Investigation of thermal stability and kinetics of thermal degradation of meridional isomers of aminocarboxylato cobalt(III) complexes
Само за регистроване кориснике
2003
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The thermal properties of some mixed complexes of cobalt(III) containing tetradentate ethylenediamine-N,N'-di-3-propionate (eddp) ligand and several amino acids were investigated by thermogravimetry (TG) and differential scanning calorimetry (DSC). The thermal stability derived from decomposition temperatures was discussed in terms of amino acid present. It was shown that the processes of thermal decomposition of these complexes are multi-step degradation processes. Some of these can be separated into individual steps. The corresponding kinetic and thermodynamic parameters of these processes were determined, and the possible mechanisms were discussed. (C) 2002 Elsevier Science B.V. All rights reserved.
Кључне речи:
cobalt(III) complexes / thermal analysis / kinetic studiesИзвор:
Thermochimica Acta, 2003, 399, 1-2, 145-152Издавач:
- Elsevier Science Bv, Amsterdam
DOI: 10.1016/S0040-6031(02)00458-6
ISSN: 0040-6031
WoS: 000181813900014
Scopus: 2-s2.0-0037463903
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Grgurić-Šipka, Sanja AU - Sabo, Tibor AU - Trifunović, Srećko R. AU - Minić, Dragica M. PY - 2003 UR - https://cherry.chem.bg.ac.rs/handle/123456789/545 AB - The thermal properties of some mixed complexes of cobalt(III) containing tetradentate ethylenediamine-N,N'-di-3-propionate (eddp) ligand and several amino acids were investigated by thermogravimetry (TG) and differential scanning calorimetry (DSC). The thermal stability derived from decomposition temperatures was discussed in terms of amino acid present. It was shown that the processes of thermal decomposition of these complexes are multi-step degradation processes. Some of these can be separated into individual steps. The corresponding kinetic and thermodynamic parameters of these processes were determined, and the possible mechanisms were discussed. (C) 2002 Elsevier Science B.V. All rights reserved. PB - Elsevier Science Bv, Amsterdam T2 - Thermochimica Acta T1 - Investigation of thermal stability and kinetics of thermal degradation of meridional isomers of aminocarboxylato cobalt(III) complexes VL - 399 IS - 1-2 SP - 145 EP - 152 DO - 10.1016/S0040-6031(02)00458-6 ER -
@article{ author = "Grgurić-Šipka, Sanja and Sabo, Tibor and Trifunović, Srećko R. and Minić, Dragica M.", year = "2003", abstract = "The thermal properties of some mixed complexes of cobalt(III) containing tetradentate ethylenediamine-N,N'-di-3-propionate (eddp) ligand and several amino acids were investigated by thermogravimetry (TG) and differential scanning calorimetry (DSC). The thermal stability derived from decomposition temperatures was discussed in terms of amino acid present. It was shown that the processes of thermal decomposition of these complexes are multi-step degradation processes. Some of these can be separated into individual steps. The corresponding kinetic and thermodynamic parameters of these processes were determined, and the possible mechanisms were discussed. (C) 2002 Elsevier Science B.V. All rights reserved.", publisher = "Elsevier Science Bv, Amsterdam", journal = "Thermochimica Acta", title = "Investigation of thermal stability and kinetics of thermal degradation of meridional isomers of aminocarboxylato cobalt(III) complexes", volume = "399", number = "1-2", pages = "145-152", doi = "10.1016/S0040-6031(02)00458-6" }
Grgurić-Šipka, S., Sabo, T., Trifunović, S. R.,& Minić, D. M.. (2003). Investigation of thermal stability and kinetics of thermal degradation of meridional isomers of aminocarboxylato cobalt(III) complexes. in Thermochimica Acta Elsevier Science Bv, Amsterdam., 399(1-2), 145-152. https://doi.org/10.1016/S0040-6031(02)00458-6
Grgurić-Šipka S, Sabo T, Trifunović SR, Minić DM. Investigation of thermal stability and kinetics of thermal degradation of meridional isomers of aminocarboxylato cobalt(III) complexes. in Thermochimica Acta. 2003;399(1-2):145-152. doi:10.1016/S0040-6031(02)00458-6 .
Grgurić-Šipka, Sanja, Sabo, Tibor, Trifunović, Srećko R., Minić, Dragica M., "Investigation of thermal stability and kinetics of thermal degradation of meridional isomers of aminocarboxylato cobalt(III) complexes" in Thermochimica Acta, 399, no. 1-2 (2003):145-152, https://doi.org/10.1016/S0040-6031(02)00458-6 . .