Vibrational spectra of (MMIII)-M-I S-2 type synthetic minerals (M-I = Tl or Ag and M-III = As or Sb)
Само за регистроване кориснике
2003
Аутори
Minceva-Sukarova, BJovanovski, G
Makreski, P
Soptrajanov, B
Griffith, W
Willis, R
Gržetić, Ivan
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The far infrared and Raman spectra of four (MMS2)-M-I-S-III type synthetic minerals (lorandite, TIAsS2; smithite, AgAsS2; weissbergite, TlSbS2, and miargyrite, AgSbS2) were studied at room temperature. Their vibrational spectra were compared with the corresponding far infrared and Raman spectra Of (M2S3)-S-III type minerals: orpiment, As2S3 and stibnite, Sb2S3. In spite of different crystal structure of these minerals, a similarity between the vibrational spectra of the three arsenic containing minerals (orpiment, As2S3; lorandite, TlAsS2 and smithite, AgAsS2), on the one hand, and the three antimony containing minerals (stibnite, Sb2S3; weissbergite, TlSbS2 and miargyrite, AgSbS2), on the other hand, has been detected. The observed spectral behavior was discussed in terms of structural similarities and differences between the minerals containing As atoms and the ones containing Sb atoms. Thus, the arsenic containing minerals are characterized by the layer-like structure and the presen...ce of rather similar As-S bond distances (208-236 pm), whereas the antimony containing minerals have sheet-like structure and the variety of Sb-S bond distances, spreading in a wider range of values (241-296 pm). (C) 2003 Elsevier Science B.V. All rights reserved.
Кључне речи:
Raman / far infrared spectra / arsenic and antimony containing sulfide mineralsИзвор:
Journal of Molecular Structure, 2003, 651, 181-189Издавач:
- Elsevier Science Bv, Amsterdam
DOI: 10.1016/S0022-2860(03)00105-4
ISSN: 0022-2860
WoS: 000183424200023
Scopus: 2-s2.0-0038070487
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Minceva-Sukarova, B AU - Jovanovski, G AU - Makreski, P AU - Soptrajanov, B AU - Griffith, W AU - Willis, R AU - Gržetić, Ivan PY - 2003 UR - https://cherry.chem.bg.ac.rs/handle/123456789/557 AB - The far infrared and Raman spectra of four (MMS2)-M-I-S-III type synthetic minerals (lorandite, TIAsS2; smithite, AgAsS2; weissbergite, TlSbS2, and miargyrite, AgSbS2) were studied at room temperature. Their vibrational spectra were compared with the corresponding far infrared and Raman spectra Of (M2S3)-S-III type minerals: orpiment, As2S3 and stibnite, Sb2S3. In spite of different crystal structure of these minerals, a similarity between the vibrational spectra of the three arsenic containing minerals (orpiment, As2S3; lorandite, TlAsS2 and smithite, AgAsS2), on the one hand, and the three antimony containing minerals (stibnite, Sb2S3; weissbergite, TlSbS2 and miargyrite, AgSbS2), on the other hand, has been detected. The observed spectral behavior was discussed in terms of structural similarities and differences between the minerals containing As atoms and the ones containing Sb atoms. Thus, the arsenic containing minerals are characterized by the layer-like structure and the presence of rather similar As-S bond distances (208-236 pm), whereas the antimony containing minerals have sheet-like structure and the variety of Sb-S bond distances, spreading in a wider range of values (241-296 pm). (C) 2003 Elsevier Science B.V. All rights reserved. PB - Elsevier Science Bv, Amsterdam T2 - Journal of Molecular Structure T1 - Vibrational spectra of (MMIII)-M-I S-2 type synthetic minerals (M-I = Tl or Ag and M-III = As or Sb) VL - 651 SP - 181 EP - 189 DO - 10.1016/S0022-2860(03)00105-4 ER -
@article{ author = "Minceva-Sukarova, B and Jovanovski, G and Makreski, P and Soptrajanov, B and Griffith, W and Willis, R and Gržetić, Ivan", year = "2003", abstract = "The far infrared and Raman spectra of four (MMS2)-M-I-S-III type synthetic minerals (lorandite, TIAsS2; smithite, AgAsS2; weissbergite, TlSbS2, and miargyrite, AgSbS2) were studied at room temperature. Their vibrational spectra were compared with the corresponding far infrared and Raman spectra Of (M2S3)-S-III type minerals: orpiment, As2S3 and stibnite, Sb2S3. In spite of different crystal structure of these minerals, a similarity between the vibrational spectra of the three arsenic containing minerals (orpiment, As2S3; lorandite, TlAsS2 and smithite, AgAsS2), on the one hand, and the three antimony containing minerals (stibnite, Sb2S3; weissbergite, TlSbS2 and miargyrite, AgSbS2), on the other hand, has been detected. The observed spectral behavior was discussed in terms of structural similarities and differences between the minerals containing As atoms and the ones containing Sb atoms. Thus, the arsenic containing minerals are characterized by the layer-like structure and the presence of rather similar As-S bond distances (208-236 pm), whereas the antimony containing minerals have sheet-like structure and the variety of Sb-S bond distances, spreading in a wider range of values (241-296 pm). (C) 2003 Elsevier Science B.V. All rights reserved.", publisher = "Elsevier Science Bv, Amsterdam", journal = "Journal of Molecular Structure", title = "Vibrational spectra of (MMIII)-M-I S-2 type synthetic minerals (M-I = Tl or Ag and M-III = As or Sb)", volume = "651", pages = "181-189", doi = "10.1016/S0022-2860(03)00105-4" }
Minceva-Sukarova, B., Jovanovski, G., Makreski, P., Soptrajanov, B., Griffith, W., Willis, R.,& Gržetić, I.. (2003). Vibrational spectra of (MMIII)-M-I S-2 type synthetic minerals (M-I = Tl or Ag and M-III = As or Sb). in Journal of Molecular Structure Elsevier Science Bv, Amsterdam., 651, 181-189. https://doi.org/10.1016/S0022-2860(03)00105-4
Minceva-Sukarova B, Jovanovski G, Makreski P, Soptrajanov B, Griffith W, Willis R, Gržetić I. Vibrational spectra of (MMIII)-M-I S-2 type synthetic minerals (M-I = Tl or Ag and M-III = As or Sb). in Journal of Molecular Structure. 2003;651:181-189. doi:10.1016/S0022-2860(03)00105-4 .
Minceva-Sukarova, B, Jovanovski, G, Makreski, P, Soptrajanov, B, Griffith, W, Willis, R, Gržetić, Ivan, "Vibrational spectra of (MMIII)-M-I S-2 type synthetic minerals (M-I = Tl or Ag and M-III = As or Sb)" in Journal of Molecular Structure, 651 (2003):181-189, https://doi.org/10.1016/S0022-2860(03)00105-4 . .