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Complex compounds of platinum(IV) and O,O-dialkyl-ethylenediamine-N,N '-di-3-propanoate ligands. A structural evidence for geometry of hydrolytic product of some esters

Authorized Users Only
2004
Authors
Sabo, Tibor
Kaluđerović, Goran N.
Grgurić-Šipka, Sanja
Heinemann, FW
Trifunović, Srećko R.
Article (Published version)
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Abstract
Depending on the ester alkyl group, the reaction of O,O-dialkylethylenediamine-N,N'-di-3-propanoate ligands (R(2)eddp) with potassium hexachloroplatinate(IV) afforded trans-dichloro(ethylenediamine-N,N'-di-3-propanoato)platinum(IV) and tetrachloro(O,O-dialkyl-ethylenediamine-N,N'-di-3-propanoato)platinum(IV) complexes. The complexes were characterized by elemental analysis, electronic absorption, infrared, H-1 and C-13 NMR spectroscopy. The trans configuration of [Pt(eddp)Cl-2] complex was confirmed by X-ray crystallography. (C) 2003 Elsevier B.V. All rights reserved.
Keywords:
platinum(IV) / tetradentate ligands / bidentate ligands / eddp
Source:
Inorganic Chemistry Communications, 2004, 7, 2, 241-244
Publisher:
  • Elsevier Science Bv, Amsterdam

DOI: 10.1016/j.inoche.2003.11.007

ISSN: 1387-7003

WoS: 000188859000026

Scopus: 2-s2.0-0842299401
[ Google Scholar ]
34
32
URI
https://cherry.chem.bg.ac.rs/handle/123456789/568
Collections
  • Publikacije
Institution/Community
Hemijski fakultet
TY  - JOUR
AU  - Sabo, Tibor
AU  - Kaluđerović, Goran N.
AU  - Grgurić-Šipka, Sanja
AU  - Heinemann, FW
AU  - Trifunović, Srećko R.
PY  - 2004
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/568
AB  - Depending on the ester alkyl group, the reaction of O,O-dialkylethylenediamine-N,N'-di-3-propanoate ligands (R(2)eddp) with potassium hexachloroplatinate(IV) afforded trans-dichloro(ethylenediamine-N,N'-di-3-propanoato)platinum(IV) and tetrachloro(O,O-dialkyl-ethylenediamine-N,N'-di-3-propanoato)platinum(IV) complexes. The complexes were characterized by elemental analysis, electronic absorption, infrared, H-1 and C-13 NMR spectroscopy. The trans configuration of [Pt(eddp)Cl-2] complex was confirmed by X-ray crystallography. (C) 2003 Elsevier B.V. All rights reserved.
PB  - Elsevier Science Bv, Amsterdam
T2  - Inorganic Chemistry Communications
T1  - Complex compounds of platinum(IV) and O,O-dialkyl-ethylenediamine-N,N '-di-3-propanoate ligands. A structural evidence for geometry of hydrolytic product of some esters
VL  - 7
IS  - 2
SP  - 241
EP  - 244
DO  - 10.1016/j.inoche.2003.11.007
UR  - Kon_1567
ER  - 
@article{
author = "Sabo, Tibor and Kaluđerović, Goran N. and Grgurić-Šipka, Sanja and Heinemann, FW and Trifunović, Srećko R.",
year = "2004",
abstract = "Depending on the ester alkyl group, the reaction of O,O-dialkylethylenediamine-N,N'-di-3-propanoate ligands (R(2)eddp) with potassium hexachloroplatinate(IV) afforded trans-dichloro(ethylenediamine-N,N'-di-3-propanoato)platinum(IV) and tetrachloro(O,O-dialkyl-ethylenediamine-N,N'-di-3-propanoato)platinum(IV) complexes. The complexes were characterized by elemental analysis, electronic absorption, infrared, H-1 and C-13 NMR spectroscopy. The trans configuration of [Pt(eddp)Cl-2] complex was confirmed by X-ray crystallography. (C) 2003 Elsevier B.V. All rights reserved.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Inorganic Chemistry Communications",
title = "Complex compounds of platinum(IV) and O,O-dialkyl-ethylenediamine-N,N '-di-3-propanoate ligands. A structural evidence for geometry of hydrolytic product of some esters",
volume = "7",
number = "2",
pages = "241-244",
doi = "10.1016/j.inoche.2003.11.007",
url = "Kon_1567"
}
Sabo, T., Kaluđerović, G. N., Grgurić-Šipka, S., Heinemann, F.,& Trifunović, S. R.. (2004). Complex compounds of platinum(IV) and O,O-dialkyl-ethylenediamine-N,N '-di-3-propanoate ligands. A structural evidence for geometry of hydrolytic product of some esters. in Inorganic Chemistry Communications
Elsevier Science Bv, Amsterdam., 7(2), 241-244.
https://doi.org/10.1016/j.inoche.2003.11.007
Kon_1567
Sabo T, Kaluđerović GN, Grgurić-Šipka S, Heinemann F, Trifunović SR. Complex compounds of platinum(IV) and O,O-dialkyl-ethylenediamine-N,N '-di-3-propanoate ligands. A structural evidence for geometry of hydrolytic product of some esters. in Inorganic Chemistry Communications. 2004;7(2):241-244.
doi:10.1016/j.inoche.2003.11.007
Kon_1567 .
Sabo, Tibor, Kaluđerović, Goran N., Grgurić-Šipka, Sanja, Heinemann, FW, Trifunović, Srećko R., "Complex compounds of platinum(IV) and O,O-dialkyl-ethylenediamine-N,N '-di-3-propanoate ligands. A structural evidence for geometry of hydrolytic product of some esters" in Inorganic Chemistry Communications, 7, no. 2 (2004):241-244,
https://doi.org/10.1016/j.inoche.2003.11.007 .,
Kon_1567 .

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