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dc.creatorMitrović, Aleksandra
dc.creatorAbellán, Gonzalo
dc.creatorHirsch, Andreas
dc.date.accessioned2021-10-21T10:36:13Z
dc.date.available2021-10-21T10:36:13Z
dc.date.issued2021
dc.identifier.issn2046-2069
dc.identifier.urihttps://cherry.chem.bg.ac.rs/handle/123456789/4741
dc.description.abstractThe post-graphene era is undoubtedly marked by two-dimensional (2D) sheet polymers, such as black phosphorus (BP). This emerging material has a fascinating structure and outstanding electronic properties and has been postulated for a plethora of applications. The need to circumvent the pronounced oxophilicity of P atoms has dominated the research on this material in recent years, with the objective of finding the most effective method to improve its environmental stability. When it comes to chemical functionalization, the few approaches reported so far involve some drawbacks such as low degree of addition and low production ability. This review presents the concepts and strategies of our studies on the chemical functionalization of BP, both non-covalent and covalent, emphazising the current synthetic challenges. Moreover, we also provide some effective pathways for the chemical activation of the unreactive basal plane, the identification of the effective binding strategies, and the concept to overcome hurdles associated with characterization tools. This work will provide fundamental insights into the controlled chemical functionalization and characterization of BP, fostering the research on this appealing 2D material.
dc.languageen
dc.publisherRoyal Society of Chemistry
dc.relationEuropean Research Council (ERC) No. 804110
dc.relationEuropean Commission (742145,604391)
dc.relationSpanish Government (CEX2019-000919-M, PID2019-111742GA-I00)
dc.relationGeneralitat Valenciana (CIDEGENT/2018/001 and iDiFEDER/2018/061)
dc.relationGerman Research Foundation (DFG) No. FLAG-ERA AB694/2-1 and SFB 953
dc.rightsopenAccess
dc.rights.urihttps://creativecommons.org/licenses/by-nc/4.0/
dc.sourceRSC Advances
dc.sourceRSC AdvancesRSC Adv.
dc.titleCovalent and non-covalent chemistry of 2D black phosphorus
dc.typearticleen
dc.rights.licenseBY-NC
dcterms.abstractХирсцх, Aндреас; Aбеллáн, Гонзало; Митровић, Aлександра;
dc.citation.volume11
dc.citation.issue42
dc.citation.spage26093
dc.citation.epage26101
dc.identifier.wos000680655300031
dc.identifier.doi10.1039/D1RA04416H
dc.citation.rankM22~
dc.identifier.pmid34381597
dc.type.versionpublishedVersion
dc.identifier.scopus2-s2.0-85111910378
dc.identifier.fulltexthttps://cherry.chem.bg.ac.rs/bitstream/id/28449/Covalent_and_non-covalent_pub_2021.pdf


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