Synthesis of MnCo2O4 as modifiers for simultaneous determination of Pb(II) and Cd(II)
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The porous spinel oxide nanoparticles, MnCo2O4, were synthesized by citrate gel combustion
technique. Morphology, crystallinity and Co/Mn content of modified electrode was characterized
and determined by Fourier transform infra-red spectroscopy (FT-IR), scanning
electron microscopy (SEM), energy dispersive spectrometry (EDS), X-ray diffraction pattern
analysis (XRD), simultaneous thermogravimetry and differential thermal analysis (TG/DTA).
Nanoparticles were used for modification of glassy carbon electrode (GCE) and new sensor
was applied for simultaneous determination of Pb(II) and Cd(II) ions in water samples with
the linear sweep anodic stripping voltammetry (LSASV).The factors such as pH, deposition
potential and deposition time are optimized. Under optimal conditions the wide linear concentration
range from 0.05 to 40 μmol/dm3was obtained for Pb(II), with limit of detection
(LOD) of 8.06 nmol/dm3 and two linear concentration ranges were obtained for Cd(II), from
0.05 to... 1.6 μmol/dm3 and from 1.6 to 40 μmol/dm3, with calculated LOD of 7.02 nmol/dm3.
The selectivity of the new sensor was investigated in the presence of interfering ions. The
sensor is stable and it gave reproducible results. The new sensor was succesfully applied
on determination of heavy metals in natural waters.
Izvor:
PLOS ONE, 2019, 14, 2, 1-19Izdavač:
- PLOS
DOI: 10.1371/journal.pone.0210904
ISSN: 1932-6203
WoS: 000457874000037
Scopus: 2-s2.0-85061121718
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Institucija/grupa
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Antunović, Vesna R. AU - Ilić, Marija AU - Baošić, Rada AU - Jelić, Dijana AU - Lolić, Aleksandar PY - 2019 UR - http://cherry.chem.bg.ac.rs/handle/123456789/4987 AB - The porous spinel oxide nanoparticles, MnCo2O4, were synthesized by citrate gel combustion technique. Morphology, crystallinity and Co/Mn content of modified electrode was characterized and determined by Fourier transform infra-red spectroscopy (FT-IR), scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), X-ray diffraction pattern analysis (XRD), simultaneous thermogravimetry and differential thermal analysis (TG/DTA). Nanoparticles were used for modification of glassy carbon electrode (GCE) and new sensor was applied for simultaneous determination of Pb(II) and Cd(II) ions in water samples with the linear sweep anodic stripping voltammetry (LSASV).The factors such as pH, deposition potential and deposition time are optimized. Under optimal conditions the wide linear concentration range from 0.05 to 40 μmol/dm3was obtained for Pb(II), with limit of detection (LOD) of 8.06 nmol/dm3 and two linear concentration ranges were obtained for Cd(II), from 0.05 to 1.6 μmol/dm3 and from 1.6 to 40 μmol/dm3, with calculated LOD of 7.02 nmol/dm3. The selectivity of the new sensor was investigated in the presence of interfering ions. The sensor is stable and it gave reproducible results. The new sensor was succesfully applied on determination of heavy metals in natural waters. PB - PLOS T2 - PLOS ONE T1 - Synthesis of MnCo2O4 as modifiers for simultaneous determination of Pb(II) and Cd(II) VL - 14 IS - 2 SP - 1 EP - 19 DO - 10.1371/journal.pone.0210904 ER -
@article{ author = "Antunović, Vesna R. and Ilić, Marija and Baošić, Rada and Jelić, Dijana and Lolić, Aleksandar", year = "2019", abstract = "The porous spinel oxide nanoparticles, MnCo2O4, were synthesized by citrate gel combustion technique. Morphology, crystallinity and Co/Mn content of modified electrode was characterized and determined by Fourier transform infra-red spectroscopy (FT-IR), scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), X-ray diffraction pattern analysis (XRD), simultaneous thermogravimetry and differential thermal analysis (TG/DTA). Nanoparticles were used for modification of glassy carbon electrode (GCE) and new sensor was applied for simultaneous determination of Pb(II) and Cd(II) ions in water samples with the linear sweep anodic stripping voltammetry (LSASV).The factors such as pH, deposition potential and deposition time are optimized. Under optimal conditions the wide linear concentration range from 0.05 to 40 μmol/dm3was obtained for Pb(II), with limit of detection (LOD) of 8.06 nmol/dm3 and two linear concentration ranges were obtained for Cd(II), from 0.05 to 1.6 μmol/dm3 and from 1.6 to 40 μmol/dm3, with calculated LOD of 7.02 nmol/dm3. The selectivity of the new sensor was investigated in the presence of interfering ions. The sensor is stable and it gave reproducible results. The new sensor was succesfully applied on determination of heavy metals in natural waters.", publisher = "PLOS", journal = "PLOS ONE", title = "Synthesis of MnCo2O4 as modifiers for simultaneous determination of Pb(II) and Cd(II)", volume = "14", number = "2", pages = "1-19", doi = "10.1371/journal.pone.0210904" }
Antunović, V. R., Ilić, M., Baošić, R., Jelić, D.,& Lolić, A.. (2019). Synthesis of MnCo2O4 as modifiers for simultaneous determination of Pb(II) and Cd(II). in PLOS ONE PLOS., 14(2), 1-19. https://doi.org/10.1371/journal.pone.0210904
Antunović VR, Ilić M, Baošić R, Jelić D, Lolić A. Synthesis of MnCo2O4 as modifiers for simultaneous determination of Pb(II) and Cd(II). in PLOS ONE. 2019;14(2):1-19. doi:10.1371/journal.pone.0210904 .
Antunović, Vesna R., Ilić, Marija, Baošić, Rada, Jelić, Dijana, Lolić, Aleksandar, "Synthesis of MnCo2O4 as modifiers for simultaneous determination of Pb(II) and Cd(II)" in PLOS ONE, 14, no. 2 (2019):1-19, https://doi.org/10.1371/journal.pone.0210904 . .