Crystal structure and modeling calculation of the columnar helix 2,6-Bis(imino)phenoxy iron(III) chloride
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Crystal structure of novel bis(imino)phenoxychloro-iron(III) chloride demonstrated a columnar helix through hydrogen bonding of anion-cation molecules and intermolecular pi-pi interactions, along with the syntheses and characterization of the new compounds. A quantum-chemical single point calculations of the interaction energies were performed on the basis of the X-ray structural data. (C) 2002 Elsevier Science B.V. All rights reserved.
Keywords:self-assembly / ion pair / columnar helix / pi-pi interaction
Source:Inorganic Chemistry Communications, 2003, 6, 1, 5-9
- Elsevier Science Bv, Amsterdam