Francis Group, Philadelphia., 53(4), 355-363.
https://doi.org/10.1080/00958970108022622
Kon_1437
Dinovic V, Grgurić-Šipka S, Xu X, Sabo T. Preparation and characterization of cobalt(III) complexes with sarcosine and some tetradentate ligands of the edda type. in Journal of Coordination Chemistry. 2001;53(4):355-363.
doi:10.1080/00958970108022622
Kon_1437 .
Dinovic, VM, Grgurić-Šipka, Sanja, Xu, XY, Sabo, Tibor, "Preparation and characterization of cobalt(III) complexes with sarcosine and some tetradentate ligands of the edda type" in Journal of Coordination Chemistry, 53, no. 4 (2001):355-363,
https://doi.org/10.1080/00958970108022622 .,
Kon_1437 .
