Synthesis and characterization of tris[butyl-(1-methyl-3-phenyl-propyl)-dithiocarbamato]-cobalt(III) seskvitoluene

Abstract

A new bidentate ligand butyl-(1-methyl-3-phenyl-propyl)-dithiocarbamate (bmPhipdtc) was prepared, as the sodium salt. In the reaction of hexaaminecobalt(III) chloride with NabmPhipdtc, the corresponding tris[butyl-(1-methyl-3-phenyl-propyl)-dithiocarbamato]cobalt(III), [Co(bmPhipdtc)(3)] complex was prepared. The complex was characterized by elemental analysis, infrared, electronic absorption, H-1 and C-13-NMR spectroscopy.

Sintetisan je novi bidentatni ligand butil-(1-metil-3-fenil-propil)-ditiokarbamat (bmΦpdtc), kao natrijumova so. Reakcijom heksaamminkobalt(III)-hlorida i navedenog liganda dobijen je odgovarajući kompleks tris[butil-(1-metil-3-fenil-propil) ditiokarbamato]kobalt(III), [Co(bmΦpdtc)3]. Kompleks je okarakterisan elementalnom analizom, infracrvenim, elektronsko-apsorpcionim, 1H i 13C-NMR spektrima.