Comparison of non-destructive techniques and conventionally used spectrometric techniques for determination of elements in plant samples (coniferous leaves)
Аутори
Orlić, JovanaAničić-Urošević, Mira
Vergel, Konstantin
Zinicovscaia, Inga
Stojadinović, Sanja M.
Gržetić, Ivan
Ilijević, Konstantin
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Conventionally used spectrometric techniques of inductively coupled plasma optical emission spectrometry (ICP-OES) and inductively coupled plasma optical emission spectrometry (ICP-MS) usually involve time-consuming sample preparation procedure of a sample dissolution which requires the usage of aggressive and toxic chemicals. The need for suitable and sustainable analytical methods for direct multi-elemental analysis of plant samples has been increased in recent years. Spectrometric techniques for direct sample analysis, instrumental neutron activation analysis (INAA) and X-ray fluorescence (XRF) have been applied in environmental studies and various fields of screening tests. Nevertheless, these techniques are not commonly used for plant sample analysis and their performances need to be evaluated. This research aimed to assess how reliable non-destructive techniques are in the determination of elements in plants compared to conventionally used spectrometric techniques. A total of 49 ...plant samples of four conifer species (Pinus nigra, Abies alba, Taxus baccata and Larix decidua) were measured using two conventionally applied (ICP-MS, ICP-OES) and two non-destructive techniques (wavelength dispersive XRF (WD-XRF), INAA). The comparison was performed by investigation of relative ratios of concentrations and by correlation analysis. Moreover, precision of the techniques was examined and compared. The quality control included analysis of NIST pine needles certified reference material (1575a) using all examined techniques. Our results suggest that additional analytical and quality control steps are necessary for reaching the highest accuracy of multi-elemental analysis.
Кључне речи:
multi-element determination / WD-XRF / standardless analysis / INAA / ICP-OES / ICP-MSИзвор:
Journal of the Serbian Chemical Society, 2022, 87, 1, 69-81Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200168 (Универзитет у Београду, Хемијски факултет) (RS-MESTD-inst-2020-200168)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200026 (Универзитет у Београду, Институт за хемију, технологију и металургију - ИХТМ) (RS-MESTD-inst-2020-200026)
DOI: 10.2298/JSC210921101O
ISSN: 0352-5139
WoS: 000768809100007
Scopus: 2-s2.0-85124474681
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Orlić, Jovana AU - Aničić-Urošević, Mira AU - Vergel, Konstantin AU - Zinicovscaia, Inga AU - Stojadinović, Sanja M. AU - Gržetić, Ivan AU - Ilijević, Konstantin PY - 2022 UR - http://cherry.chem.bg.ac.rs/handle/123456789/5007 AB - Conventionally used spectrometric techniques of inductively coupled plasma optical emission spectrometry (ICP-OES) and inductively coupled plasma optical emission spectrometry (ICP-MS) usually involve time-consuming sample preparation procedure of a sample dissolution which requires the usage of aggressive and toxic chemicals. The need for suitable and sustainable analytical methods for direct multi-elemental analysis of plant samples has been increased in recent years. Spectrometric techniques for direct sample analysis, instrumental neutron activation analysis (INAA) and X-ray fluorescence (XRF) have been applied in environmental studies and various fields of screening tests. Nevertheless, these techniques are not commonly used for plant sample analysis and their performances need to be evaluated. This research aimed to assess how reliable non-destructive techniques are in the determination of elements in plants compared to conventionally used spectrometric techniques. A total of 49 plant samples of four conifer species (Pinus nigra, Abies alba, Taxus baccata and Larix decidua) were measured using two conventionally applied (ICP-MS, ICP-OES) and two non-destructive techniques (wavelength dispersive XRF (WD-XRF), INAA). The comparison was performed by investigation of relative ratios of concentrations and by correlation analysis. Moreover, precision of the techniques was examined and compared. The quality control included analysis of NIST pine needles certified reference material (1575a) using all examined techniques. Our results suggest that additional analytical and quality control steps are necessary for reaching the highest accuracy of multi-elemental analysis. T2 - Journal of the Serbian Chemical Society T1 - Comparison of non-destructive techniques and conventionally used spectrometric techniques for determination of elements in plant samples (coniferous leaves) VL - 87 IS - 1 SP - 69 EP - 81 DO - 10.2298/JSC210921101O ER -
@article{ author = "Orlić, Jovana and Aničić-Urošević, Mira and Vergel, Konstantin and Zinicovscaia, Inga and Stojadinović, Sanja M. and Gržetić, Ivan and Ilijević, Konstantin", year = "2022", abstract = "Conventionally used spectrometric techniques of inductively coupled plasma optical emission spectrometry (ICP-OES) and inductively coupled plasma optical emission spectrometry (ICP-MS) usually involve time-consuming sample preparation procedure of a sample dissolution which requires the usage of aggressive and toxic chemicals. The need for suitable and sustainable analytical methods for direct multi-elemental analysis of plant samples has been increased in recent years. Spectrometric techniques for direct sample analysis, instrumental neutron activation analysis (INAA) and X-ray fluorescence (XRF) have been applied in environmental studies and various fields of screening tests. Nevertheless, these techniques are not commonly used for plant sample analysis and their performances need to be evaluated. This research aimed to assess how reliable non-destructive techniques are in the determination of elements in plants compared to conventionally used spectrometric techniques. A total of 49 plant samples of four conifer species (Pinus nigra, Abies alba, Taxus baccata and Larix decidua) were measured using two conventionally applied (ICP-MS, ICP-OES) and two non-destructive techniques (wavelength dispersive XRF (WD-XRF), INAA). The comparison was performed by investigation of relative ratios of concentrations and by correlation analysis. Moreover, precision of the techniques was examined and compared. The quality control included analysis of NIST pine needles certified reference material (1575a) using all examined techniques. Our results suggest that additional analytical and quality control steps are necessary for reaching the highest accuracy of multi-elemental analysis.", journal = "Journal of the Serbian Chemical Society", title = "Comparison of non-destructive techniques and conventionally used spectrometric techniques for determination of elements in plant samples (coniferous leaves)", volume = "87", number = "1", pages = "69-81", doi = "10.2298/JSC210921101O" }
Orlić, J., Aničić-Urošević, M., Vergel, K., Zinicovscaia, I., Stojadinović, S. M., Gržetić, I.,& Ilijević, K.. (2022). Comparison of non-destructive techniques and conventionally used spectrometric techniques for determination of elements in plant samples (coniferous leaves). in Journal of the Serbian Chemical Society, 87(1), 69-81. https://doi.org/10.2298/JSC210921101O
Orlić J, Aničić-Urošević M, Vergel K, Zinicovscaia I, Stojadinović SM, Gržetić I, Ilijević K. Comparison of non-destructive techniques and conventionally used spectrometric techniques for determination of elements in plant samples (coniferous leaves). in Journal of the Serbian Chemical Society. 2022;87(1):69-81. doi:10.2298/JSC210921101O .
Orlić, Jovana, Aničić-Urošević, Mira, Vergel, Konstantin, Zinicovscaia, Inga, Stojadinović, Sanja M., Gržetić, Ivan, Ilijević, Konstantin, "Comparison of non-destructive techniques and conventionally used spectrometric techniques for determination of elements in plant samples (coniferous leaves)" in Journal of the Serbian Chemical Society, 87, no. 1 (2022):69-81, https://doi.org/10.2298/JSC210921101O . .