Complex compounds of platinum(IV) and O,O-dialkyl-ethylenediamine-N,N '-di-3-propanoate ligands. A structural evidence for geometry of hydrolytic product of some esters
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2004
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Depending on the ester alkyl group, the reaction of O,O-dialkylethylenediamine-N,N'-di-3-propanoate ligands (R(2)eddp) with potassium hexachloroplatinate(IV) afforded trans-dichloro(ethylenediamine-N,N'-di-3-propanoato)platinum(IV) and tetrachloro(O,O-dialkyl-ethylenediamine-N,N'-di-3-propanoato)platinum(IV) complexes. The complexes were characterized by elemental analysis, electronic absorption, infrared, H-1 and C-13 NMR spectroscopy. The trans configuration of [Pt(eddp)Cl-2] complex was confirmed by X-ray crystallography. (C) 2003 Elsevier B.V. All rights reserved.
Ključne reči:
platinum(IV) / tetradentate ligands / bidentate ligands / eddpIzvor:
Inorganic Chemistry Communications, 2004, 7, 2, 241-244Izdavač:
- Elsevier Science Bv, Amsterdam
DOI: 10.1016/j.inoche.2003.11.007
ISSN: 1387-7003
WoS: 000188859000026
Scopus: 2-s2.0-0842299401
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Institucija/grupa
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Sabo, Tibor AU - Kaluđerović, Goran N. AU - Grgurić-Šipka, Sanja AU - Heinemann, FW AU - Trifunović, Srećko R. PY - 2004 UR - https://cherry.chem.bg.ac.rs/handle/123456789/568 AB - Depending on the ester alkyl group, the reaction of O,O-dialkylethylenediamine-N,N'-di-3-propanoate ligands (R(2)eddp) with potassium hexachloroplatinate(IV) afforded trans-dichloro(ethylenediamine-N,N'-di-3-propanoato)platinum(IV) and tetrachloro(O,O-dialkyl-ethylenediamine-N,N'-di-3-propanoato)platinum(IV) complexes. The complexes were characterized by elemental analysis, electronic absorption, infrared, H-1 and C-13 NMR spectroscopy. The trans configuration of [Pt(eddp)Cl-2] complex was confirmed by X-ray crystallography. (C) 2003 Elsevier B.V. All rights reserved. PB - Elsevier Science Bv, Amsterdam T2 - Inorganic Chemistry Communications T1 - Complex compounds of platinum(IV) and O,O-dialkyl-ethylenediamine-N,N '-di-3-propanoate ligands. A structural evidence for geometry of hydrolytic product of some esters VL - 7 IS - 2 SP - 241 EP - 244 DO - 10.1016/j.inoche.2003.11.007 ER -
@article{ author = "Sabo, Tibor and Kaluđerović, Goran N. and Grgurić-Šipka, Sanja and Heinemann, FW and Trifunović, Srećko R.", year = "2004", abstract = "Depending on the ester alkyl group, the reaction of O,O-dialkylethylenediamine-N,N'-di-3-propanoate ligands (R(2)eddp) with potassium hexachloroplatinate(IV) afforded trans-dichloro(ethylenediamine-N,N'-di-3-propanoato)platinum(IV) and tetrachloro(O,O-dialkyl-ethylenediamine-N,N'-di-3-propanoato)platinum(IV) complexes. The complexes were characterized by elemental analysis, electronic absorption, infrared, H-1 and C-13 NMR spectroscopy. The trans configuration of [Pt(eddp)Cl-2] complex was confirmed by X-ray crystallography. (C) 2003 Elsevier B.V. All rights reserved.", publisher = "Elsevier Science Bv, Amsterdam", journal = "Inorganic Chemistry Communications", title = "Complex compounds of platinum(IV) and O,O-dialkyl-ethylenediamine-N,N '-di-3-propanoate ligands. A structural evidence for geometry of hydrolytic product of some esters", volume = "7", number = "2", pages = "241-244", doi = "10.1016/j.inoche.2003.11.007" }
Sabo, T., Kaluđerović, G. N., Grgurić-Šipka, S., Heinemann, F.,& Trifunović, S. R.. (2004). Complex compounds of platinum(IV) and O,O-dialkyl-ethylenediamine-N,N '-di-3-propanoate ligands. A structural evidence for geometry of hydrolytic product of some esters. in Inorganic Chemistry Communications Elsevier Science Bv, Amsterdam., 7(2), 241-244. https://doi.org/10.1016/j.inoche.2003.11.007
Sabo T, Kaluđerović GN, Grgurić-Šipka S, Heinemann F, Trifunović SR. Complex compounds of platinum(IV) and O,O-dialkyl-ethylenediamine-N,N '-di-3-propanoate ligands. A structural evidence for geometry of hydrolytic product of some esters. in Inorganic Chemistry Communications. 2004;7(2):241-244. doi:10.1016/j.inoche.2003.11.007 .
Sabo, Tibor, Kaluđerović, Goran N., Grgurić-Šipka, Sanja, Heinemann, FW, Trifunović, Srećko R., "Complex compounds of platinum(IV) and O,O-dialkyl-ethylenediamine-N,N '-di-3-propanoate ligands. A structural evidence for geometry of hydrolytic product of some esters" in Inorganic Chemistry Communications, 7, no. 2 (2004):241-244, https://doi.org/10.1016/j.inoche.2003.11.007 . .