Differently prepared PbO2/graphitic carbon nitride composites for efficient electrochemical removal of Reactive Black 5 dye
Authors
Marković, AleksandarSavić, Slađana D.

Kukuruzar, Andrej

Konya, Zoltan
Manojlović, Dragan D.

Ognjanović, Miloš

Stanković, Dalibor

Article (Published version)
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In this paper, electrochemical degradation of Reactive Black 5 (RB5) textile azo dye was examined in regard to different synthesis procedures for making PbO2–graphitic carbon nitride (g-C3N4) electrode. The reaction of with ClO− in the presence of different surfactants, i.e., cetyltrimethylammonium bromide (CTAB) and tetrabutylammonium phosphate (TBAP), under conventional conditions, resulted in the formation of PbO2 with varying morphology. The obtained materials were combined with g-C3N4 for the preparation of the final composite materials, which were then characterized morphologically and electrochemically. After optimizing the degradation method, it was shown that an anode comprising a steel electrode coated with the composite of PbO2 synthesized using CTAB as template and g-C3N4, and using 0.15 M Na2SO4 as the supporting electrolyte, gave the best performance for RB5 dye removal from a 35 mg/L solution. The treatment duration was 60 min, applying a current of 0.17 A (electrode sur...face 4 cm2, current density of 42.5 mA/cm2), while the initial pH of the testing solution was 2. The reusability and longevity of the electrode surface (which showed no significant change in activity throughout the study) may suggest that this approach is a promising candidate for wastewater treatment and pollutant removal.
Keywords:
advanced oxidation processes / electrode morphology / energy efficiency / lead dioxide / reactive azo dye / surfactant-assisted synthesisSource:
Catalysts, 2023, 13, 2, 328-Publisher:
- MDPI
Funding / projects:
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200168 (University of Belgrade, Faculty of Chemistry) (RS-200168)
- EUREKA project E!13303.
- Ministry of Science and Higher Education of the Russian Federation (agreement No. 075-15-20221135).
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Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Marković, Aleksandar AU - Savić, Slađana D. AU - Kukuruzar, Andrej AU - Konya, Zoltan AU - Manojlović, Dragan D. AU - Ognjanović, Miloš AU - Stanković, Dalibor PY - 2023 UR - http://cherry.chem.bg.ac.rs/handle/123456789/5806 AB - In this paper, electrochemical degradation of Reactive Black 5 (RB5) textile azo dye was examined in regard to different synthesis procedures for making PbO2–graphitic carbon nitride (g-C3N4) electrode. The reaction of with ClO− in the presence of different surfactants, i.e., cetyltrimethylammonium bromide (CTAB) and tetrabutylammonium phosphate (TBAP), under conventional conditions, resulted in the formation of PbO2 with varying morphology. The obtained materials were combined with g-C3N4 for the preparation of the final composite materials, which were then characterized morphologically and electrochemically. After optimizing the degradation method, it was shown that an anode comprising a steel electrode coated with the composite of PbO2 synthesized using CTAB as template and g-C3N4, and using 0.15 M Na2SO4 as the supporting electrolyte, gave the best performance for RB5 dye removal from a 35 mg/L solution. The treatment duration was 60 min, applying a current of 0.17 A (electrode surface 4 cm2, current density of 42.5 mA/cm2), while the initial pH of the testing solution was 2. The reusability and longevity of the electrode surface (which showed no significant change in activity throughout the study) may suggest that this approach is a promising candidate for wastewater treatment and pollutant removal. PB - MDPI T2 - Catalysts T1 - Differently prepared PbO2/graphitic carbon nitride composites for efficient electrochemical removal of Reactive Black 5 dye VL - 13 IS - 2 SP - 328 DO - 10.3390/catal13020328 ER -
@article{ author = "Marković, Aleksandar and Savić, Slađana D. and Kukuruzar, Andrej and Konya, Zoltan and Manojlović, Dragan D. and Ognjanović, Miloš and Stanković, Dalibor", year = "2023", abstract = "In this paper, electrochemical degradation of Reactive Black 5 (RB5) textile azo dye was examined in regard to different synthesis procedures for making PbO2–graphitic carbon nitride (g-C3N4) electrode. The reaction of with ClO− in the presence of different surfactants, i.e., cetyltrimethylammonium bromide (CTAB) and tetrabutylammonium phosphate (TBAP), under conventional conditions, resulted in the formation of PbO2 with varying morphology. The obtained materials were combined with g-C3N4 for the preparation of the final composite materials, which were then characterized morphologically and electrochemically. After optimizing the degradation method, it was shown that an anode comprising a steel electrode coated with the composite of PbO2 synthesized using CTAB as template and g-C3N4, and using 0.15 M Na2SO4 as the supporting electrolyte, gave the best performance for RB5 dye removal from a 35 mg/L solution. The treatment duration was 60 min, applying a current of 0.17 A (electrode surface 4 cm2, current density of 42.5 mA/cm2), while the initial pH of the testing solution was 2. The reusability and longevity of the electrode surface (which showed no significant change in activity throughout the study) may suggest that this approach is a promising candidate for wastewater treatment and pollutant removal.", publisher = "MDPI", journal = "Catalysts", title = "Differently prepared PbO2/graphitic carbon nitride composites for efficient electrochemical removal of Reactive Black 5 dye", volume = "13", number = "2", pages = "328", doi = "10.3390/catal13020328" }
Marković, A., Savić, S. D., Kukuruzar, A., Konya, Z., Manojlović, D. D., Ognjanović, M.,& Stanković, D.. (2023). Differently prepared PbO2/graphitic carbon nitride composites for efficient electrochemical removal of Reactive Black 5 dye. in Catalysts MDPI., 13(2), 328. https://doi.org/10.3390/catal13020328
Marković A, Savić SD, Kukuruzar A, Konya Z, Manojlović DD, Ognjanović M, Stanković D. Differently prepared PbO2/graphitic carbon nitride composites for efficient electrochemical removal of Reactive Black 5 dye. in Catalysts. 2023;13(2):328. doi:10.3390/catal13020328 .
Marković, Aleksandar, Savić, Slađana D., Kukuruzar, Andrej, Konya, Zoltan, Manojlović, Dragan D., Ognjanović, Miloš, Stanković, Dalibor, "Differently prepared PbO2/graphitic carbon nitride composites for efficient electrochemical removal of Reactive Black 5 dye" in Catalysts, 13, no. 2 (2023):328, https://doi.org/10.3390/catal13020328 . .