Preparation and characterization of cobalt(III) complexes with sarcosine and some tetradentate ligands of the edda type
Abstract
Meridional geometrical isomers of cobalt(III) complexes with sarcosine (N-methylglycine) and tetradentate ligands edda (ethylenediamine-N, N ' -diacetate ion), eddp (ethylenediamine-N, N ' -di-3-propionate ion) and 1,3-pdda (1, 3-propylenediamine-N,N ' -diacetate ion) have been prepared. The edda and eddp cobalt(III) complexes were made by the reaction of sarcosine and sodium ethylenediamine-N, N ' -diacetato(carbonato)cobaltate(III), and sodium uns-cis-(ethylenediamine-N,, N ' -di-3-propionato)(carbonato)cobaltate(III) dihydrate, respectively. The previously synthesized pdda-cobalt(III) complex with sarcosine was obtained by a new route by direct synthesis of cobalt(II) chloride hexahydrate with sarcosine and 1,3-pdda in the presents of lead(IV) oxide. Complexes were isolated chromatographically and characterized by elemental analysis, electron absorption spectra, infrared spectra and H-1 NMR spectroscopy.
Keywords:
cobalt (II) complexes / edda type ligands / sarcosineSource:
Journal of Coordination Chemistry, 2001, 53, 4, 355-363Publisher:
- Gordon Breach Publishing, Taylor & Francis Group, Philadelphia
DOI: 10.1080/00958970108022622
ISSN: 0095-8972
WoS: 000170024600009
Scopus: 2-s2.0-0035552756
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Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Dinovic, VM AU - Grgurić-Šipka, Sanja AU - Xu, XY AU - Sabo, Tibor PY - 2001 UR - https://cherry.chem.bg.ac.rs/handle/123456789/463 AB - Meridional geometrical isomers of cobalt(III) complexes with sarcosine (N-methylglycine) and tetradentate ligands edda (ethylenediamine-N, N ' -diacetate ion), eddp (ethylenediamine-N, N ' -di-3-propionate ion) and 1,3-pdda (1, 3-propylenediamine-N,N ' -diacetate ion) have been prepared. The edda and eddp cobalt(III) complexes were made by the reaction of sarcosine and sodium ethylenediamine-N, N ' -diacetato(carbonato)cobaltate(III), and sodium uns-cis-(ethylenediamine-N,, N ' -di-3-propionato)(carbonato)cobaltate(III) dihydrate, respectively. The previously synthesized pdda-cobalt(III) complex with sarcosine was obtained by a new route by direct synthesis of cobalt(II) chloride hexahydrate with sarcosine and 1,3-pdda in the presents of lead(IV) oxide. Complexes were isolated chromatographically and characterized by elemental analysis, electron absorption spectra, infrared spectra and H-1 NMR spectroscopy. PB - Gordon Breach Publishing, Taylor & Francis Group, Philadelphia T2 - Journal of Coordination Chemistry T1 - Preparation and characterization of cobalt(III) complexes with sarcosine and some tetradentate ligands of the edda type VL - 53 IS - 4 SP - 355 EP - 363 DO - 10.1080/00958970108022622 ER -
@article{ author = "Dinovic, VM and Grgurić-Šipka, Sanja and Xu, XY and Sabo, Tibor", year = "2001", abstract = "Meridional geometrical isomers of cobalt(III) complexes with sarcosine (N-methylglycine) and tetradentate ligands edda (ethylenediamine-N, N ' -diacetate ion), eddp (ethylenediamine-N, N ' -di-3-propionate ion) and 1,3-pdda (1, 3-propylenediamine-N,N ' -diacetate ion) have been prepared. The edda and eddp cobalt(III) complexes were made by the reaction of sarcosine and sodium ethylenediamine-N, N ' -diacetato(carbonato)cobaltate(III), and sodium uns-cis-(ethylenediamine-N,, N ' -di-3-propionato)(carbonato)cobaltate(III) dihydrate, respectively. The previously synthesized pdda-cobalt(III) complex with sarcosine was obtained by a new route by direct synthesis of cobalt(II) chloride hexahydrate with sarcosine and 1,3-pdda in the presents of lead(IV) oxide. Complexes were isolated chromatographically and characterized by elemental analysis, electron absorption spectra, infrared spectra and H-1 NMR spectroscopy.", publisher = "Gordon Breach Publishing, Taylor & Francis Group, Philadelphia", journal = "Journal of Coordination Chemistry", title = "Preparation and characterization of cobalt(III) complexes with sarcosine and some tetradentate ligands of the edda type", volume = "53", number = "4", pages = "355-363", doi = "10.1080/00958970108022622" }
Dinovic, V., Grgurić-Šipka, S., Xu, X.,& Sabo, T.. (2001). Preparation and characterization of cobalt(III) complexes with sarcosine and some tetradentate ligands of the edda type. in Journal of Coordination Chemistry Gordon Breach Publishing, Taylor & Francis Group, Philadelphia., 53(4), 355-363. https://doi.org/10.1080/00958970108022622
Dinovic V, Grgurić-Šipka S, Xu X, Sabo T. Preparation and characterization of cobalt(III) complexes with sarcosine and some tetradentate ligands of the edda type. in Journal of Coordination Chemistry. 2001;53(4):355-363. doi:10.1080/00958970108022622 .
Dinovic, VM, Grgurić-Šipka, Sanja, Xu, XY, Sabo, Tibor, "Preparation and characterization of cobalt(III) complexes with sarcosine and some tetradentate ligands of the edda type" in Journal of Coordination Chemistry, 53, no. 4 (2001):355-363, https://doi.org/10.1080/00958970108022622 . .