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dc.creatorMinceva-Sukarova, B
dc.creatorJovanovski, G
dc.creatorMakreski, P
dc.creatorSoptrajanov, B
dc.creatorGriffith, W
dc.creatorWillis, R
dc.creatorGržetić, Ivan
dc.date.accessioned2018-11-22T00:06:12Z
dc.date.available2018-11-22T00:06:12Z
dc.date.issued2003
dc.identifier.issn0022-2860
dc.identifier.urihttp://cherry.chem.bg.ac.rs/handle/123456789/557
dc.description.abstractThe far infrared and Raman spectra of four (MMS2)-M-I-S-III type synthetic minerals (lorandite, TIAsS2; smithite, AgAsS2; weissbergite, TlSbS2, and miargyrite, AgSbS2) were studied at room temperature. Their vibrational spectra were compared with the corresponding far infrared and Raman spectra Of (M2S3)-S-III type minerals: orpiment, As2S3 and stibnite, Sb2S3. In spite of different crystal structure of these minerals, a similarity between the vibrational spectra of the three arsenic containing minerals (orpiment, As2S3; lorandite, TlAsS2 and smithite, AgAsS2), on the one hand, and the three antimony containing minerals (stibnite, Sb2S3; weissbergite, TlSbS2 and miargyrite, AgSbS2), on the other hand, has been detected. The observed spectral behavior was discussed in terms of structural similarities and differences between the minerals containing As atoms and the ones containing Sb atoms. Thus, the arsenic containing minerals are characterized by the layer-like structure and the presence of rather similar As-S bond distances (208-236 pm), whereas the antimony containing minerals have sheet-like structure and the variety of Sb-S bond distances, spreading in a wider range of values (241-296 pm). (C) 2003 Elsevier Science B.V. All rights reserved.en
dc.publisherElsevier Science Bv, Amsterdam
dc.rightsrestrictedAccess
dc.sourceJournal of Molecular Structure
dc.subjectRamanen
dc.subjectfar infrared spectraen
dc.subjectarsenic and antimony containing sulfide mineralsen
dc.titleVibrational spectra of (MMIII)-M-I S-2 type synthetic minerals (M-I = Tl or Ag and M-III = As or Sb)en
dc.typearticle
dc.rights.licenseARR
dcterms.abstractСоптрајанов, Б; Гриффитх, W; Wиллис, Р; Јовановски, Г; Гржетић, Иван; Минцева-Сукарова, Б; Макрески, П;
dc.citation.volume651
dc.citation.spage181
dc.citation.epage189
dc.identifier.wos000183424200023
dc.identifier.doi10.1016/S0022-2860(03)00105-4
dc.citation.other651: 181-189
dc.citation.rankM23
dc.type.versionpublishedVersionen
dc.identifier.scopus2-s2.0-0038070487
dc.identifier.rcubKon_1531


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